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简要说明了太阳能电池对电极的作用,并阐述了铂对电极、镍对电极、聚合物对电极和氧化铜对电极目前的发展状况.碳材料具有良好的导电性能和催化性能,具有制备太阳能电池对电极的基本性质.详细论述了碳材料对电板的制备工艺及其性能参数,与其它对电极相比,碳材料制备的对电极导电性能好,光电转化率可达到铂电极的90%,优于其它材料制备的对电极,而且价格低廉,因此碳材料对电极具有广阔的发展前景.碳材料对电极是染料敏化太阳能电池的重要研究方向.

The function of counter electrode of dye-sensitized solar cells is briefly introduced, and the development of Pt counter electrode, Ni counter electrode, polymer counter electrode and CuO counter electrode are presented.Carbon materials with high electrical properties and good catalytic properties may be used to prepare counter electrode of dye-sensitized solar cells. In this paper, the preparing processes and performance parameters of carbon materials counter electrode are indicated in detail. In compared with other counter electrodes, it is found that the counter electrodes prepared by carbon materials are high electrical conductivity,and its photo-electron conversion efficiency is up to 90% of those of Pt electrodes. Furthermore, counter electrodes from carbon are low in price, which will contribute to potential development. In present,carbon counter electrodes are the important research subject in the field of dye-sensitized solar cells.

参考文献

[1] Ishiwaki T;Inoue H;Makishima A .Transport and interfacial transfer of electrons in dye-sensitized nanocrystalline solar cells[J].Journal of Materials Science,2000,35:1669.
[2] O'Regan B;Gratzel M .A low-cost,high-efficiency solar cell based on dye-sensitized colloidal TiO2 films[J].NATURE,1999,353:737.
[3] Green M A et al.Solar cell efficiency tables(version23)[J].Prog Photovolt:Res Appl,2004,12:55.
[4] Gratzel M .Photovoltaic performance and long-term stability of dye-sensitized mesocopic cells[J].Cr Chimie,2006,9:578.
[5] 郝三存,吴季怀,林建明,黄昀昉.铂修饰光阴极及其在纳晶太阳能电池中的应用[J].感光科学与光化学,2004(03):175-182.
[6] 范乐庆,吴季怀,黄昀昉,林建明.阴极修饰对染料敏化TiO2太阳能电池性能的改进[J].电子元件与材料,2003(05):1-3.
[7] Anandan Sambandam;Wen Xiaogang;Yang Shile .Room temperature growth of CuO nanorld arrays on copper and their application as a cathode in dye-sensitized solar cells[J].Materials Chemistry and Physics,2005,93:35.
[8] Jonas F;Schrader I .Conductive modifications of polymers with polypyrroles and polythionphenes[J].Synthetic Metals,1991,41(03):831.
[9] Dietrich M;Herinze J;Heywang G et al.Electrochemical and spectroscopic characterization of polyalkylenedioxythiophenes[J].Journal of Electroanalytical Chemistry,1994,369:87.
[10] Groenendaal L;Jonas F;Freitag D et al.Poly(3,4-ethylenedioxythiophene) and its derivatives:past,present,and future[J].Advanced Materials,2000,12(07):481.
[11] Yohannes T.;Inganas O. .Photoelectrochemical studies of the junction between poly[3-(4-octylphenyl)thiophene] and a redox polymer electrolyte[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,1998(2):193-202.
[12] Yasuteru Satito;Wataru Kubo;Takayuki Kitamura et al.I-/I-3 redox reaction behavior on poly(3,4-ethlylenedioxythiophene) counter electrode in dye-sensitized solar cells[J].Journal of Photochemistry and Photobiology A:Chemistry,2004,164:153.
[13] Muto T.Conductive polymerbased couter electrode fabrication for plastic film dye-sensitized cells[A].Sweden,Uppsala,2006:50.
[14] 方晓明,张正国,马婷丽.染料敏化纳米薄膜太阳电池的新型对电极研究[J].太阳能学报,2006(02):111-115.
[15] Seigo Ito et al.High-efficiency(7.2%) flexible dye-sensitized solar cells with Ti-metal substrate for nanocrystallineTiO2 photoanode[J].Chemistry Communications,2006,38:4004.
[16] Wroblowa H S;Saunders A .Flow-through eletrodes:Ⅱ.The I-3/I-redox couple[J].Journal of Electroanalytical Chemistry,1973,42(03):329.
[17] Tarasevich M R.Mo-dern aspects of electrochemistry[M].New York:Plenum Press,1989:295.
[18] Ralph S;Partric B;Serge L.Carbon molecules and materials[M].UK:Taylor & Francis,2002
[19] 安藤淳平;[日]炭素材料学会;高尚愚.活性炭基础与应用[M].北京:中国材料出版社,1984
[20] 沈曾民.新型碳材料,石墨的制备原理和方法、反应机理、微观结构和性能以及其应用[M].北京:化学工业出版社,2003
[21] 成会明.纳米碳管制备、结构、物性及应用[M].北京:化学工业出版社,2002
[22] Kay A.;Gratzel M. .LOW COST PHOTOVOLTAIC MODULES BASED ON DYE SENSITIZED NANOCRYSTALLINE TITANIUM DIOXIDE AND CARBON POWDER[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,1996(1):99-117.
[23] Kiyoaki Imoto et al.High performance carbon counter electrode for dye-sensitized solar cells[J].Solar Energy Materials and Solar Cells,2003,79:459.
[24] Huang Z;Liu XH;Li KX;Li DM;Luo YH;Li H;Song WB;Chen LQ;Meng QB .Application of carbon materials as counter electrodes of dye-sensitized solar cells[J].Electrochemistry communications,2007(4):596-598.
[25] Murakami TN;Ito S;Wang Q;Nazeeruddin MK;Bessho T;Cesar I;Liska P;Humphry-Baker R;Comte P;Pechy P .Highly efficient dye-sensitized solar cells based on carbon black counter electrodes[J].Journal of the Electrochemical Society,2006(12):A2255-A2261.
[26] Lindstram H;Holmberg A;Magnusson E et al.A new method for manufacturing nanostructured electrodes on plastic substrates[J].Nano Letters,2001,1(02):97.
[27] 黄昆原;韩汝琦改.固体物理学[M].北京:高等教育出版社,1998
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