蒸发诱导自组装仿生合成高有序度三维六方介孔氧化硅薄膜

功能材料, 2006, 37(10): 1653-1656.

蒸发诱导自组装仿生合成高有序度三维六方介孔氧化硅薄膜

田甜 ^1, , 骆志刚 ^2, , 张学骜 ^3, , 吴文健 ^4, , 王建方 ^5,

1.国防科技大学,计算机学院,湖南,长沙,410073

2.国防科技大学,计算机学院,湖南,长沙,410073

3.国防科技大学,航天与材料工程学院,湖南,长沙,410073

4.国防科技大学,航天与材料工程学院,湖南,长沙,410073

5.国防科技大学,航天与材料工程学院,湖南,长沙,410073

关键词：仿生合成 , 蒸发诱导自组装 , 制备 , 三维六方 , 介孔氧化硅薄膜

Biomimetic synthesis of highly oriented 3D-hexagonal mesoporous silica thin films by evaporation-induced self-assembly process

借鉴自然界生物矿化的形成机理,利用蒸发诱导自组装(EISA)的方法,以十六烷基三甲基溴化铵(CTAB)为结构导向剂,正硅酸乙酯(TEOS)为硅源,通过浸渍提拉在普通玻璃片上制备出高有序度、三维六方结构的介孔氧化硅薄膜,通过XRD、TEM、低温N2吸附/脱附等方法对薄膜进行了表征,并初步讨论了形成三维六方结构的机理.

参考文献

[1]	Aksay I A;Trau M;Manne S et al.[J].Science,1996,273:892-898.
[2]	Kresge C T;Leonowicz M E;Roth W J et al.[J].Nature,1992,359:710-712.
[3]	Beck J S;Vartuli J C;Roth W J et al.[J].Journal of the American Chemical Society,1992,114:10834-10843.
[4]	Xiao F S;Han Y;Yu Y et al.[J].Journal of the American Chemical Society,2002,124:888-889.
[5]	Kisler J M;Dahler A;Stevens G W et al.[J].Microporous and Mesoporous Materials,2001,44-45:769-774.
[6]	Jang J;Oh J H;Stucky G D .[J].Angewandte Chemie International Edition,2002,41:4016-4019.
[7]	Scott B J;Wirnsberger G;McGehee M D et al.[J].Advanced Materials,2001,13:1231-1234.
[8]	Homma T .[J].Materials Science and Engineering,1998,23:243-285.
[9]	Yang H;Coombs N;Sokolov I et al.[J].Nature,1996,381:589-592.
[10]	Brown AS.;Reynolds PA.;Penfold J.;White JW.;Holt SA. .Growth of highly ordered thin silicate films at the air-water interface[J].Langmuir: The ACS Journal of Surfaces and Colloids,1998(19):5532-5538.
[11]	Yang H;Kuperman A;Coombs N et al.[J].Nature,1996,379:703-705.
[12]	Aksay I A;Trau M;Manne S et al.[J].Science,1996,273:892-898.
[13]	Schacht S;Huo Q;Voigt-Martin I G et al.[J].Science,1996,273:768-771.
[14]	LU Y.;GANGULI R.;DREWIEN C. A.;ANDERSON M. T.;BRINKER C. J.;GONG W.;GUO Y.;SOYEZ H.;DUNN B.;HUANG M. H.;ZINK J. I. .CONTINUOUS FORMATION OF SUPPORTED CUBIC AND HEXAGONAL MESOPOROUS FILMS BY SOL GEL DIP-COATING[J].Nature,1997(6649):364-368.
[15]	Brinker CJ.;Sellinger A.;Fan HY.;Lu YF. .Evaporation-induced self-assembly: Nanostructures made easy[J].Advanced Materials,1999(7):579-585.
[16]	Naik S P;Yamakita S;Ogura M et al.[J].Microporous and Mesoporous Materials,2004,75:51-59.
[17]	Tolbert S H;Schffer T E;Feng J et al.[J].Chemistry of Materials,1997,9:1962-1967.
[18]	Grosso D.;Babonneau F.;Albouy PA.;Amenitsch H.;Balkenende AR. Brunet-Bruneau A.;Rivory J. .An in situ study of mesostructured CTAB-silica film formation during dip coating using time-resolved SAXS and interferometry measurements[J].Chemistry of Materials,2002(2):931-939.
[19]	Besson S.;Gacoin T.;Ricolleau C.;Jacquiod C.;Boilot JP. .Phase diagram for mesoporous CTAB-silica films prepared under dynamic conditions[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(2):404-409.
[20]	Zhao D.;Melosh N.;Feng J.;Chmelka BF.;Stucky GD.;Yang P. .Continuous mesoporous silica films with highly ordered large pore structures[J].Advanced Materials,1998(16):1380-138+.
[21]	Zhao D;Yang P;Margolese D I et al.[J].Chemical Communications,1998,22:2499-2500.
[22]	Ogawa M;Masukawa N .[J].Microporous and Mesoporous Materials,2000,38:35-41.
[23]	Honma I.;Kundu D.;Endo A.;Zhou HS. .Structural control of surfactant-templated hexagonal, cubic, and lamellar mesoporous silicate thin films prepared by spin-casting[J].Advanced Materials,2000(20):1529-1533.
[24]	徐如人;庞文琴;于吉红.[M].北京:科学出版社,2004:558-559.
[25]	Israelachvili J.Intermolecular and Surface Forces[M].New York:Academic Press,1992

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

蒸发诱导自组装仿生合成高有序度三维六方介孔氧化硅薄膜

Biomimetic synthesis of highly oriented 3D-hexagonal mesoporous silica thin films by evaporation-induced self-assembly process

参考文献