欢迎登录材料期刊网

材料期刊网

高级检索

尖晶石型钛酸锂作为锂离子电池负极材料,在充放电过程中其晶体结构不会发生改变,不可逆容量损失较小,被称为“零应变”材料.它具有循环寿命长、充电过程快、安全性高等特性,符合下一代锂离子电池的要求.本文综述了钛酸锂负极材料的研究近况,着重阐述了纳米化、引入导电碳、金属元素掺杂、阴离子掺杂以及复合改性等方法对钛酸锂进行改性,探究对其电性能的影响和以后的发展方向.

参考文献

[1] Li JR;Tang ZL;Zhang ZT .Controllable formation and electrochemical properties of one-dimensional nanostructured spinel Li4Ti5O12[J].Electrochemistry communications,2005(9):894-899.
[2] Jizhang Chen;Li Yang;Shaohua Fang;Shin-ichi Hirano;Kazuhiro Tachibana .Synthesis of hierarchical mesoporous nest-like Li_4Ti_5O_(12) for high-rate lithium ion batteries[J].Journal of Power Sources,2012(Feb.15):59-66.
[3] Hun-Gi Jung;Junghoon Kim;Bruno Scrosati;Yang-Kook Sun .Micron-sized, carbon-coated Li_4Ti_5O_(12) as high power anode material for advanced lithium batteries[J].Journal of Power Sources,2011(18):7763-7766.
[4] 何则强,刘文萍,熊利芝,陈上,吴显明,樊绍兵.锂离子电池用Li4Ti5O12-碳复合材料的制备与电化学性能[J].无机化学学报,2007(04):733-737.
[5] Junjie Huang;Zhiyu Jiang .The preparation and characterization of Li{sub}4Ti{sub}5O{sub}12/carbon nano-tubes for lithium ion battery[J].Electrochimica Acta,2008(26):7756-7759.
[6] Xing Li;Meizhen Qu;Zuolong Yu .Preparation and electrochemical performance of Li4Ti5O12/graphitized carbon nanotubes composite[J].Solid state ionics,2010(13):635-639.
[7] C.H.Chen;J.T.Vaughey;A.N.Jansen;D.W.Dees;A.J.Kahaian;T.Goacher;M.M.Thackeray .Studies of Mg-Substituted Li_(4-x)Mg_xTi_5O_(12) Spinel Electrodes (0<=x<=1) for Lithium Batteries[J].Journal of the Electrochemical Society,2001(1):A102-A104.
[8] Cheng Chao Li;Qiu Hong Li;Li Bao Chen .A Facile Titanium Glycolate Precursor Route to Mesoporous Au/Li4Ti5O_(12 )Spheres for High-Rate Lithium-Ion Batteries[J].ACS applied materials & interfaces,2012(3):1233-1238.
[9] Yan-Jing Hao;Qiong-Yu Lai;Yuan-Duan Chen .In situ deposition method preparation of Li_4Ti_5O_(12)-SnO_2 composite materials for lithium ion batteries[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2008(1/2):404-409.
[10] Guan-Nan Zhu;Hai-Jing Liu;Ji-Hua Zhuang;Cong-Xiao Wang;Yong-Gang Wang;Yong-Yao Xia .Carbon-coated nano-sized Li_4Ti_5O_(12) nanoporous micro-sphere as anode material for high-rate lithium-ion batteries[J].Energy & environmental science: EES,2011(10):4016-4022.
[11] Eunae Kcrng;Yoon Seok Jung;Gi-Heon Kim;Jinyoung Chun;Ulrich Wiesner;Anne C. Dillon;Jin Kon Kim;Jinwoo Lee .Highly Improved Rate Capability for a Lithium-Ion Battery Nano-Li_4Ti_5O_(12) Negative Electrode via Carbon-Coated Mesoporous Uniform Pores with a Simple Self-Assembly Method[J].Advanced functional materials,2011(22):4349-4357.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%