氰酸酯(CE)树脂被公认为是"21世纪制备高性能结构/功能材料最具竞争力的树脂品种",但是高固化温度以及由此带来的固化物性能稳定性差的问题成为制约CE应用的瓶颈.因此,CE树脂的固化催化研究显示出重要的理论意义和巨大的应用价值.综述了近年来CE树脂固化催化研究的新进展,包括各类专门催化剂及其催化机理,以及用于CE增韧增强的改性材料对CE固化反应的催化效应,展望了CE树脂固化催化研究的发展趋势.
参考文献
[1] | Hamerton I;Hay J N .Recent developments in the chemistry of cyanate esters[J].Polymer International,1998,47(04):465. |
[2] | Chaplin A;Hamerton I;Howlin Brendan J et al.Development of novel functionalized arylcyanate ester oligomers 1.Synthesis and thermal characterization of the monomers[J].Macromolecules,1994,27(18):4927. |
[3] | 王结良,梁国正,杨洁颖,任鹏刚,赵雯,房红强.高频氰酸酯基覆铜板基板的研制[J].中国塑料,2004(01):46-49. |
[4] | Chaplin A. .Studying water uptake effects in resins based on cyanate ester/bismaleimide blends[J].Polymer: The International Journal for the Science and Technology of Polymers,2000(11):3945-3956. |
[5] | Taylor A.; .RTM Material Developments for Improved Processability and Performance[J].SAMPE Journal,2000(4):17-25. |
[6] | Simonsl;Gillbam J K .Cure kinetics of a thermosetting liquid dicyanate ester monomer/high-Tg polycyanurate material[J].Journal of Applied Polymer Science,1993,47(03):461. |
[7] | Chang J Y;Hong J L .Polycyanurates modified with hydroxyl-terminated or cyanated poly(ether sulfone)[J].Polymer,2000,42(04):1525. |
[8] | Liu M C;Hong J L .Cure kinetics and gravimetric analysis of a flexible aromatic dicyanate,cyanated phenylene sebacate oligomer[J].Polymer,1994,35(13):2822. |
[9] | McCormick F B;Brown Wensley K A;DeVoe R J .Energycurable cyanate compositions[P].US,5215860,1993-06-01. |
[10] | Bauer M;Bauer J.Aspect of the kinetics,modeling and simulation of network build-up during cyanate ester cure[A].Glasgow:Chapman and Hall,1994 |
[11] | Gaku M;Kimbara H .Process for producing polyfunctional cyanate ester polymer[P].US,4 820 855,1989-04-11. |
[12] | Owusu AO.;Gotro JT.;Martin GC. .TRIAZINE FORMATION IN CYANATE-BASED RESIN SYSTEMS AT ROOM TEMPERATURE CONDITIONS[J].Polymer: The International Journal for the Science and Technology of Polymers,1996(21):4869-4872. |
[13] | Shimp D A .Metal carboxylate/alcohol curing catalyst for polycyanate ester of polyhydric phenol[P].US,4 608 434,1986-08-26. |
[14] | Liu HP.;George GA. .MECHANISM AND KINETICS OF POLYMERIZATION OF A DICYANATE ESTER RESIN PHOTOCATALYSED BY AN ORGANOMETALLIC COMPOUND[J].Polymer: The International Journal for the Science and Technology of Polymers,1996(16):3675-3682. |
[15] | Jakubek V;Lees A J;Fuerniss S J et al.Photocatalytic and photoinitiating properties of iron organometaUic complexes in solution and aromatic dicyanate esters[J].American Chemical Society,Polymer Priprints,Division of Polymer Chemistry,1997,38(01):195. |
[16] | Liu H.;Halley PJ.;George GA. .STUDIES ON THE GELATION OF PHOTOCATALYSED DICYANATE ESTER RESINS[J].Polymer: The International Journal for the Science and Technology of Polymers,1997(12):2997-3002. |
[17] | Dona Mathew;C. P. Reghunadhan Nair;K. Krishnan;K. N. Ninan .Catalysis of the Cure Reaction of Bisphenol A Dicyanate. A DSC Study[J].Journal of Polymer Science, Part A. Polymer Chemistry,1999(8):1103-1114. |
[18] | Wenfeng Li;Guozheng Liang;Wenli Xin .Triazine reaction of cyanate ester resin systems catalyzed by organic tin compound: kinetics and mechanism[J].Polymer international,2004(7):869-876. |
[19] | 李文峰,刘建勋,辛文利,梁国正,王志强,轩立新.有机锡化合物催化氰酸树脂的性能[J].航空学报,2004(05):513-515. |
[20] | Gomez CM;Recalde IB;Mondragon M .Kinetic parameters of a cyanate ester resin catalyzed with different proportions of nonylphenol and cobalt acetylacetonate catalyst[J].European Polymer Journal,2005(11):2734-2741. |
[21] | 李文峰,辛文利,梁国正,马晓燕,朱光明.氰酸酯树脂的固化反应及其催化剂[J].航空材料学报,2003(02):56-62. |
[22] | Hong SG;Yeh CS .Catalytic effects of copper oxides on the curing and degradation reactions of cyanate ester resin[J].Journal of Applied Polymer Science,2007(1):442-448. |
[23] | Chang Jer-Yuan .Morphology and fracture toughness of poly(ether sulfone)-blended polycyanurates[J].Polymer: The International Journal for the Science and Technology of Polymers,2000(12):4513-4521. |
[24] | Gu Aijuan .High performance bismaleimide/cyanate ester hybrid polymer networks with excellent dielectric properties[J].Journal of Computer Science and Technology,2006,66:1749. |
[25] | Koh Henry C Y;Dai Jie;Tan Eileen et al.Catalytic effect of 2,2 prime-diallyl bisphenol A on thermal curing of cyanate esters[J].Journal of Applied Polymer Science,2006,101(03):1775. |
[26] | Tim J.Wooster;Simmi Abrol;Douglas R.MacFarlane .Cyanate ester polymerization catalysis by layered-silicates[J].Polymer: The International Journal for the Science and Technology of Polymers,2004(23):7845-7852. |
[27] | GrenierLoustalot MF;Lartigau C .Influence of the stoichiometry of epoxy-cyanate systems (non-catalyzed and catalyzed) on molten state reactivity[J].Journal of Polymer Science, Part A. Polymer Chemistry,1997(15):3101-3115. |
[28] | Chen Ping.Study on the properties of cured compound in cyanate/epoxy co-curing system[A].,2000:915. |
[29] | 黄丽,王琛,洪旭辉.环氧树脂/氰酸酯共固化体系热性能的研究[J].北京化工大学学报(自然科学版),2007(02):164-168. |
[30] | 杨洁颖,梁国正,房红强,宫兆合.环氧改性氰酸酯树脂的研究[J].工程塑料应用,2004(02):64-66. |
[31] | 孟季茹,赵磊,梁国正,贾巧英.无机晶须在聚合物中的应用[J].化工新型材料,2001(12):1-6. |
[32] | 徐兆瑜.晶须的研究和应用新进展[J].化工技术与开发,2005(02):11-17. |
[33] | 任鹏刚,梁国正,卢婷利,房红强,杨洁颖,周文胜.ZnO晶须改性石墨纤维/双酚A二氰酸酯复合材料[J].复合材料学报,2005(02):46-51. |
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