稀土氟化物纳米材料由于其特殊的光、电、磁性质,在光学器件、显示、生物标记、光学晶体等领域有着广泛的应用,已成为材料科学领域的研究热点之一.目前研究者已用沉淀法、微乳液法、水热与溶剂热法、溶胶-凝胶法、微波法、超声波法、前驱体热解法、静电纺丝法等成功地制备出了纳米颗粒、纳米线、纳米膜、多面体纳米晶、复合结构纳米晶、核壳结构纳米材料等稀土氟化物纳米材料.本文总结了上述几种制备方法的研究进展,讨论了其优缺点,并结合课题组在稀土氟化物纳米材料制备方面的工作,对纳米稀土氟化物制备方法的发展方向做了展望.
参考文献
| [1] | Zheng-Guang Yan;Chun-Hua Yan .Controlled synthesis of rare earth nanostructures[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2008(42):5046-5059. |
| [2] | Kim C.H.;Kwon I.E. .Phosphors for plasma display panels[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1):33-39. |
| [3] | Moine B;Bizarri G .Rare-earth doped phosphors:oldies or goldies[J].Materials Science and Engineering B,2003,105(1-3):2. |
| [4] | Hsiu-Chih Yeh;Rong-Ho Lee;Li-Hsin Chan .Synthesis, Properties, and Applications of Tetraphenylmethane-Based Molecular Materials for Light-Emitting Devices[J].Chemistry of Materials,2001(9):2788-2796. |
| [5] | Aivo Lepland;Gustaf Arrhenius;David Cornell .Apatite in early Arehean Isua supracrus-tal rocks,southern West Greenland:its origin,association with graphite,and potential as a biomarker[J].Precambrian Research,2002,118(3-4):221. |
| [6] | Idris NM;Li Z;Ye L .Tracking transplanted cells in live animal using upconversion fluorescent nanoparticles.[J].Biomaterials,2009(28):5104-5113. |
| [7] | Wang X;Shan GY;Chao KF;Zhang YL;Liu RL;Feng LY;Zeng QH;Sun YJ;Liu YC;Kong XG .Effects of Er3+ concentration on UV/blue upconverted luminescence and a three-photon process in the cubic nanocrystalline Y2O3 : Er3+[J].Materials Chemistry and Physics,2006(2/3):370-374. |
| [8] | Orlovskii YV.;Basiev TT.;Orlovskaya EO.;Privis YS.;Fedorov VV.;Mirov SB. .Direct nanosecond Nd -> Ce nonradiative energy transfer in cerium trifluoride laser crystals[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2003(3):211-218. |
| [9] | Kiyoshi Shimamura;Encarnacion G. Villora;Satoshi Nakakita;Martin Nikl;Noboru Ichinose .Growth and scintillation characteristics of CeF_3, PrF_3 and NdF_3 single crystals[J].Journal of Crystal Growth,2004(1/3):208-215. |
| [10] | 王亚军,刘前,索全伶,郝东升,郭锋.稀土氟化物的沉淀方法及组成研究[J].稀土,2000(01):14-18. |
| [11] | Miao Wang;Qing-Li Huang;Jian-Ming Hong;Xue-Tai Chen .Controlled synthesis of different morphological YF_3 crystalline particles at room temperature[J].Materials Letters,2007(10):1960-1963. |
| [12] | T.Grzyb,S.Lis.Photoluminescent properties of LaF3:Eu3+ and GdF3:Eu3+ nanoparticles prepared by co-precipitation method[J].稀土学报(英文版),2009(04):588-592. |
| [13] | Pi Daibo;Wang Feng;Fan Xianping;Wang Minquan Zhang Yong .Luminescence behavior of Eu3+ doped LaF3 nanoparticles[J].Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,2005,61(11-12):2455. |
| [14] | 刘桂霞,苏瑞相,王进贤,董相廷.棒状LaF3：Eu3+纳米晶的制备与发光性能[J].高等学校化学学报,2008(03):461-464. |
| [15] | 刘桂霞,王进贤,苏瑞相,董相廷.SiO2/LaF3：Eu3+核壳结构发光粒子的制备与表征[J].化学学报,2008(19):2170-2173. |
| [16] | Guo Fuqiang;Li Hongfei .Synthesis of mesoperous YF3 nanoflowers via solvent extraction route[J].Materials Science and Engineering B,2009,163(02):134. |
| [17] | Jan W. Stouwdam;Frank C. J. M. van Veggel .Near-infrared Emission of Redispersible Er~(3+), Nd~(3+), and Ho~(3+) Doped LaF_3 Nanoparticles[J].Nano letters,2002(7):733-737. |
| [18] | Jianshe Wang;Shuhui Bo;Limei Song .One-step synthesis of highly water-soluble LaF_3:Ln~(3+) nanocrystals in methanol without using any ligands[J].Nanotechnology,2007(46):465606(1-6). |
| [19] | Feng Wang;Yong Zhang;Xianping Fan .One-pot synthesis of chitosan/LaF_3:Eu~(3+) nanocrystals for bio-applications[J].Nanotechnology,2006(5):1527-1532. |
| [20] | Lu Xiaojing;Peng Yin .The fitst rare-earth fluoride one-dimensional nanostructures:template synthesis of LnF3(Ln=Eu,La)nanotubes[J].Frontiers of Chemistry in China,2010,5(01):76. |
| [21] | 连洪洲,石春山.用于纳米粒子合成的微乳液[J].化学通报,2004(05):333-340,348. |
| [22] | 闫景辉,张鸣,连洪州,叶泽人,石春山.微乳液体系相图的研究及其在纳米氟化物制备中的应用[J].高等学校化学学报,2005(06):1006-1009. |
| [23] | 闫景辉,宋丽红,李中田,张海燕,张挥球.微乳液法制备YF3：Er纳米材料[J].无机化学学报,2007(08):1432-1434. |
| [24] | Lian H;Zhang M;Liu J;Ye Z;Yan J;Shi C .Synthesis and spectral properties of lutetium-doped CeF3 nanoparticles[J].Chemical Physics Letters,2004(4-6):362-365. |
| [25] | Wang Guofeng;Qin Weiping;Wei Guodong;Zhu Peifen Kim Ryongjin .Size-dependent upconversion luminescence in YF3:Yb3+/Tm3+ nanobundles[J].Journal of Fluorine Chemistry,2009,129(11):1110. |
| [26] | Guofeng Wang;Weiping Qin;Guodong Wei .Synthesis and upconversion luminescence properties of YF3:Yb~(3+)/Tm~(3+) octahedral nanocrystals[J].Journal of Fluorine Chemistry,2009(2):158-161. |
| [27] | Qiu Sunqing;Dong Junxiu;Chen Guoxu .Synthesis of CeF3 nanoparticles from water-in-oil microemulsions[J].Powder Technology,2000,113(1-2):9. |
| [28] | Zhang H;Li HF;Li DQ;Meng SL .Synthesis and characterization of ultrafine CeF3 nanoparticles modified by catanionic surfactant via a reverse micelles route[J].Journal of Colloid and Interface Science,2006(2):509-515. |
| [29] | Masih Darbandi;Thomas Nann .One-pot synthesis of YF_3@silica core/shell nanoparticles[J].Chemical communications,2006(7):776-778. |
| [30] | Lemyre, JL;Ritcey, AM .Synthesis of lanthanide fluoride nanoparticles of varying shape and size[J].Chemistry of Materials,2005(11):3040-3043. |
| [31] | Zhang Yue;Li Yadong .Red photoluminescence properties and crystal structure of sodium earth oxyborate[J].Journal of Alloys and Compounds,2004,307(1-2):99. |
| [32] | Chen Yan;Yuan Hongming;Tian Ge;Zhang Ganghua Feng Shouhua .Hydrothermal synthesis and magnetic properties of RMn2O5(R=La,Pr,Nd,Tb,Bi)and LaMn2O5+δ[J].Journal of Solid State Chemistry,2007,180(04):1340. |
| [33] | 张颂 .特殊形貌稀土纳米发光材料的合成及其性能研究[D].长春理工大学,2009. |
| [34] | Zhao Chunyan;Feng Shouhua;Xu Ruren;Shi Chunsan Ni Jiazuan.Hydrothermal synthesis and lanthanide doping of complex fluorides,LiYF4,KYF4 and BaBeF4 under mild conditions[J].Chemical Communications,1997(10):945. |
| [35] | Wang X;Zhuang J;Peng Q;Li YD .Hydrothermal synthesis of rare-earth fluoride nanocrystals[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2006(17):6661-6665. |
| [36] | Yang Xiaofeng;Dong Xianting;Wang Jinxian;Liu Guixia .Glycine-assisted hydrothermal synthesis of single-crystalline LaF3:Eu3+ hexagonal nanoplates[J].Journal of Alloys and Compounds,2009,487(1-2):298. |
| [37] | 李霞 .稀土氟化物纳米发光材料的制备及性能研究[D].长春理工大学,2010. |
| [38] | Shijin Wang;Hualan Xu;Xiangshu Chen;Shengliang Zhong;Jianwen Jiang;Yixiang Huang;Shangping Wang;Rong Xu .Solvothermal Synthesis Of Disk-like Yf_3 Superstructures[J].Journal of Crystal Growth,2008(22):4697-4700. |
| [39] | 张茂峰,孟建新,刘应亮,满石清.LaF3：Eu3+纳米粒子的水热法制备及发光性质研究[J].中国稀土学报,2005(05):564-567. |
| [40] | Shengliang Zhong;Shijin Wang;Hualan Xu;Chungen Li;Yixiang Huang;Shangping Wang;Rong Xu .Facile Synthesis Of Water-soluble Yf_3 And Yf_3: Ln~(3+) Nanocrystals[J].Materials Letters,2009(5):530-532. |
| [41] | Hao-Xiang Zhong;Jian-Ming Hong;Xiao-Feng Cao;Xue-Tai Chen;Zi-Ling Xue .Ionic-liquid-assisted Synthesis Of Yf_3 With Different Crystalline Phases And Morphologies[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2009(3):623-628. |
| [42] | 王淼,孙同明,石玉军.不同形貌YF_3微米晶的水热合成及YF_3：Eu~（3+）荧光性质[J].无机化学学报,2010(02):274-278. |
| [43] | Huang Bin;Liu Zheng;Hong Jianming;Chen Xuetai,Xue Ziling,You Xiaozeng .Solvothermal growth and characterization of one-dimensional-nanostructured materials NH4 LnF4 and LnF3 (Ln=Nd.Sm,Eu,Gd and Tb)[J].Journal of Crystal Growth,2005,276(34):613. |
| [44] | Xu, ZH;Li, CX;Yang, PP;Zhang, CM;Huang, SS;Lin, J .Rare Earth Fluorides Nanowires/Nanorods Derived from Hydroxides: Hydrothermal Synthesis and Luminescence Properties[J].Crystal growth & design,2009(11):4752-4758. |
| [45] | Renata Reisfeld;Tsiala Saraidarov .Innovative materials based on sol-gel technology[J].Optical materials,2006(1/2):64-70. |
| [46] | Agrawal Anoop;Cronin John P;Zhang Raymond .Review of solid state electrochromic coatings produced using sol-gel techniques[J].Solar Energy Materials and Solar Cells,1993,31(01):9. |
| [47] | Shinobu Fujihara;Kazuaki Tokumo .Chemical processing for inorganic fluoride and oxyfluoride materials having optical functions[J].Journal of Fluorine Chemistry,2009(12):1106-1110. |
| [48] | Fujihara S;Koji S;Kimura T .Structure and optical properties of (Gd,Eu)F-3-nanocrystallized sol-gel silica films[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2004(8):1331-1335. |
| [49] | 张先如,徐政.微波技术在材料化学中的原理及其应用进展[J].辐射研究与辐射工艺学报,2005(04):196-200. |
| [50] | Thostenson E.T.;Chou T.-W. .Microwave processing:fundamentals and applications[J].Composites, Part A. Applied science and manufacturing,1999(9):1055-1071. |
| [51] | 涂华民,张秀凤,张迈生.轻稀土氟化物的微波固相快速合成法[J].稀有金属,2004(05):875-879. |
| [52] | 张秀凤,涂华民,张迈生,林木良.纳米氟化铈（Ⅲ）的微波固相氧化还原合成法[J].材料导报,2003(01):78-80. |
| [53] | Lin Ma;Wei-Xiang Chen;Yi-Fan Zheng;Jie Zhao;Zhude Xu .Microwave-assisted hydrothermal synthesis and characterizations of PrF_3 hollow nanoparticles[J].Materials Letters,2007(13):2765-2768. |
| [54] | Ni, YH;Li, GY;Hong, JM .Ultrasonic assisted synthesis, characterization and influence factors of monodispersed dumbbell-like YF3 nanostructures[J].Ultrasonics sonochemistry,2010(3):509-514. |
| [55] | Yan RX;Li YD .Down/Up conversion in Ln(3+)-doped YF3 nanocrystals[J].Advanced functional materials,2005(5):763-770. |
| [56] | Wang, ZL;Quan, ZW;Jia, PY;Lin, CK;Luo, Y;Chen, Y;Fang, J;Zhou, W;O'Connor, CJ;Lin, J .Facile synthesis and photoluminescent properties of redispersible CeF3, CeF3 : Tb3+, and CeF3 : Tb3+/LaF3 (core/shell) nanoparticles[J].Chemistry of Materials,2006(8):2030-2037. |
| [57] | Kong DY;Wang ZL;Lin CK;Quan ZW;Li YY;Li CX;Lin J .Biofunctionalization of CeF3 : Tb3+ nanoparticles[J].Nanotechnology,2007(7):75601-1-75601-7-0. |
| [58] | WANG Zhenling,LI Min,WANG Chang,CHANG Jiazhong,SHI Hengzhen,LIN Jun.Photoluminescence properties of LaF3: Eu3+ nanoparticles prepared byrefluxing method[J].稀土学报（英文版）,2009(01):33-37. |
| [59] | Yang Wei;Fengqi Lu;Xinrong Zhang .Polyol-mediated synthesis of water-soluble LaF_3:Yb,Er upconversion fluorescent nanocrystals[J].Materials Letters,2007(6):1337-1340. |
| [60] | Yu Wang;Langping Tu;Junwei Zhao .Upconversion Luminescence of β-NaYF4: Yb~(3+), Er~(3+)@β-NaYF4 Core/Shell Nanoparticles: Excitation Power Density and Surface Dependence[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(17):7164-7169. |
| [61] | Zhuravleva N G;Sapoletova N A;Eliseev A A;Lukashin A V Tretyakov Yu D Kynast U .The synthesis of monodisperse trioctylphosphine oxide-capped EuF3 nanoparticles[J].Optical Materials,2006,28(6-7):606. |
| [62] | John-Christopher Boyer;John A.Capobianco;Louis A.Cuccia;Fiorenzo Vetrone .Synthesis of Colloidal Upconverting NaYF_4 Nanocrystals Doped with Er~(3+),Yb~(3+) and Tm~(3+),Yb~(3+) via Thermal Decomposition of Lanthanide Trifluoroacetate Precursors[J].Journal of the American Chemical Society,2006(23):7444-7445. |
| [63] | Sun X;Zhang YW;Du YP;Yan ZG;Si R;You LP;Yan CH .From trifluoroacetate complex precursors to monodisperse rare-earth fluoride and oxyfluoride nanocrystals with diverse shapes through controlled fluorination in solution phase[J].Chemistry: A European journal,2007(8):2320-2332. |
| [64] | Andreas Greiner;Joachim H. Wendorff .Electrospinning: A Fascinating Method for the Preparation of Ultrathin Fibers[J].Angewandte Chemie,2007(30):5670-5703. |
| [65] | Koski A;Yim K;Shivkumar S .Effect of molecular weight on fibrous PVA produced by electrospinning[J].Materials Letters,2004,58(3-4):493. |
| [66] | Dong B;Song HW;Yu HQ;Zhang H;Qin RF;Bai X;Pan GH;Lu SZ;Wang F;Fan LB .Upconversion properties, of Ln(3+) doped NaYF4/polymer composite fibers prepared by electrospinning[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(5):1435-1440. |
| [67] | 周博秘 .静电纺丝法制备稀土氟化物纳米纤维与表征[D].长春理工大学,2008. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%