欢迎登录材料期刊网

材料期刊网

高级检索

采用近空间升华法在FTO玻璃衬底上制备CdZnTe多晶厚膜,并采用扫描电镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)、紫外-可见光谱仪、I-V测试仪等对CdZnTe厚膜的表面形貌、成分、结构以及光电性能进行分析表征。结果表明,所制备的CdZnTe膜均匀致密,随生长时间的延长,晶粒尺寸明显增大;不同厚度的CdZnTe膜均表现出沿(111)晶面的择优生长;CdZnTe厚膜的禁带宽度在1.53~1.56eV之间;电阻率在1010Ω.cm数量级,具有较好的光电响应,试制的薄膜探测器可用作计数型探测器。

Polycrystalline CdZnTe thick films were deposited on glass substrates via close-spaced sublimation (CSS) technique. The morphology, composition, micro-structure, optical and electrical properties of CdZnTe thick films were investigated by SEM, EDS, XRD, UV spectrophotometer and I-V measurements. It is found that the grains are uniform, also, the grain sizes increase significantly with increasing deposition time. The XRD results show that all the thick films possess cubic structure, and tend to grow along the orientation of (111) face. The optical energy gap of all the thick films are in the region of 1.53-1.56eV. The resistivity of the films are 10^10Ω cm orders of magnitude, and have good optical response. It can be used for counting detectors.

参考文献

[1] Alan Owens;A. Peacock .Compound semiconductor radiation detectors[J].Nuclear Instruments and Methods in Physics Research, Section A. Accelerators, Spectrometers, Detectors and Associated Equipment,2004(1/2):18-37.
[2] Schlesinger TE.;Yoon H.;Lee EY.;Brunett BA.;Franks L. James RB.;Toney JE. .Cadmium zinc telluride and its use as a nuclear radiation detector material [Review][J].Materials Science & Engineering, R. Reports: A Review Journal,2001(4/5):103-189.
[3] Sellin PJ .Thick film compound semiconductors for X-ray imaging applications[J].Nuclear Instruments and Methods in Physics Research, Section A. Accelerators, Spectrometers, Detectors and Associated Equipment,2006(1):1-8.
[4] Reno J L;Jones E D .Determination of the dependence of band-gap energy on composition for Cd1-xZnxTe[J].Physical Review B:Condensed Matter,1992,3(05):1440-1442.
[5] Kim BJ.;Wang JF.;Lalev GM.;Park YG.;Shindo D.;Isshiki M. .Growth and strain investigation of Cd0.96Zn0.04Te/GaAs by hot-wall epitaxy[J].Materials Chemistry and Physics,2003(3):581-585.
[6] Bansal A;Rajaram P .Electrochemical growth of CdZnTe thin films[J].Materials Letters,2005,59:3666-3671.
[7] Kwon JS.;Shin DY.;Choi IS.;Kim HS.;Kim KH.;Kim SU.;Park MJ. .Growth of polycrystalline Cd0.8Zn0.2Te thick films for X-ray detectors[J].Physica status solidi, B. Basic research,2002(2):1097-1101.
[8] Okamoto T;Kono M;Jibiki T;Imai K;Kishihara H;Kaino M;Tokuda S;Sato T .Close-spaced sublimation growth and characterization of polycrystalline Cd1-xZnxTe thick films for flat-panel X-ray detectors[J].Japanese journal of applied physics,2008(4 Pt.1):2079-2082.
[9] SATOSHI TOKUDA;HIROYUKI KISHIHARA;SUSUMU ADACHI;TOSHIYUKI SATO .Preparation and characterization of polycrystalline CdZnTe films for large-area, high-sensitivity X-ray detectors[J].Journal of Materials Science. Materials in Electronics,2004(1):1-8.
[10] 李锦,郑毓峰,徐金宝,孙严飞,陈树义.CdTe薄膜的制备方法比较及其结构性能研究[J].功能材料,2002(05):508-510.
[11] Prabakar K;Venkatachalam S;Jeyachandran YL;Narayandass SK;Mangalaraj D .Optical constants of vacuum evaporated Cd0.2Zn0.8Te thin films[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2004(1):1-12.
[12] X. Mathew .Band gap of CdTe thin films-The dependence on temperature[J].Journal of Materials Science Letters,2002(7):529-531.
[13] [OL].http://www,photoeff.com.provides.tables/graphs/data on coefficients
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%