为了解决烟用聚丙烯(PP)滤嘴材料对烟气吸附性能差、降焦性能低等问题,采用等离子体辐射引发的方法,在烟用聚丙烯纤维基体上分两步接枝丙烯酸(AA)和2-丙烯酰胺-2-甲基丙磺酸(AMPS)单体,制备了聚丙烯高吸附滤嘴.讨论了单体浓度、辐照时间、阻聚剂浓度对聚丙烯纤维接枝率的影响.利用衰减全反射红外光谱和扫描电子显微镜对接枝后的聚丙烯纤维基体的表面化学组成和形貌结构进行表征,结果表明,AMPS单体被成功接枝到PP纤维上.当改性后聚丙烯纤维的接枝率为22.8%时,改性后聚丙烯纤维滤嘴对烟气的过滤效果比改性前明显提高,烟气中的总粒相物比未改性滤嘴降低了30.5%,焦油及烟碱含量分别降低43.2%和31.7%.
参考文献
[1] | Fujioka K;Shibamoto T .Determination of toxic carbonyl compounds in cigarette smoke.[J].Environmental toxicology,2006(1):47-54. |
[2] | Al Rashidi M;Shihadeh A;Saliba NA .Volatile aldehydes in the mainstream smoke of the narghile waterpipe.[J].Food and Chemical Toxicology: An International Journal Published for the British Industrial Biological Research,2008(11):3546-3549. |
[3] | Turhan Y;Turan P;Dogan M;Alkan M;Narnli H;Demirbas O .Characterization and adsorption properties of chemically modified sepiolite[J].Industrial & Engineering Chemistry Research,2008(6):1883-1895. |
[4] | Kim I Y;Seo S J;Moon H S et al.Chitosan and its deriv-atives for tissue engineering applications[J].Biotechnol-ogy Advances,2008,26(01):1-21. |
[5] | Yamada K;Takeda S;Hirata M .Improvement of autohesive and adhesive properties of polyethylene plates by photografting with glycidyl methacrylate[J].Journal of Applied Polymer Science,2007(1):493-500. |
[6] | Yamada K.;Kimura J.;Hirata M. .Autohesive properties of polyolefins photografted with hydrophilic monomers[J].Journal of Applied Polymer Science,2003(14):2244-2252. |
[7] | Xing CM;Deng JP;Yang WT .Synthesis of antibacterial polypropylene film with surface immobilized polyvinylpyrrolidone-iodine complex[J].Journal of Applied Polymer Science,2005(5):2026-2031. |
[8] | Ma ZW.;Gao CY.;Juan J.;Ji J.;Gong YH.;Shen JC. .Surface modification of poly-L-lactide by photografting of hydrophilic polymers towards improving its hydrophilicity[J].Journal of Applied Polymer Science,2002(10):2163-2171. |
[9] | GB/T 19609-2004.卷烟用常规分析用吸烟机测定总粒相物和焦油[S]. |
[10] | 闫克玉,王建民,姚二民,闫洪洋,黄鸿勋.卷烟烟气气相中的有害物质及其减少措施[J].郑州轻工业学院学报(自然科学版),2005(04):15-18. |
[11] | YC/T156-2001.烟总粒相物中烟碱的测定气相色谱法[S]. |
[12] | YC/T157-2001.卷烟总粒相物中水分的测定气相色谱法[S]. |
[13] | Yu H;Cao Y;Kang G et al.Enhancing antifouling property of polysulfone ultrafiltration membrane by grafting zwitterionic copolymer via UV-initiated poly-merization[J].Journal of Membrane Science,2009,342(01):6-13. |
[14] | Yang WT.;Ranby B. .BULK SURFACE PHOTOGRAFTING PROCESS AND ITS APPLICATIONS .2. PRINCIPAL FACTORS AFFECTING SURFACE PHOTOGRAFTING[J].Journal of Applied Polymer Science,1996(3):545-555. |
[15] | 李绍宁,魏俊富,赵孔银,张环,姜智广,孙世军,王小雪.聚丙烯接枝丙烯酸丁酯吸油纤维的制备和表征[J].功能材料,2011(z3):559-561. |
[16] | Kubota H;Ogiwara Y .Effect of water in vapor-phase photografting of vinyl monomers on polymer films[J].Journal of Applied Polymer Science,1991,43(05):1001-1005. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%