介绍了LED散热基片(金刚石-铜)的基本连接方式,分析金刚石与金属材料的直接焊接和金刚石先表面金属化后再和金属焊接的两种方式,概述了金刚石焊接检测技术并提出了金刚石钎焊存在的相关问题。对依次镀钛、银薄膜的金刚石块和镀银铜基片在500℃进行真空焊接研究,对焊接前后的样品进行XRD衍射分析得知:镀钛银的金刚石薄膜在焊接时,钛金属与金刚石表面的碳原子形成了碳化钛。
The basic structure of Light Emitting Diode(LED)was introduced. The direct welding between diamond and metal, and the welding between surface metalized diamond and metal were analyzed. Detecting techniques in diamond welding were introduced and the problems about diamond welding to metal were proposed. Vacuum-welding at 500 ℃ of diamond with deposited titanium,silver to copper with a buffer layer of silver was researched,and the components of welding interface were investigated using X-ray diffraction(XRD). The results show that titanium reacts with carbon in welding process,and then produces titanium carbide(TiC).
参考文献
[1] | 王晓明,郭伟玲,高国,沈光地.LED--新一代照明光源[J].现代显示,2005(07):15-19,41. |
[2] | 陈明祥,罗小兵,马泽涛,刘胜.大功率白光LED封装设计与研究进展[J].半导体光电,2006(06):653-658. |
[3] | 刘一兵,黄新民,刘国华.基于功率型LED散热技术的研究[J].照明工程学报,2008(01):69-73. |
[4] | 顾长志,金曾孙,吕宪义,邹广田,张纪法,方容川.高导热金刚石薄膜的研究[J].物理学报,1997(10):1984-1989. |
[5] | Gu Changzhi;Jin Zengsun;Lu Xianyi et al.The deposition of diamond film with high thermal conductivity[J].Thin Solid Films,1997,311:124-127. |
[6] | Qiuping Wei;M.N.R. Ashfold;Z.M. Yu;Li Ma;D.F. Yin .Fabrication of high density, adherent films of five-fold symmetric diamond crystals by hot filament chemical vapour deposition[J].Journal of Crystal Growth,2011(1):72-76. |
[7] | Qiuping Wei;Michael N.R. Ashfold;Yu. A. Mankelevich .Diamond growth on WC-Co substrates by hot filament chemical vapor deposition: Effect of filament-substrate separation[J].Diamond and Related Materials,2011(5/6):641-650. |
[8] | Wei, Q.;Yu, Z.M.;Ashfold, M.N.R.;Chen, Z.;Wang, L.;Ma, L. .Effects of thickness and cycle parameters on fretting wear behavior of CVD diamond coatings on steel substrates[J].Surface & Coatings Technology,2010(1):158-167. |
[9] | Vedawyas M.;Kumar A.;Sivananthan G. .Textured polycrystalline diamond films on Cu metal substrates by hot filament chemical vapor deposition[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2000(1):16-21. |
[10] | 汤凤林,杨凯华,段隆臣.金刚石表面金属化(镀膜)的试验研究[J].探矿工程,2000(05):14-16,24. |
[11] | 戴达煌;周克崧.金刚石薄膜沉积制备工艺与应用[M].北京:冶金工业出版社,2001:9-10. |
[12] | 田民波;刘德令.薄膜科学与技术手册(下册)[M].北京:机械工业出版社,1991:855. |
[13] | 陈光华;张阳.金刚石薄膜的制备与应用[M].北京:化学工业出版社,2004:77-82. |
[14] | 吴玉会,李国彬,李长龙,王春芳.金刚石表面金属化[J].天津理工学院学报,2002(04):62-65. |
[15] | 冒爱琴,何宜柱,郑翠红,朱伟长,闫勇,李家茂.金刚石表面金属化的研究现状[J].材料导报,2005(02):31-33. |
[16] | 项东,李木森,许斌,刘科高.镀覆金刚石技术的研究进展[J].超硬材料工程,2006(03):44-49. |
[17] | 黄敏,薛屺.金刚石表面金属化与分析表征[J].超硬材料工程,2009(04):54-56. |
[18] | 郭铁峰 .金刚石表面金属化方法[J].金刚石与磨料磨具工程,1997,102(06):3-6. |
[19] | 王明智,钟建平,王艳辉.金刚石表面镀层在电火花烧结过程中的行为及对制品性能的影响[J].粉末冶金技术,2003(04):209-212. |
[20] | 张凤林,付凯旋,王成勇,魏昕.镀覆金属对金刚石性能的影响及其在自蔓延高温中的变化[J].金属热处理,2003(04):33-36. |
[21] | 邱万奇,潘建伟,刘仲武,余红雅,钟喜春,曾德长.电镀铬-金刚石复合过渡层提高金刚石膜/基结合力[J].无机材料学报,2012(02):205-208. |
[22] | 宋月清,康志君,高云.金刚石与金属(或合金)的结合界面分析[J].人工晶体学报,1999(04):404-408. |
[23] | 刘雄飞,李晨辉.镀膜金刚石与结合剂之间的结合状态研究[J].粉末冶金技术,2001(05):262-265. |
[24] | 李耕.金刚石与其表面金属化层及胎体间的热应力分析[J].粉末冶金技术,2002(04):209-214. |
[25] | 裴夤崟,龙伟民,杨继东.钎焊法金刚石表面金属化[J].焊接技术,2010(01):30-33. |
[26] | 郑斌.金刚石薄膜的表面金属化及与Ti薄膜的界面扩散反应的AES研究[J].材料工程,1998(08):16. |
[27] | 方啸虎,刘瑞平,温简杰.钎焊金刚石工具制备的研究现状和进展[J].超硬材料工程,2009(02):28-32. |
[28] | A. Trenker;H. Seidemann .High-vacuum brazing of diamond tools[J].Industrial Diamond Review,2002(592):49-51. |
[29] | 亢世江,陈学广,吕志勇,杨立军.钎焊金刚石膜的试验研究及机理分析[J].焊接学报,2005(02):77-80. |
[30] | 韩国明.焊接工艺理论与技术[M].北京:机械工业出版社,2007:100-124. |
[31] | 关砚聪,陈玉全,姚德明.Ag-Cu-Ti钎料钎焊单晶金刚石磨粒的研究[J].金刚石与磨料磨具工程,2005(03):23-25. |
[32] | Hsieh Yuchan;Lin Shuntian .Microstructural development of Cu-Sn-Ti alloys on graphite[J].Journal of Alloys and Compounds,2008,466:126-132. |
[33] | 孟卫如,徐可为,杨吉军,南俊马.金刚石工具真空钎焊钎料的适应性[J].焊接学报,2004(01):80-82. |
[34] | 亢世江,陈学广,吕志勇,杨立军.钎焊金刚石膜的试验研究及机理分析[J].焊接学报,2005(02):77-80. |
[35] | 李丹,赵密,孙凤莲,孙文山.Ag-Cu-Ti钎料在金刚石表面的润湿状况[J].哈尔滨理工大学学报,2000(03):101-104. |
[36] | 孙凤莲,冯吉才,刘会杰,邱平善,李丹.Ag-Cu-Ti钎料中Ti元素在金刚石界面的特征[J].中国有色金属学报,2001(01):103-106. |
[37] | C.Y. Wang;Y.M. Zhou;F.L. Zhang .Interfacial microstructure and performance of brazed diamond grits with Ni-Cr-P alloy[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2009(1/2):884-888. |
[38] | Klotz, UE;Liu, CL;Khalid, FA;Elsener, HR .Influence of brazing parameters and alloy composition on interface morphology of brazed diamond[J].Materials Science and Engineering. A, Structural Materials: Properties, Microstructure and Processing,2008(1/2):265-270. |
[39] | 张凤林,周玉梅,付凯旋,王成勇.Cr、Ti金属粉改善Ag-Cu-Zn合金对金刚石的钎焊性能研究[J].金刚石与磨料磨具工程,2007(03):22-25. |
[40] | 卢金斌,徐九华.Ag-Cu-Ti钎焊金刚石的界面结构及热应力分析[J].稀有金属材料与工程,2009(04):642-646. |
[41] | 李新宇,高陇桥,刘征,郭辉.CVD金刚石薄膜金属化及其与金属的焊接研究[J].真空电子技术,2010(04):43-46. |
[42] | 邓朝晖,伍俏平,张荣辉,潘占.铜基钎料真空钎焊镀钛金刚石[J].硅酸盐学报,2011(02):343-348. |
[43] | 李以善;刘德镇.焊接结构检测技术[M].北京:化学工业出版社,2009:1-350. |
[44] | 季春锋 .金刚石钎焊质量评价方法研究[D].南京航空航天大学,2009. |
[45] | 韩红芹 .超声无损检测在金属材料焊接中的研究应用[D].吉林:吉林大学机械工程系,2011. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%