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  4. 原子转移自由基聚合催化剂固载化的研究进展

材料导报, 2011, 25(7): 52-55.

原子转移自由基聚合催化剂固载化的研究进展

王雯雯 1, , 张秋禹 2, , 郭飞鸽 3, , 顾军渭 4, , 尹常杰 5, , 孙九立 6,

1.西北工业大学理学院应用化学系,西安710129

2.西北工业大学理学院应用化学系,西安710129

3.西北工业大学理学院应用化学系,西安710129

4.西北工业大学理学院应用化学系,西安710129

5.西北工业大学理学院应用化学系,西安710129

6.西北工业大学理学院应用化学系,西安710129

基金项目:   国家自然科学基金(50773063)  

关键词： 原子转移自由基聚合 , 配体 , 催化剂固载化 , 催化机理

Progress in Immobilization of Catalyst in Atom Transfer Radical Polymerization

简述了原子转移自由基聚合( ATRP)的反应机理,并就相应的配体和催化剂的发展进行了概述,指出了将催化剂固载成为降低产物中催化剂残留的有效途径,重点论述了固载催化机理及近年来固载催化技术的最新研究进展,最后展望了ATRP催化剂固载化技术的发展方向.

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