基于平衡常数法建立生物质水蒸气汽化的热力学平衡模型.模型计算结果表明:生物质水蒸气汽化产气组分趋于稳定的汽化条件为845～950℃、S/B(水蒸气质量与生物质质量之比)为1.5～2.0(g/g),900℃、S/B为1.64时合成气(CO+H2)产量最高,为73.15％.利用高温铜渣显热作为生物质水蒸气汽化吸热反应的外热源,计算不同汽化温度下铜渣的热焓和余热利用率.计算结果表明:汽化温度在720～950℃范围内,铜渣余热利用率为25.28％～60.04％;最优汽化工况下,铜渣余热利用率为31.66％,系统能量转化率高达48％.
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