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针对100 μm和200 μm厚的2种超薄微制品,采用单因素实验,对等规聚丙烯微注塑制品的形态结构进行研究,并分析注射速度对超薄微注塑制品形态结构的影响.研究结果表明,超薄微注塑制品中呈现出2种典型的形态结构,200μn微制品厚度方向呈现出纯剪切层的无芯结构,剪切层内为明显的Shish-Kebab结构;100μtm厚微制品内部形态为含大比例柱晶结构的皮芯结构;广角X射线衍射结果显示无芯结构内形态沿流动方向呈现高度取向,且β晶含量微弱.含柱晶层皮芯结构的取向也较明显,且结构中有明显β晶存在.注射速度对超薄微注塑制品的形态结构、结晶度和取向度都有重要的影响,存在临界注射速度,当注射速度小于该临界速度时,制品内部结晶度、取向度随着注射速度的提高而提高.

参考文献

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