欢迎登录材料期刊网

材料期刊网

高级检索

尖晶石型锂锰氧化物是目前最具发展前景的锂吸附剂.介绍了锂锰氧化物的合成方法及结构、Li+的抽提/嵌入反应机理和锂离子筛吸附锂过程中的影响因素,讨论了对目前在锂吸附剂的制备及实际应用等方面存在的问题,并展望了锂锰氧化物离子筛未来的研究方向.

Spinel-type lithium manganese oxide is the most promising lithium adsorbent. The synthesis method and the structure of lithium manganese oxides are described, the Li+ extraction/insertion mechanism is reviewed,and the effect factors of adsorbing lithium are discussed. The synthesis and application of lithium adsorbents are gathered and discussed. Furthermore,promising avenues for further research in this area are expected.

参考文献

[1] 陈东文.锂与社会[J].化学教育,1997(05):3.
[2] 纪志永,袁俊生,李鑫钢.锂离子筛的制备及其交换性能研究[J].离子交换与吸附,2006(04):323-329.
[3] Wang L;Ma W;Liu R;Li HY;Meng CG .Correlation between Li+ adsorption capacity and the preparation conditions of spinel lithium manganese precursor[J].Solid state ionics,2006(17/18):1421-1428.
[4] 纪志永 .锂吸附剂的合成及其吸附性能研究[D].河北工业大学,2004.
[5] 黄乐之,戈桦.尖晶石型锂离子筛前驱体的制备和性能表征[J].无机盐工业,2008(07):25-28.
[6] Koyanaka H;Matsubaya O;Koyanaka Y et al.Quantitative correlation between Li absorption and H content in manganese oxide spinel λ-MnO2[J].Journal of Electroanalytical Chemistry,2003,559:77.
[7] 卢集政;赖琼钰 .锂嵌脱化合物LiMn2O4的微波烧结研究[J].化学研究与应用,1998,10(06):620.
[8] 李琪,李飞,乔庆东.Li1+xMn2O4的合成及表征[J].石油化工高等学校学报,2004(04):22-25.
[9] Yi T F;Dai C S;Gao K et al.Effects of synthetic parameters on structure and electrochemical performance of spinel lithium manganese oxide by citric acid-assisted sol-gel method[J].Journal of Alloys and Compounds,2006,425:343.
[10] Kanasaku T.;Yamamoto N.;Amezawa K. .Hydrothermal synthesis and electrochemical properties of Li-Mn-spinel[J].Solid state ionics,2000(1/2):51-56.
[11] Chitraker R;Kanoh H;Miyai Y.A new type of manganese oxide(MnO2 · 0.5H2O) derived from Li1.6 Mn1.6O4and its lithium ion-iieve properties[J].CHEMISTRY OF MATERIALS,2000:315112.
[12] Zhang YC.;Wang H.;Xu HY.;Wang B.;Yan H.;Ahniyaz A.;Yoshimura M. .Low-temperature hydrothermal synthesis of spinel-type lithium manganese oxide nanocrystallites[J].Solid state ionics,2003(1/2):113-117.
[13] 王萍,解廷月,李海.脉冲激光沉积技术[J].山西大同大学学报(自然科学版),2008(04):19-22.
[14] Xia H;Lua L;Ceder G .Li diffusion in LiCoO2 thin films prepared by pulsed laser deposition[J].Journal of Power Sources,2006,159:1422.
[15] Aitchison P;Ammundsen B;Bell T et al.Proton insertion in spinel lithium manganates and the effect of manganese substitution[J].Physica B,2000,276-278:847.
[16] Piszora P;Catlow C R A;Woodley S M et al.Relationship of crystal structure to interionic intercations in the lithiummanganese spinel oxides[J].Computers Chemistry,2000,24:609.
[17] Kim Y S;Kanoh H;Hirotsu T et al.Chemical bonding of ion-exchange type sites in spinel-type manganese oxides Li1.33 Mn1.67 O4[J].Materials Research Bulletin,2002,37:91.
[18] Feng Q;Kanoh H;Miyai Y et al.Hydrothermal synthesis of lithium and sodium manganese oxides and their metal ion extraction/insertion reactions[J].Chemistry of Materials,1995,7:1226.
[19] Ooi K;Miyai Y;Sakakihara J .Mechanism of lithium(1+)insertion in spinel-type manganese oxides:Redox and ion-exchange reactions[J].Langmuir,1991,7:1167.
[20] Feng Q;Miyai Y;Kanoh H et al.Li+ Extraction/insertion with spinel-type lithium manganese oxides:Characterization of redox-type and ion-exchange-type sites[J].Langmuir,1992,8:1861.
[21] Ammundsen B;Jones D J;Burns J R R .Effect of chemical extraction of lithium qn the local structure of spinel lithium manganese oxides determined by X-ray absorption spectroscopy[J].Chemistry of Materials,1996,8:2799.
[22] Ariza M J;Jones D J;Rozire J et al.Probing the local structure and the role of protons in lithium sorption processes of a new lithium-rich manganese oxide[J].Chemistry of Materials,2006,18:1885.
[23] 李艳;齐涛;王丽娜 等.离子筛材料的合成及其对盐湖卤水中锂的选择性吸附[J].山西大同大学学报,2008,24(04):19.
[24] Wang, L;Meng, CG;Ma, W .Study on Li+ uptake by lithium ion-sieve via the pH technique[J].Colloids and Surfaces. A, Physicochemical and Engineering Aspects,2009(1/3):34-39.
[25] Wang L;Meng CG;Han M;Ma W .Lithium uptake in fixed-pH solution by ion sieves[J].Journal of Colloid and Interface Science,2008(1):31-40.
[26] 张碧泉.EMD的离子交换行为及其离子筛法提取锂的研究[J].高等学校化学学报,1996(08):1195.
[27] Chitrakar R;Kanoh H;Miyai Y et al.Recovery of lithium from seawater using manganese oxide adsorbent(H1.6 Mn1.6-O4) derived from Li1.6 Mn1.6 O4[J].Industrial and Engineering Chemistry Research,2001,40:2054.
[28] 孟兴智 .离子筛型锂吸附剂的成型及其性能研究[D].河北工业大学,2005.
[29] 蔡邦肖.日本的海水化学资源提取技术研究[J].东海海洋,2000(04):52.
[30] Umeno A;Miyai Y;Takagi N et al.Preparation and adsorptive properties of membrane-type adsorbents for lithium recovery from seawater[J].Industrial and Engineering Chemistry Research,2002,41:4281.
[31] Chung K S;Lee J C;Kim W K et al.Inorganic adsorbent containing polymeric membrane reservoir for the recovery of lithium from seawater[J].Journal of Membrane Science,2008,325:503.
[32] 徐粉燕,钟辉,罗静.尖晶石锂锰氧化物离子筛的结构及掺杂改性[J].矿产综合利用,2008(01):31-34.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%