钢铁, 2014, 49(6): 1-7.
节能低成本高品质非调质钢的研发
陈思联 1, , 惠卫军 2, , 王连海 3, , 铬转化膜的性能以替代铬酸盐钝化膜,以钛盐为成膜主剂,钨酸盐为上色剂,多羟基有机酸钠为配位剂,在6063铝材表面进行无铬有色化学转化,采用铬酸盐点滴试验、电化学方法、中性盐雾试验及划格法对转化膜的耐蚀性、附着力进行了测试,并对转化液配方及成膜条件进行了优选,探讨了添加剂及工艺参数对膜层质量的影响.结果表明:较优转化液配方及成膜条件为2.0 g/L钛盐、0.3～0.5 g/L钨酸盐上色剂,0.5～0.7 g/L多羟基有机酸钠配位剂,25 ～ 30℃,pH值为3.2 ～3.6,转化时间为5～7 min;优化工艺可在6063铝合金表面获得均一的金黄色无铬转化膜,自腐蚀电流密度仅为基材的1/6;转化膜与聚酯漆膜的附着力与六价铬转化膜的相当;该工艺完全无铬、无毒.","authors":[{"authorName":"刘晓辉","id":"1494747a-7722-49ab-b2a9-811b0345b1e1","originalAuthorName":"刘晓辉"},{"authorName":"欧阳贵","id":"da79e82c-c9e7-44dc-90c6-829c229b97d1","originalAuthorName":"欧阳贵"},{"authorName":"占稳","id":"b5023c52-5b56-4539-9094-b5b817b7f2c4","originalAuthorName":"占稳"}],"doi":"","fpage":"28","id":"3dcd0cfc-bbc4-43b0-9f57-3ee4c5d32bb1","issue":"3","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"69d73dcc-c655-42d5-a466-f0ad435d225a","keyword":"化学转化","originalKeyword":"化学转化"},{"id":"5791dd4d-fb56-4eae-b472-61d479a36abb","keyword":"无铬有色转化膜","originalKeyword":"无铬有色转化膜"},{"id":"9289b30a-d218-4d58-88be-1dc0f4526888","keyword":"6063铝合金","originalKeyword":"6063铝合金"},{"id":"b8f58efd-f29c-4808-a741-0d36096f433b","keyword":"耐蚀性能","originalKeyword":"耐蚀性能"},{"id":"11704f0c-f6b2-4a1e-b4aa-b5f0daca4c66","keyword":"附着力","originalKeyword":"附着力"}],"language":"zh","publisherId":"clbh201403008","title":"6063铝合金无铬有色化学转化工艺探讨","volume":"47","year":"2014"},{"abstractinfo":"在含有Ti/Zr的处理液中加入单宁酸、有机缓蚀剂和硫酸锰,在铝合金基体上得到了耐蚀性能优异的金黄色转化膜.研究了处理液各组分对转化膜外观以及耐蚀性能的影响,确定了成膜的最佳工艺为:H2TiF6 7 g/L,H2ZrF6 1 g/L,F-3 g/L,单宁酸7g/L,硫酸锰5g/L,有机酸缓蚀剂2g/L,pH 4.9,成膜时间10 min.研究表明,单宁酸和H2TiF6是转化膜着色的关键,二者缺一不可.由最佳工艺得到的转化膜的自腐蚀电流密度是铝合金基体的1.3％,耐蚀性能明显提高.","authors":[{"authorName":"易爱华","id":"be12ad99-4b84-49c7-b06d-ffb288727101","originalAuthorName":"易爱华"},{"authorName":"黎雪芬","id":"b4cce8ce-bbb0-4b02-ac23-c6e6df3691c0","originalAuthorName":"黎雪芬"},{"authorName":"李文芳","id":"1c52d973-8515-4914-a54c-41d15f305589","originalAuthorName":"李文芳"},{"authorName":"杜军","id":"2e013400-40c5-43bc-9dca-ede809b2da4e","originalAuthorName":"杜军"}],"doi":"","fpage":"519","id":"0f82e168-1f10-497a-a1f8-a590f918b507","issue":"12","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰 "},"keywords":[{"id":"5ed2d66e-5c31-44a2-b0fc-fc55f86d5b77","keyword":"铝合金","originalKeyword":"铝合金"},{"id":"779f559d-3bc4-4316-922b-043d475241bc","keyword":"氟钛酸","originalKeyword":"氟钛酸"},{"id":"69098eb5-4166-450d-8afb-ab7979697e81","keyword":"氟锆酸","originalKeyword":"氟锆酸"},{"id":"1a917515-3857-4b0b-a8bc-557ba30c8b15","keyword":"单宁酸","originalKeyword":"单宁酸"},{"id":"850a5c90-1cfc-4763-bbef-ed76c8bcec11","keyword":"化学转化膜","originalKeyword":"化学转化膜"},{"id":"63ab87c7-ad64-4a28-95a8-1740022b7085","keyword":"着色","originalKeyword":"着色"},{"id":"0c958856-6043-4048-923c-92cc8ca3ea62","keyword":"耐蚀性","originalKeyword":"耐蚀性"}],"language":"zh","publisherId":"ddyts201412007","title":"铝合金表面有色转化膜快速成膜工艺","volume":"33","year":"2014"},{"abstractinfo":"环保的需要使得铬酸盐转化膜逐渐被各种无铬转化膜所替代.本文介绍了含氧酸盐、锆盐和钛盐、稀土、植酸、硅烷等无铬表面转化膜的形成机理及发展现状.随着科技的发展,无铬转化膜将引起人们越来越多的重视,并能应用于更多的领域中.","authors":[{"authorName":"胡会利","id":"b48e3776-9252-4c3e-95d2-683b9f18ada2","originalAuthorName":"胡会利"},{"authorName":"陈丽姣","id":"bad8ec2d-b98b-44f3-b443-e45ab2b1820e","originalAuthorName":"陈丽姣"}],"doi":"","fpage":"727","id":"7227181f-db85-43e8-99b9-211b14679df6","issue":"10","journal":{"abbrevTitle":"FSYFH","coverImgSrc":"journal/img/cover/FSYFH.jpg","id":"25","issnPpub":"1005-748X","publisherId":"FSYFH","title":"腐蚀与防护"},"keywords":[{"id":"0f9ea2cd-6409-4cec-a405-ea7869b9efeb","keyword":"转化膜","originalKeyword":"转化膜"},{"id":"5fac935c-998c-4ff1-9357-a40c42d4d256","keyword":"含氧酸盐","originalKeyword":"含氧酸盐"},{"id":"1883c2a8-0f3f-436e-bc5e-684cf72e65f8","keyword":"稀土","originalKeyword":"稀土"},{"id":"375ab785-ad01-4eb5-8bcf-0b54b2e0dcdc","keyword":"植酸","originalKeyword":"植酸"},{"id":"3a2a34b0-adc7-4123-8585-1032566da9c4","keyword":"硅烷","originalKeyword":"硅烷"}],"language":"zh","publisherId":"fsyfh200910015","title":"表面转化膜无铬化技术的研究动向","volume":"30","year":"2009"},{"abstractinfo":"综述了国内外镁合金无铬化学转化膜研究现状,通过分析不同转化液的配方、主要处理工艺及相应转化膜的组成、结构、形貌、膜层的耐蚀性能,指出现有无铬转化技术存在的不足,并展望了无铬化学转化膜的未来发展趋势.","authors":[{"authorName":"张华","id":"3379c14d-2a15-48cb-9bf1-770954c73d26","originalAuthorName":"张华"},{"authorName":"姚广春","id":"2e930d46-e256-41f7-8b86-8f59c22c63c1","originalAuthorName":"姚广春"},{"authorName":"刘宜汉","id":"26bf49c2-17bb-40be-ad07-6a30680b6ad7","originalAuthorName":"刘宜汉"}],"doi":"","fpage":"77","id":"bfbbdb4e-b2e8-408c-ac73-8cd65716c3cc","issue":"3","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"d4806806-8666-4fc5-8370-fbe8be3717fa","keyword":"镁合金","originalKeyword":"镁合金"},{"id":"e6c37485-e5e6-4a66-a68a-23602f62b053","keyword":"无铬转化膜","originalKeyword":"无铬转化膜"},{"id":"278c7807-ee16-4599-ab4e-7b7c9b654716","keyword":"化学转化膜","originalKeyword":"化学转化膜"}],"language":"zh","publisherId":"cldb200703021","title":"镁合金无铬化学转化膜的研究进展","volume":"21","year":"2007"},{"abstractinfo":"目前，常规紫铜无铬转化液主要由苯骈三氮唑（BTA）、配位剂和表面活性剂组成，所得转化膜的耐蚀性较差。在常规无铬转化液中加入钼酸钠和硝酸镧，并确定了一种环保型紫铜表面无铬成膜工艺：12g／L BTA，8g／LNa2MoO4，4g／LLa（NO3）3·6H2O，10g／LC6H807，4g／LC7H606S·2H2O，温度50℃，时间5min。通过中性盐雾试验测试了所得转化膜的耐蚀性；采用极化曲线和交流阻抗谱分析了转化膜在1mol／LHCl中的电化学行为，同时用场发射扫描电镜（FESEM）观察了转化膜的表面形貌。结果表明：本工艺无铬、环保，可在紫铜表面形成完整、致密的转化膜，缓蚀率达98．8％，耐蚀性优于铬酸盐钝化膜和常规无铬钝化膜。","authors":[{"authorName":"郑伟","id":"897cf914-7be6-4a69-9eae-38bbd3982669","originalAuthorName":"郑伟"},{"authorName":"吴玉程","id":"43c1110d-a53b-4585-a057-5fe4ed5d2db7","originalAuthorName":"吴玉程"},{"authorName":"刘万青","id":"b77140e1-3d0e-4a91-b480-867ef2f9893a","originalAuthorName":"刘万青"},{"authorName":"舒霞","id":"0b2e91b1-6f87-4f0d-bdd6-3535fe8bd0e4","originalAuthorName":"舒霞"},{"authorName":"郑玉春","id":"127b566f-c8aa-4186-a572-598dfb7521a5","originalAuthorName":"郑玉春"},{"authorName":"黄新民","id":"5a4fa613-b011-48ed-b2b5-3bd20d578d3d","originalAuthorName":"黄新民"}],"doi":"","fpage":"1","id":"3c46d91d-1e7e-4af3-b3b7-6d0442a22600","issue":"6","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"db7a47f3-4eeb-4ac9-82ae-18940d72475a","keyword":"无铬转化膜","originalKeyword":"无铬转化膜"},{"id":"ac31bb88-6564-4250-9aaf-b253a4388976","keyword":"BTA","originalKeyword":"BTA"},{"id":"86bae38d-e006-4d77-9cf0-bf29fef185b0","keyword":"钼酸钠","originalKeyword":"钼酸钠"},{"id":"2f6a903a-82a7-46b3-b9f2-87b57fe53313","keyword":"硝酸镧","originalKeyword":"硝酸镧"},{"id":"b10e0c66-7a40-45b8-8fb0-46d77a7aaa90","keyword":"紫铜","originalKeyword":"紫铜"},{"id":"f2307334-d3ef-4b82-bd15-2adbd1e66f87","keyword":"电化学行为","originalKeyword":"电化学行为"},{"id":"62f47f17-0b42-496d-9c2f-c775a5905469","keyword":"表面形貌","originalKeyword":"表面形貌"},{"id":"001700c7-8a5e-4517-a334-85db26566d61","keyword":"耐蚀性","originalKeyword":"耐蚀性"}],"language":"zh","publisherId":"clbh201206002","title":"紫铜表面新型无铬转化膜的耐蚀性能","volume":"45","year":"2012"},{"abstractinfo":"综述了镁合金多种无铬化学转化膜工艺的研究现状及其发展前景.总结了镁合金在磷酸盐、磷酸-高锰酸盐、稀土、锡酸盐、植酸及锆酸盐等多种体系中的基本成膜工艺,比较了不同工艺得到的表面钝化膜的组成及膜层性能,分析了各成膜工艺的优缺点,指出了各工艺的工业化应用的可行性.","authors":[{"authorName":"程瑾宁","id":"c372ed8f-b20c-4d05-a198-a72d77bac32c","originalAuthorName":"程瑾宁"},{"authorName":"孙伶","id":"eda666ce-1075-4ffd-bdd1-44e0bd4b342e","originalAuthorName":"孙伶"},{"authorName":"胡会利","id":"2a5daf8f-b821-4198-b962-04496682eec3","originalAuthorName":"胡会利"},{"authorName":"李宁","id":"855c75d9-5dbe-4848-8a7c-48975f188fef","originalAuthorName":"李宁"}],"doi":"10.3969/j.issn.1001-3849.2008.02.004","fpage":"11","id":"24282664-0f25-4480-b176-dc020fcc8896","issue":"2","journal":{"abbrevTitle":"DDYJS","coverImgSrc":"journal/img/cover/DDYJS.jpg","id":"20","issnPpub":"1001-3849","publisherId":"DDYJS","title":"电镀与精饰 "},"keywords":[{"id":"acab7b46-6c15-48dd-b58d-2c4e7270b8bd","keyword":"镁合金","originalKeyword":"镁合金"},{"id":"a2a3f706-cfe0-4938-9acc-f63e5bc3376c","keyword":"化学转化膜","originalKeyword":"化学转化膜"},{"id":"033aff2f-20ff-4cdf-b45e-cfb6ca4a5234","keyword":"耐蚀性","originalKeyword":"耐蚀性"},{"id":"6a51e145-be1c-403b-b642-eba69b85906b","keyword":"无铬","originalKeyword":"无铬"}],"language":"zh","publisherId":"ddjs200802004","title":"镁合金无铬化学转化膜工艺研究现状","volume":"30","year":"2008"},{"abstractinfo":"综述了铝及铝合金无铬表面化学转化膜工艺的应用现状及各种工艺的成膜机理,包括磷酸盐处理、钛锆类处理、稀土转化膜、锰酸盐转化、硅酸盐及钼酸盐处理.目前在生产中已经获得应用的有磷酸盐处理和锆钛转化处理,但还没有一种无铬处理工艺能够完全代替铬酸盐处理工艺.","authors":[{"authorName":"秦振华","id":"9770d7d5-1861-441b-b9bf-0fb2643464c7","originalAuthorName":"秦振华"},{"authorName":"李红玲","id":"6f7f8e0a-700c-4668-8a98-a359ce4dcab1","originalAuthorName":"李红玲"}],"doi":"","fpage":"269","id":"5dd49a65-6ecc-4d17-847c-e7ea242b2464","issue":"3","journal":{"abbrevTitle":"FSXB","coverImgSrc":"journal/img/cover/腐蚀学报封面.jpg","id":"24","issnPpub":"2667-2669","publisherId":"FSXB","title":"腐蚀学报（英文）"},"keywords":[{"id":"d3404759-04b7-413e-bfb3-694e8b6dd8b2","keyword":"铝","originalKeyword":"铝"},{"id":"94bc01af-29b0-402f-96df-904adb7b1cce","keyword":"铝合金","originalKeyword":"铝合金"},{"id":"9b09805e-f912-4cc1-aa01-773401c67156","keyword":"无铬化学转化膜","originalKeyword":"无铬化学转化膜"}],"language":"zh","publisherId":"fskxyfhjs201403015","title":"铝及铝合金无铬化学转化膜工艺的研究进展","volume":"26","year":"2014"},{"abstractinfo":"常温下对6061铝合金表面转化膜进行了研究,分别讨论了Zn2+、Po3-4、F-、Fe2+、Ce3+、Cu2+对磷化膜质量的影响,同时通过正交试验和综合评定法确定出了一种不含铬的铝合金稀土磷化液的介质组成及相应的工艺参数.转化膜成分含有Zn、Fe、P、O、Ce的复合磷酸盐,结果表明:此磷化液在常温下,8 min即可在6061铝合金表面上生成一层均匀、致密、耐蚀性良好的磷化膜.该方法工艺简单,在整个工艺过程中不需要使用铬元素,对环境影响小,具有良好的应用前景.","authors":[{"authorName":"娄淑芳","id":"b1907a5c-a157-46a6-af6e-1269b339ccf6","originalAuthorName":"娄淑芳"},{"authorName":"李红玲","id":"bb561b13-b595-40f1-b913-563f6f78fc61","originalAuthorName":"李红玲"}],"doi":"10.3969/j.issn.0253-4312.2011.01.011","fpage":"38","id":"de7d6faa-5865-43fb-a02a-ff53a99fe05a","issue":"1","journal":{"abbrevTitle":"TLGY","coverImgSrc":"journal/img/cover/TLGY.jpg","id":"61","issnPpub":"0253-4312","publisherId":"TLGY","title":"涂料工业 "},"keywords":[{"id":"c9705f1e-6152-4eb6-b56b-8930f93369d7","keyword":"无铬","originalKeyword":"无铬"},{"id":"7e111b25-e52e-4826-8e13-259c4eb04946","keyword":"6061铝合金","originalKeyword":"6061铝合金"},{"id":"d54a6a06-92a7-4e76-b645-512c9203e1a8","keyword":"稀士转化膜","originalKeyword":"稀士转化膜"},{"id":"1ca565a4-bff6-42c8-b2a7-c1f7a875aa6f","keyword":"磷化","originalKeyword":"磷化"}],"language":"zh","publisherId":"tlgy201101011","title":"无铬磷酸盐稀土转化膜工艺研究","volume":"41","year":"2011"},{"abstractinfo":"以单宁酸和氟钛酸盐为主体原料,加入硝酸铜,在铝合金表面形成化学转化膜,以硫酸铜点滴试验为依据,通过单因素实验优化了铝合金非铬转化膜工艺条件:乙二胺四乙酸二钠0.5 g/L,氟钛酸钾1.0g/L,氟硼酸铵0.25 g/L,单宁酸0.8 g/L,马日夫盐0.5 g/L,A液(含Cu(NO3)2·3H2O和氟钛酸)25 mL/L,化学转化液的pH 2.5～3.5,温度35℃,浸渍时间15 min.该工艺可在铝合金表面形成完整致密的金黄色非晶态化学转化膜,硫酸铜点滴时间达到6 min,具有较好的抗蚀性能.","authors":[{"authorName":"陈泽民","id":"3f97506b-250d-476d-be58-4a5df4297f76","originalAuthorName":"陈泽民"},{"authorName":"高梦颖","id":"98526216-0c51-4e97-b723-c530f9b81540","originalAuthorName":"高梦颖"},{"authorName":"杨红贤","id":"59bccbdc-570c-408c-9522-b3d16145b1ab","originalAuthorName":"杨红贤"}],"doi":"","fpage":"391","id":"97c430e8-ea42-4ba3-b376-f4ccd6053144","issue":"7","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰 "},"keywords":[{"id":"32e2590e-6be1-4c22-95d4-b4fc3abc24f4","keyword":"铝合金","originalKeyword":"铝合金"},{"id":"df688894-b61f-4bec-be1a-a84154b4fd3c","keyword":"化学转化膜","originalKeyword":"化学转化膜"},{"id":"c33c1690-fcba-446b-a611-956024af9492","keyword":"单宁酸","originalKeyword":"单宁酸"},{"id":"34860d65-0834-485a-a121-5b6398690833","keyword":"氟钛酸盐","originalKeyword":"氟钛酸盐"},{"id":"4edcf762-e804-49a0-b9a7-47e30ebb212f","keyword":"耐蚀性","originalKeyword":"耐蚀性"}],"language":"zh","publisherId":"ddyts201507007","title":"铝合金无铬化学转化膜工艺研究","volume":"34","year":"2015"},{"abstractinfo":"研究了一种适用于铝及铝合金的无铬化学转化工艺,探讨了转化液的主要成分和工艺条件对转化膜质量的影响,得到了较好的工艺条件:氟锆酸钾1.0～2.0 g/L,氢氟酸0.5 ～ 1.5 mL/L,促进剂4～6g/L,氧化剂(硝酸镁)8～12g/L,pH 3.5～4.0,温度40～60℃,氧化时间4～6min.按此工艺制备的转化膜均匀致密,呈彩虹色,色泽鲜艳,附着力1级,在35 ℃、5％(质量分数)的氯化钠溶液中的腐蚀速率为0.019 89 g/(m2·h),与铬酸盐钝化膜的耐蚀性相当.喷涂在该转化膜上的漆膜,当中性盐雾试验进行至240h时,仍无脱落.","authors":[{"authorName":"肖鑫","id":"1def6d72-386f-40e1-a959-bb1776bd89a8","originalAuthorName":"肖鑫"},{"authorName":"许律","id":"5ac42125-64bd-4699-a426-2751cf25cac7","originalAuthorName":"许律"},{"authorName":"邓轾轩","id":"10df3529-7f27-4030-9db4-849651a57551","originalAuthorName":"邓轾轩"},{"authorName":"王韬","id":"a0b567f5-cde2-4cde-91da-4f7055ed5046","originalAuthorName":"王韬"},{"authorName":"阳颉","id":"1e13aa63-29b3-4bb9-88a1-7df2b9242686","originalAuthorName":"阳颉"}],"doi":"","fpage":"37","id":"dc297898-e99c-4c14-86e5-59dba4c76c16","issue":"10","journal":{"abbrevTitle":"DDYTS","coverImgSrc":"journal/img/cover/DDYTS.jpg","id":"21","issnPpub":"1004-227X","publisherId":"DDYTS","title":"电镀与涂饰 "},"keywords":[{"id":"6aba68fc-035d-4bed-b2a9-de5e09454cff","keyword":"铝和铝合金","originalKeyword":"铝和铝合金"},{"id":"83152076-d997-4493-834d-a73a5e9eb5f0","keyword":"无铬化学转化膜:氟锆酸盐","originalKeyword":"无铬化学转化膜:氟锆酸盐"},{"id":"f5a27969-a957-499b-94f2-70be60d9be1b","keyword":"耐蚀性","originalKeyword":"耐蚀性"}],"language":"zh","publisherId":"ddyts201110010","title":"铝及铝合金无铬氟锆酸盐化学转化膜","volume":"30","year":"2011"}],"totalpage":12605,"totalrecord":126049}