A new electroluminescent material, salicylaldehyde anil zinc (SAZ) was synthesized, which can form high quality, thermal stability, nano-scale amorphous films by vacuum evaporation. Its structure, thermal stability were characterized by infrared (IR) spectra, differential thermal analysis-thermogravimetry (DTA-TG) analysis,respectively. The optical properties of SAZ were investigated by UV absorption spectra, Photoluminescence (PL) excitation and emission spectra. The highest occupied molecular orbits (HOMO), lowest unoccupied molecular orbits (LUMO) and optical band gap were evaluated by cyclic voltammetry curve and optical absorption band edge. The electroluminescent devices using SAZ as the emissive layer emit green light with a peak wavelength at 509 nm and a brightness of about 3.1 cd/m2.
参考文献
[1] | C W Tang;S A Van Slyke .[J].Applied Physics Letters,1987,51(12):913. |
[2] | C W Tang;S A Van Slyke;C H Chen .[J].Journal of Applied Physics,1989,65:3610. |
[3] | C H Chen;J Shi .[J].Coordination Chemistry Reviews,1998,171:161. |
[4] | Yuji Hamada .[J].IEEE Transactions on Electron Devices,1997,44(08):1208. |
[5] | O K Kwon;Y K Kim;B C Sohn;Y K Ha .[J].MOLECULAR CRYSTALS AND LIQUID CRYSTALS,2000,349:405. |
[6] | Hong CAO;Xicun GAO;Baowen ZHANG;Chunhui HUANG, Yi CAO .[J].Synthetic Metals,1998,96(03):191. |
[7] | Y Hamada;T Sano;H Fujii;Y Nishio, H Takeshi, K Shibata .[J].Japanese Journal of Applied Physics,1996,35:1339. |
[8] | X. T. Tao;H. Suzuki;T. Watanabe .Metal complex polymer for second harmonic generation and electroluminescence applications[J].Applied physics letters,1997(9/12):1503-1505. |
[9] | Yuji Hamada;Takeshi Sano;Masayuki Fujita;Takanori Fujii, Yoshitaka Nishio, Kenichi Shibata .[J].Japanese Journal of Applied Physics,1993,32:511. |
[10] | Yan SHAO;Yong QIU;Wenhua HU;Xiaoyin HONG .[J].Advanced Materials for Optics and Electronics,2000,10(06):285. |
[11] | Gui Yu;Yunqi Liu;Yaru Song .A new blue light-emitting material[J].Synthetic Metals,2001(1/3):211-214. |
[12] | Kim Sung Min;Kim Jin-Soon;Sohn Byung Chung .[J].MOLECULAR CRYSTALS AND LIQUID CRYSTALS,2001,371:321. |
[13] | Yunqi LIU;Yu GUI;Xia WU .[J].Chin J Luminesce,2000,21(zk):17. |
[14] | L Sacconi;P Paoletti;M Ciampolini .[J].Journal of the American Chemical Society,1963,85:411. |
[15] | J Wagner;R O Loutfy;C K Hsiao .[J].Journal of Materials Science,1982,17:2781. |
[16] | Y Abe;K Onlsawa;S Aratani;M Hannazono .[J].Journal of the Electrochemical Society,1992,193:641. |
[17] | S. Zolezzi;A. Decinti;E. Spodine .Syntheses and characterization of copper(II) complexes with Schiff-base ligands derived from ethylenediamine, diphenylethylenediamine and nitro, bromo and methoxy salicylaldehyde[J].Polyhedron: The International Journal for Inorganic and Organometallic Chemistry,1999(6):897-904. |
[18] | M Kasha .[J].Radiation Research,1963,20:55. |
[19] | R M Hochstrasser;M Kasha .[J].Photochemistry and Photobiology,1964,3:317. |
[20] | M Ahmed;Z H Khanl .[J].Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy,2000,56:965. |
[21] | 宋文波,陈旭,吴芳,田文晶,马淤光,许宏鼎.有机/聚合物材料体系能带结构的表征电化学方法研究[J].高等学校化学学报,2000(09):1422-1426. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%