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钒基固溶体合金是一类重要的贮氢材料.概述了金属钒的氢化特性,讨论了钒基固溶体合金有效贮氢量低的原因;综述了合金组元及非金属杂质元素对钒基固溶体合金性能的影响,在吸氢主要元素钒基中添加其它元素(Ti、Ni、Cr、Mn、Fe、Hf、Zr、Nb、Co、Al、Si等)有利于提高合金的贮氢性能.

参考文献

[1] 彭述明,赵鹏骥,杨茂年,姚书久,罗顺忠,徐志磊.金属钒及其氢化物的晶体结构模拟[J].原子能科学技术,2000(05):469-472.
[2] Jang KJ.;Kim DM.;Yu JS.;Lee JY.;Jung JH. .Self-discharge mechanism of vanadium-titanium metal hydride electrodes for Ni-MH rechargeable battery[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):290-294.
[3] Okada M;Kuriiwa T;Tamura T et al.Ti-V-Cr b.c.c.alloys with high protium content[J].Journal of Alloys and Compounds,2002,330-332:511.
[4] 胡子龙.贮氢材料[M].北京:化学工业出版社,2002:39.
[5] 李荣,周上祺,陈昌国,梁国明,刘守平,孔纪兰.钒氢化物电子结构的量子化学研究[J].物理化学学报,2005(07):716-720.
[6] 赵罡,刘守平,周上祺,李荣,任勤.钒-氢反应规律与钒基固溶体贮氢合金开发[J].钢铁钒钛,2003(02):39-43.
[7] 廖小珍,刘文华,马紫峰.Surface Modification of a MCFC Anode by Electrochemical Alloying[J].稀有金属,2001(02):126-129.
[8] Huang Taizhong;Wu Zhu;Xia Baojia et al.Influence of V content on structure and hydrogen desorption performance of Ti-Cr-V based hydrogen storage alloys[J].Materials Chemistry and Physics,2005,93:544.
[9] Huang Taizhong;Wu Zhu;Chen Jinzhou et al.Dependence of hydrogen storage capacity of TiCr1.8-x(VFe)x on VFe content[J].Material Science and Engineering,2004,385:17.
[10] 杜树立,王新华,陈立新,李寿权,陈长聘,汤滢,肖学章.Ti1.0VxMn2-x(x=0.6~1.6)合金的微结构和储氢性能[J].稀有金属材料与工程,2006(08):1285-1288.
[11] 彭述明;龙兴贵;杨茂年 等.钛-钒合金及其氢化物的第一原理研究[J].化学通报(印刷版),2001,3(02):7.
[12] Kim J H;Lee H;Lee P S et al.A study on the improvement of the cyclic durability by Cr substitution in V-Ti alloy and surface modification by ball-milling process[J].Journal of Alloys and Compounds,2003,348:293.
[13] Pan Hongge;Li Rui;Gao Mingxia et al.Effects of Cr on the structural and electrochemical properties of Tiv-based two-phase hydrogen storage alloys[J].Journal of Alloys and Compounds,2005,404-406:669.
[14] Chen Lixin;Gao Rui;Lei Yongquan et al.Structural and electrochemical characteristics of V2.1TiNi0.5Hf0.05M0.152(M=Co,Cr)hydrogen storage electrode alloys[J].Materials Chemistry and Physics,2005,92:554.
[15] 郑坊平,陈立新,王亚茹,王新华,李露,陈长聘.(Ti0.1V0.9)1-xFex(x=0~0.06)合金的相结构及储氢性能[J].功能材料,2006(09):1438-1441.
[16] Cho S.W.;Enoki H. .Effect of Fe addition on hydrogen storage characteristics of Ti_(0.16) Zr_(0.05) Cr_(0.22)V_(0.57) alloy[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):304-310.
[17] Yu X B;Feng S L;Wu Z et al.Hydrogen storage performance of Ti-V-based BCC phase alloys with various Fe content[J].Journal of Alloys and Compounds,2005,393:129.
[18] Yan Yigang;Chen Yungui;Liang Hao et al.Hydrogen storage properties of V30-Ti-Cr-Fe alloys[J].Journal of Alloys and Compounds,2007,427:110.
[19] Tsukahara M;Takahashi K;Mishima T et al.The V3TiNi0.56 hydride electrode its electrochemical and cycle life characterization[J].Journal of Alloys and Compounds,1995,231:616.
[20] 代发帮,陈立新,刘剑,郑坊平,张志鸿,雷永泉.TiV2.1Nix(x=0.2~0.6)贮氢合金的相结构及电化学性能[J].稀有金属材料与工程,2005(09):1500-1504.
[21] Guo Rui;Chen Lixin;Lei Yongquan et al.The effect of Ni content on the phase structures and electrochemical properties of V2.1 TiNix(x=0.1~0.9)hydrogen storage alloys[J].International Journal of Hydrogen Energy,2003,28:803.
[22] Pan Hongge;Li Rui;Gao Mingxia et al.Effect of Ni on the structural and electrochemical properties of Ti-V-based hydrogen storage alloys[J].International Journal of Hydrogen Energy,2006,31:1188.
[23] Tamura T;Tominaga Y;Matsumoto K et al.Protium absorption properties of Ti-V-Cr-Mn alloys with a b.c.c.structure[J].Journal of Alloys and Compounds,2002,330-332:522.
[24] Seo C Y;Kim J H;Lee P S et al.Hydrogen storage properties of vanadium-based b.c.c.solid solution metal hydrides[J].Journal of Alloys and Compounds,2003,348:252.
[25] Li Rui;Pan Hongge;Gao Mingxia et al.Investigation of microstructure and electrochemical properties of Ti0.8 Zr0.2-V2.7Mn0.5+xCr0.8 Ni1.5-x hydrogen storage alloys[J].Journal of Alloys and Compounds,2007,432:183.
[26] Kim DM.;Jang KJ.;Lee JY.;Lee SM. .The electrode characteristics of over-stoichiometric ZrMn0.5V0.5Ni1.4+y (y=0.0, 0.2, 0.4 and 0.6) alloys with C15 Laves phase structure[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):241-247.
[27] Yan Yigang;Chen Yungui;Liang Hao et al.Effect of Al on hydrogen storage properties of V30Ti35Cr25Fe10 alloy[J].Journal of Alloys and Compounds,2006,426:253.
[28] Yan Yigang;Chen Yungui;Liang Hao et al.The effect of Si on V30Ti35Cr25Fe10 BCC hydrogen storage alloy[J].Journal of Alloys and Compounds,2007,441:297.
[29] Tsukahara M;Takahashi K;Mishima T et al.Influence of various additives in vanadium-based alloys V3TiNi0.56 on secondary phase formation,hydrogen storage properties and electrode properties[J].Journal of Alloys and Compounds,1996,245:59.
[30] 梁浩,陈云贵,严义刚,吴朝玲,陶明大,涂铭旌.V55Ti20.5Cr18.1Fe6.4合金的吸放氢循环性能研究[J].稀有金属材料与工程,2006(09):1375-1378.
[31] Tsukahara M.;Isomura A.;Sakai T.;Takahashi K. .Influence of oxygen on hydrogen storage and electrode properties for micro-designed V-based battery alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):257-263.
[32] Shi J;Tsukahara M;Takeshita H T et al.Influence of carbon on electrode properties of V-Ti-Ni type hydrogen storage alloy[J].Journal of Alloys and Compounds,1999,293-295:716.
[33] 涂铭旌,陈云贵.稀土、钒钛贮氢合金及镍氢电池研究进展[J].四川大学学报(工程科学版),2006(05):1-6.
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