采用热浸镀技术在Q235钢板表面制备了镀锌层,研究了浸镀时间对镀锌钢板拉伸性能的影响,通过扫描电镜观察了拉伸断裂后镀层表面、截面和断口处的形貌,分析了镀层的断裂机理.结果表明:与基体相比,Q235钢板热浸镀锌后的抗拉强度和塑性变形能力均下降;镀件抗拉强度的下降是由表面镀锌层强度低于基体的强度造成的;而塑性的下降则是由热浸镀时在基体表面形成的微裂纹造成的;由于残余应力的存在,微裂纹首先在σ-FeZn10层中形成,在受到拉应力时,裂纹沿晶界在σ-FeZn10层中向上扩展,然后在℃-FeZn13层中裂纹沿着FeZn13/Zn的相界面扩展,最后在η-Zn层沿晶界扩展直至镀层发生完全断裂.
参考文献
[1] | ZHANG X G.Corrosion and electrochemistry of zinc[M].New York:Plenum Press,1996 |
[2] | MARDER A .The metallurgy of zinc-coated steel[J].Progress in Materials Science,2000,45:191-271. |
[3] | 许乔瑜,曾秋红.热浸镀锌合金镀层的研究进展[J].材料导报,2008(12):52-55. |
[4] | 孔纲,卢锦堂,许乔瑜.热浸镀锌合金技术的发展与应用[J].腐蚀科学与防护技术,2005(04):259-261. |
[5] | 于升学,夏原,姚枚.稀土铈对热浸镀铝层组织和性能的影响[J].机械工程材料,2006(06):77-79. |
[6] | 陆宇衡,黄彩敏,肖罡,上官琪,曾建民.热浸镀Al-43%Zn-1.6%Si合金新工艺及其镀层的组织和性能[J].机械工程材料,2010(12):25-28. |
[7] | JORDAN C;MARDER A .Fe-Zn phase formation in interstitial-free steels hot-dip galvanized at 450℃:part Ⅰ 0.00 wt%Al-Zn baths[J].Journal of Materials Science,1997,32:5593-5602. |
[8] | Lee KK;Lee IH;Lee CR;Ahn HK .In-situ observation in a scanning electron microscope on the exfoliation behavior of galvannealed Zn-Fe coating layers[J].Surface & Coatings Technology,2007(14):6261-6266. |
[9] | Ploypech, S.;Boonyongmaneerat, Y.;Jearanaisilawong, P. .Crack initiation and propagation of galvanized coatings hot-dipped at 450°C under bending loads[J].Surface & Coatings Technology,2012(18):3758-3763. |
[10] | PARISOT R;FOREST S;PINEAU A et al.Deformation and damage mechanisms of zinc coatings on hot-dip galvanized steel sheets:part Ⅱ.damage modes[J].Metallurgical and Materials Transactions:A,2004,35:813-823. |
[11] | Reumont G.;Iost A.;Foct J.;Vogt JB. .The effects of an Fe-Zn intermetallic-containing coating on the stress corrosion cracking behavior of a hot-dip galvanized steel[J].Surface & Coatings Technology,2001(2/3):265-271. |
[12] | A. GALLEGO;J.F. GIL;J.M. VICO .Coating adherence in galvanized steel assessed by acoustic emission wavelet analysis[J].Scripta materialia,2005(10):1069-1074. |
[13] | 王银军,刘学伟,彭琼瑶,彭雄奇.DC51D+AZ热镀铝锌薄板弯曲折痕缺陷的形成原因[J].机械工程材料,2012(12):98-100,104. |
[14] | 袁训华,张启富.热镀锌合金化镀层裂纹产生及扩展的原位观察[J].钢铁研究学报,2011(07):43-47. |
[15] | 袁训华,刘昕,陈斌锴,江社明,张启富.合金化镀层拉伸过程中裂纹产生及扩展的原位观察[J].金属热处理,2010(10):11-15. |
[16] | Song, G.-M.;Sloof, W.G. .Effect of alloying element segregation on the work of adhesion of metallic coating on metallic substrate: Application to zinc coatings on steel substrates[J].Surface & Coatings Technology,2011(19):4632-4639. |
[17] | G.M. Song;T. Vystavel;N. van der Pers .Relation between microstructure and adhesion of hot dip galvanized zinc coatings on dual phase steel[J].Acta materialia,2012(6/7):2973-2981. |
[18] | PANAGOPOULOS C N;GEORGIOU E P;AGATHOCLEOUS P E et al.Mechanical behavior of Zn-Fe alloy coated mild steel[J].Materials and Design,2009,30:4267-4272. |
[19] | LIDE D R.CRC Handbook of Chemistry and Physics[M].CRC Press,2003 |
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