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采用直流磁控溅射法在SLG衬底上沉积Mo薄膜,对不同溅射功率和溅射工作气压下沉积的薄膜进行X射线衍射、SEM(扫描电子显微镜)、电阻率测试,讨论了工艺参数对沉积Mo薄膜相结构、表面微观形貌、薄膜沉积速率和电学性能的影响。结果表明,随着溅射功率的增加,薄膜的结晶性能变好,沉积速率提高,在沉积功率范围内薄膜均匀致密,表面无空隙,电阻率较低;随着溅射工作气压增加,薄膜结晶性能变差,沉积速率先增加后降低,在沉积工作气压范围内,薄膜致密;随气压降低,电阻率急剧减小。因此,较高的溅射功率和较低的工作气压沉积的Mo薄膜更适合作CIGS薄膜太阳电池的BC层(背接触层)。

Molydbenum(Mo) thin films were deposited on soda-lime glass substrates using DC magnetron sputtering method.The structure,morphology,and electrical properties of the sputtered Mo films have been examined with respect to the deposition power and working gas pressure.Both increasing sputter power and decreasing work gas pressure result in the deposited Mo films exhibit better crystalline structure,more compact surface and lower resistivity.For the application of using as back ground of Cu(InGa)Se2(CIGS) solar cells,Mo films should be deposited at a higher deposition power and a lower working gas pressure.

参考文献

[1] 刘芳芳,何青,李凤岩,敖建平,孙国忠,周志强,孙云.Cu(In,Ga)Se2材料成分对其电池性能的影响[J].半导体学报,2005(10):1954-1958.
[2] Orgassa K.;Schock HW.;Werner JH. .Alternative back contact materials for thin film Cu(In,Ga)Se-2 solar cells[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2003(0):387-391.
[3] Zoppi, G.;Beattie, N.S.;Major, J.D.;Miles, R.W.;Forbes, I. .Electrical, morphological and structural properties of RF magnetron sputtered Mo thin films for application in thin film photovoltaic solar cells[J].Journal of Materials Science,2011(14):4913-4921.
[4] 齐红基,易葵,贺洪波,邵建达.溅射粒子能量对金属Mo薄膜表面特性的影响[J].物理学报,2004(12):4398-4404.
[5] 朱继国,丁万昱,王华林,张树旺,张粲,张俊计,柴卫平.Ar气压强对直流脉冲磁控溅射制备Mo薄膜性能的影响[J].微细加工技术,2008(04):35-38.
[6] 朱继国,柴卫平,王华林,张树旺,刘世民,张粲,汪亚辉.薄膜厚度对直流脉冲磁控溅射Mo薄膜光电性能的影响[J].光学仪器,2008(03):55-59.
[7] 黎刚.Mo沉积成膜质量与磁控溅射条件间关系的STM研究[J].电子显微学报,1997(04):453.
[8] 雷洁红,邢丕峰,唐永建,吴卫东.衬底温度对PLD制备的Mo薄膜结构及表面形貌的影响[J].强激光与粒子束,2009(03):377-380.
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