利用超声分散原理,将Ti(OC4H9)4/乙醇加入到丝素溶液中,发生水解-缩聚反应,制得纳米TiO2再生丝素膜.对膜的溶失率和机械强度测试,续对之进行SEM、XRD、FTIR、EDS及复合丝素整理织物的染色性能的表征.结果表明,纳米粒子在丝素膜中分布均匀,随着纳米TiO2的加入,膜机械强度提高,在水中溶失率下降;丝素膜的结晶结构从Silk Ⅰ向Silk Ⅱ转化,用复合丝素整理织物的上染率和色牢度均比纯丝素整理的高.
参考文献
| [1] | Lapidot N;Gans O;Biagimi F .[J].Journal of Sol-Gel Science and Technology,2003,26:67. |
| [2] | Kato T.;Ushijima H.;Katsumata M.;Hyodo T.;Shimizu Y.;Egashira M. .Fabrication of hollow alumina microspheres via core/shell structure of polymethylmethacrylate/alumina prepared by mechanofusion[J].Journal of Materials Science,2002(11):2317-2321. |
| [3] | Qian J;Liu Y;Liu H et al.[J].Analytical Biochemistry,1996,236:208-214. |
| [4] | Sofia S;McCarthy M B;Gronowicz G et al.[J].Journal of Biomedical Materials Research,2001,54:139-148. |
| [5] | 卢神州,李明忠,刘洋,张可达.聚乙二醇缩水甘油醚对丝素蛋白膜的改性[J].高分子材料科学与工程,2003(01):104-107. |
| [6] | Li Wang;Nemoto R;Senna M .[J].Journal of Nanoparticle Research,2000,4:535-540. |
| [7] | 陈龙武,盛闻超,甘礼华.TiO2功能薄膜的制备及影响其光催化活性的因素[J].功能材料,2002(03):246-249. |
| [8] | Tsujino M;Isobe T;Senna M .[J].Journal of Sol-Gel Science and Technology,2000,19:785-789. |
| [9] | Feng Xinxing;Zhang Lili;Chen Jianyong et al.[J].International Journal of Biological Macromolecules,2007,40:105-111. |
| [10] | Ishizu K;Shiratori S .[J].Journal of Materials Science Letters,2002,21:2105. |
| [11] | Shimura K;Kikuchi A;Katagata Y et al.[J].Journal of Sericulture Science of Jpnan,1982,51:20-26. |
| [12] | Perrin F X;Nguyen V;Vernet J L .[J].Journal of Sol-Gel Science and Technology,2003,28:205-215. |
| [13] | Miniura N;Aiba S;Higuchi M .[J].Biochemical and Biophysical Research Communications,1995,208:511-516. |
| [14] | Wang S;Wang Q H;Ying X L .[J].Chinese Journal of Polymer Science,2003,21(01):87-91. |
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