向Zn-35％Sn合金中加入不同含量的镁元素,研究了镁含量对该合金显微组织和力学性能的影响,并分析了拉伸断口形貌.结果表明:加入微量的镁元素就会对Zn-35％Sn合金的显微组织和力学性能产生显著影响(伸长率急剧下降);加入到合金中的镁元素,一部分固溶于富锌的η相中,使该相原子沿垂直于密排面方向堆垛,形成棒状组织;另一部分与锡反应生成Mg2Sn,Mg2Sn作为异质晶核促进脆锡相(γ-Sn)的形核生长,且阻碍脆锡相向白锡相(β-Sn)的同素异构转变,使脆性组织保留下来;随着镁含量的增加,η相棒状晶粒尺寸增大,取向性逐渐明显,断裂解理面变大,塑韧性急剧下降.
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