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采用超声预分散结合湿球磨法和分散剂复配方式对纳米TiO2进行表面改性处理,研制了均匀稳定分散的纳米TiO2分散液,表征了纳米TiO2改性后的彩涂板涂料及涂层性能。结果表明:纳米TiO2在分散液中的粒径集中分布在60~100 nm范围,可完全吸收330 nm左右的紫外线,对长波紫外线的散射吸收作用强于对短波紫外线的散射吸收。纳米TiO2改性彩涂板涂料用量为w(TiO2)=20%~30%。纳米TiO2改性处理可提高涂层柔韧性和附着力,减少涂层色差变化,降低失光率。涂层抗紫外老化性能优于同类传统彩涂板涂料涂层。

The deconcentration capability of modified nanoTiO2 and ageing resistance of coil coating with nanoTiO2 were studied. The modified nanoTiO2 slurry was obtained by using modifying agents, high speed agitator, ultrasonic dispersion and ball milling. The results showed that nanoTiO2 particles have stronger adsorption of UV (about 330 nm wavelength), and with the increase of nanoTiO2 particles, nanocomposite coatings take on the ascending trend of UV adsorption in some definite fields. The optimal content of nanoTiO2 in coil coating is in the range of 20%-30%. Adding nanoTiO2 enhances the flexibility and reduces the loss of glossiness of coil coatings.

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