核壳型氟代聚丙烯酸酯乳液、丙烯酸树脂、纳米粒子构成的氟碳涂料所得涂层具有优良的自清洁性能，过去对其研究不够。以过硫酸铵为引发剂，阴／非离子表面活性剂为复合乳化剂，采用半连续种子乳液共聚法，将丙烯酸丁酯（BA）、苯乙烯（ST）及1一甲基丙烯酰氧基丙基三甲氧基硅烷（MPMS）与甲基丙烯酸十二氟庚酯（DFMA）于水相中制备了一种核壳型含氟硅聚丙烯酸酯乳液，与丙烯酸树脂、纳米TiO：等制备了氟碳涂料。利用红外光谱（IR）和透射电镜（TEM）对乳液主组分结构、乳胶粒形貌及粒径大小进行了表征和分析，考察了固化温度、乳液用量对涂层性能的影响。结果表明：合成乳液的乳胶粒呈规则球状，具有核壳结构，平均粒径约为100nm；当乳液用量为45瓢固化温度为160c【=时，所得涂层性能最佳，与水的接触角达133。，具有较好的自清洁性。
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