在六枝烟煤中添加溴化钠(NaBr),研究了在煤粉燃烧过程中NaBr对汞的形态转化和NO的还原规律的影响.实验在石英固定床反应器上进行,温度范围为800~1100℃.实验结果表明,温度窗口为250~400℃时,NaBr对单质汞的氧化有一定的促进作用;在合适的温度范围内(800~1000℃),NaBr的添加能够有效地抑制NO的生成,取得比单独煤粉燃烧较好的脱硝效果.在900℃时,添加NaBr使NO生成量下降了60%.在1100℃时,NaBr对NO的还原有抑制作用.
参考文献
[1] | Ya.E. Yudovich;M.P. Ketris .Mercury in coal: a review Part 2. Coal use and environmental problems[J].International Journal of Coal Geology,2005(3):135-165. |
[2] | Sang Wook Bae;Seon Ah Roh;Sang Done Kim .NO removal by reducing agents and additives in the selective non-catalytic reduction (SNCR) process[J].Chemosphere: Environmental toxicology and risk assessment,2006(1):170-175. |
[3] | Ye Zhuang;Jason Laumb;Richard Liggett .Impacts of acid gases on mercury oxidation across SCR catalyst[J].Fuel Processing Technology,2007(10):929-934. |
[4] | VITALI V.LISSIANSKI;VLADIMIR M.ZAMANSKY;PETER M.MALY .Effect of Metal-Containing Additives on NOx Reduction in Combustion and Reburning[J].Combustion and Flame,2001(3):1118-1127. |
[5] | Zamansky Vladimir M.;Maly Peter M.;Ho Loc;Rusli Darwin;Gardiner William C. Jr.;Lissianski Vitali V. .Reactions of sodium species in the promoted SNCR process[J].Combustion and Flame,1999(4):821-831. |
[6] | Seungmoon Lee;Kwinam Park;Jin-won Park;Byung-Hwan Kim .Characteristics of reducing NO using urea and alkaline additives[J].Combustion and Flame,2005(3):200-203. |
[7] | Zhi Wang;Simo O. Pehkonen .Oxidation of elemental mercury by aqueous bromine: atmospheric implications[J].Atmospheric environment,2004(22):3675-3688. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%