Spinel NiZn ferrite thin films were prepared on glass substrates by spray plating method. Adding cetyltrimethylammoniumchloride (CTAC), adsorptive energy of substrate surface increased, and smooth surface and uniform columnar film structures were observed. The optimum reaction temperature up to 85℃ and pH up to 7.5 were obtained. As the solution pH value increases from 6.5 to 7.5, the film saturation magnetization increases to 2.48×105 A/m and electric resistivity to 5.6×102 mΩ•cm. The high real part of complex permeability μ′ up to 36.1 and the imaginary part μ′′ up to 53.2 for NiZn ferrite film at 500 MHz were achieved, and higher magnetic resonance at 508 MHz was observed. As the ferrite plate thickness is 50 μm, the attenuating characteristics for reflection loss ≤-0.8 dB can be obtained in the wide frequency ranging from 0.5 to 2.7 GHz. The μ′′ of thin film has values higher than 20 at the frequencies between 0.5 and 2 GHz, and the thin film can be applied as shielding material in GHz range.
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