聚合物质子传导电解质膜(或称质子交换膜)作为质子交换膜燃料电池(PEMFC)的电解质和隔膜,其性能在很大程度上决定了PEMFC的性能.本文对目前已商业化的全氟磺酸膜和部分氟化膜以及目前正在大力开发的非氟化质子交换膜的状况及研究进展进行了介绍,并讨论了这些质子交换膜的结构、制备、性能以及它们在燃料电池中的应用.
参考文献
[1] | Watkins D S;Blomen L J M J;Mugerwa M N.Fuel Cell Systems[M].Plenum Press, N.Y,1993 |
[2] | Prater K B .[J].Journal of Power Sources,1990,29:239. |
[3] | 衣宝廉.燃料电池[M].北京:化学工业出版社,2000 |
[4] | Savadogo O .[J].New Materials for Electrochemical Systems,1998,1:47. |
[5] | Tant M R.[M].Ionomers Van Nostrand Reinhold Co Inc , N Y,1997 |
[6] | Rikukawa M;Sanui K .[J].Progress in Polymer Science,2000,25:1463. |
[7] | Houblod H G .[J].Electrochimica Acta,2001,46:1559. |
[8] | Zawodzinski T A Jr;Derouin C;Radziski S et al.[J].Journal of the Electrochemical Society,1993,140:1041. |
[9] | Djilali N;Lu D M;Intern .[J].Thermal Science and Engineering,2002,41(01):29. |
[10] | Rajalakshmi N;Sridhar P;Dhathathreyan K S .[J].Journal of Power Sources,2002,109(02):452. |
[11] | Yang T H;Yoon Y G;Kim C S .[J].Journal of Power Sources,2002,106(1-2):328. |
[12] | 于景荣,邢丹敏,刘富强,刘建国,衣宝廉.燃料电池用质子交换膜的研究进展[J].电化学,2001(04):385-395. |
[13] | Penner R M;Martin C R .[J].Journal of the Electrochemical Society,1985,132:514. |
[14] | Liu C;Martin C R .[J].Journal of the Electrochemical Society,1990,137:510. |
[15] | Wei J;Stone C;Steck A E .[P].US Patent,5 422 411,1995. |
[16] | Adjemian K T;Lee S J;Srinivasan S et al.[J].Journal of the Electrochemical Society,2002,149(03):A256. |
[17] | Aparicio M;Damay F;Klein L C .[J].Solid-State Science and Technology,2003,26(1-3):1055. |
[18] | Wu H;Wang Y X;Wang S C .[J].Acta Polymerica Sinica,2002,4:540. |
[19] | Gao Y.;Robertson GP.;Guiver MD.;Jian XG. .Synthesis and characterization of sulfonated poly(phthalazinone ether ketone) for proton exchange membrane materials[J].Journal of Polymer Science, Part A. Polymer Chemistry,2003(4):497-507. |
[20] | Lufrano F.;Patti A.;Passalacqua E.;Squadrito G. .Sulfonated polysulfone as promising membranes for polymer electrolyte fuel cells[J].Journal of Applied Polymer Science,2000(6):1250-1256. |
[21] | Feng W;Michael H;Qing J et al.[J].Macromolecular Symposia,2001,175:387. |
[22] | Tchicaya B L;Jones D J;Roziere J .[J].Fuel Cells,2002,2(01):40. |
[23] | Lafitte B.;Karlsson LE.;Jannasch P. .Sulfophenylation of polysulfones for proton-conducting fuel cell membranes[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2002(15):896-900. |
[24] | Savadogo O;Xing B .[J].New Materials for Electrochemical Systems,2000,3(04):343. |
[25] | Uchida H;Yamada Y;Asano N et al.[J].Electrochemistry,2002,70(12):943. |
[26] | Xing B;Savadogo O J .[J].New Materials for Electrochemical Systems,1999,2:95. |
[27] | Samms SR.;Savinell RF.;Wasmus S. .THERMAL STABILITY OF PROTON CONDUCTING ACID DOPED POLYBENZIMIDAZOLE IN SIMULATED FUEL CELL ENVIRONMENTS[J].Journal of the Electrochemical Society,1996(4):1225-1232. |
[28] | Schechter A.;Savinell RF. .Imidazole and 1-methyl imidazole in phosphoric acid doped polybenzimidazole, electrolyte for fuel cells[J].Solid state ionics,2002(1/2):181-187. |
[29] | Li Q F;Hjuler H A;Bjerrum N J .[J].Electrochimica Acta,2000,45:4219. |
[30] | Gupta P N;Singh K P.[J].Solid State Ionics,1996:319. |
[31] | Kim YS.;Wang F.;Hickner M.;Zawodzinski TA.;McGrath JE. .Fabrication and characterization of heteropolyacid (H3PW12O40)/directly polymerized sulfonated poly(arylene ether sulfone) copolymer composite membranes for higher temperature fuel cell applications[J].Journal of Membrane Science,2003(1/2):263-282. |
[32] | Baradie B;Poinsignon C;Sanchez J Y et al.[J].Journal of Power Sources,1998,74:8. |
[33] | Nakajima H.;Honma I. .Proton-conducting hybrid solid electrolytes for intermediate temperature fuel cells[J].Solid state ionics,2002(3/4):607-610. |
[34] | Zaidi S M J;Mikhailenko S D;Guiver M A .[J].Journal of Membrane Science,2000,173:17. |
[35] | Ehrenberg S G;Serpico J M;Wnek G E et al.[P].US Patent,5 468 574,1995. |
[36] | Won J;Choi S W;Kang Y S et al.[J].Journal of Membrane Science,2003,214(02):245. |
[37] | Sloan J M;Elabd Y;Napadensky E .[J].Engineers,2002,60(03):3939. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%