欢迎登录材料期刊网

材料期刊网

高级检索

采用高能球磨法制备了纳米铜/石蜡复合材料.通过TEM、SEM、XRD和DSC对复合材料的微观形貌、物相及相变温度和潜热进行了表征和分析,并研究了铜含量对复合材料的热敏性、热膨胀性和热稳定性的影响.结果表明:石蜡包覆在铜粒表面,能显著提高其抗氧化性,铜/石蜡复合颗粒近似球形,粒径约为100 nm,多个复合颗粒易团聚形成微米级颗粒;铜含量对相变温度没有明显影响,但相变潜热随铜含量的增加近似线性减少;复合材料的热敏性随着铜含量的增加而提高,但其热膨胀性则降低;铜质量分数为60%的复合材料具有较短的升温时间,体膨胀率降低较小,且多次加热后稳定性较好,可作为此类热敏微驱动器的理想材料.

参考文献

[1] Carlen E T,Mastrangelo C H.Paraffin actuated surface micromachined valves[C]// Shimoyama Ⅰ.Proceedings of the IEEE international conference on microelectromechanical systems (MEMS).USA:IEEE,2000:381-385.
[2] Liu R L,Bonanno J.Single-use,thermally actuated paraffin valves for microfluidic applications[J].Sensors and Actuators B,2004,98:328-336.
[3] Svedberg M,Nikolajeff F.On the integration of flexible circuit boards with hot embossed thermoplastic structures for actuator purposes[J].Sensors and Actuators A,2006,125:534-47.
[4] 王广振,季林红,温诗铸.电磁驱动热膨胀型微型机械驱动器[J].机械工程学报,2003,39(2):79-83.Wang Guangzhen,Ji Linhong,Wen Shizhu.Thermal expansion type microactuator actuated by induction heating[J].Chinese Journal of Mechanical Engineering,2003,39(2):79-83.
[5] Wang N,Zhang X R,Zhu D S,Gao J W.The investigation of thermal conductivity and energy storage properties of graphite/paraffin composites[J].Journal of Thermal Analysis and Calorimetry,2012,107(3):949-954.
[6] Lee J S,Lucyszyn S.A micromachined refreshable braille cell[J].Journal of Microelectromechanical Systems,2005,14(4):673-682.
[7] Sant H J,Ho T,Gale B K.An in situ heater for a phasechange-material-based actuation system[J].Journal of Micromechanics and Microengineering,2010,20(8):1-7.
[8] Goldschmidtb(o)ing F,Katus P,Geipel A,Woias P.A novel self-heating paraffin membrane micro-actuator[C]// Brand O.Proceedings of the IEEE international conference on microelectromechanical systems (MEMS).USA:IEEE,2008,531-534.
[9] 马庆芳,方荣生.实用热物理性质手册[M].北京:中国农业机械出版社,1986:144-393.Ma Qingfang,Fang Rongsheng.Handbook of practical thermal physical property[M].Beijing:China Machine Press,1986:144-393.
[10] Bilotsky Y,Tomchuk P M.Size effect in electron-lattice energy exchange in small metal particles[J].Surface Science,2006,600(20):4702-4711.
[11] Yin H,Too H P,Chow G M.The effects of particle size and surface coating on the cytotoxicity of nickel ferrite[J].Biomaterials,2005,26(19):5818-5826.
[12] Gatteschi D,Sessoli R.Quantum tunneling of magnetization and related phenomena in molecular materials[J].Angewandte Chemie International Edition,2003,42(3):268-297.
[13] Wu Shuying,Zhu Dongsheng,Zhang Xiurong,Huang Jin.Preparation and melting/freezing characteristics of Cu/paraffin nanofluid as phase-change material (PCM)[J].Energy Fuels,2010,24:1894-1898.
[14] Jegadheeswaran S,Pohekar S D.Exergy analysis of particle dispersed latent heat thermal storage system for solar water heaters[J].Journal of Renewable and Sustainable Energy,2010,2(2):(023105)1-17.
[15] 徐斌,楼白杨,刘春雷,董方亮.新型纳米铜/石蜡/膨胀石墨温敏复合材料的制备及性能[J].材料研究学报,2012,26(1):101-106.Xu Bin,Lou Baiyang,Liu Chunlei,Dong Fangliang.Synthesis and properties of novel nano-copper/paraffin/expanded graphite thermo-sensitive composites[J].Chinese Journal of Materials Research,2012,26(1):101-106.
[16] 施韬,孙伟,王倩楠.凹凸棒土吸附相变储能复合材料制备及其热物理性能表征[J].复合材料学报,2009,26(5):143-147.Shi Tao,Sun Wei,Wang Qiannan.Study on preparation and thermal performance tests of attapulgite-based phase change composites for energy storage[J].Acta Materiae Compositae Sinica,2009,26(5):143-147.
[17] Giavarini C,Pochetti F.Characterization of petroleum products by DSC analysis[J].Journal of Thermal Analysis and Calorimetry,1973,5(1):83-94.
[18] Dirand M,Bouroukba M,Briard A J,Chevallier V,Petitjean D,Corriou J P.Temperatures and enthalpies of (solid + solid) and (solid + liquid) transitions of n-alkanes[J].The Journal of Chemical Thermodynamics,2002,34(8):1255-1277.
[19] Ho C J,Gao J Y.Preparation and thermophysical properties of nanoparticle-in-paraffin emulsion as phase change material[J].International Communications in Heat and Mass Transfer,2009,36(5):467-470.
[20] Sari A,Alkan C,Karaipekli A,(O)nal A.Preparation,characterization and thermal properties of styrene maleic anhydride copolymer (SMA)/fatty acid composites as form stable phase change materials[J].Energy Conversion and Management,2008,49(2):373-380.
[21] Agari Y,Ueda A,Nagai S.Thermal conductivity of polymer composite[J].Journal of Applied Polymer Science,1993,4(9):1625-1634.
[22] Keblinski P,Phillpot S R,Choi U S,Eastman J A.Mechanisms of heat flow in suspensions of nano-sized particles (nanofluids)[J].International Journal of Heat Mass Transfer,2002,45(4):855-863.
[23] 谢华清,奚同庚,王锦昌.纳米流体介质导热机理初探[J].物理学报,2003,52(6):1144-1149.Xie Huaqing,Xi Tonggeng,Wang Jinchang.Study on the mechanism of heat conduction in nanofluid medium[J].Acta Physica Sinica,2003,52(6):1144-1149.
[24] 宣益民,李强.纳米流体能量传递理论与应用[M].北京:科学出版社,2010:98-99.Xuan Yimin,Li Qiang.Energy transfer theory and application of nanofluids[M].Beijing:Science Press,2010:98-99.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%