掺杂3 mol% LaCl3的NaAlH4试样的放氢量最大并且放氢动力学性能最好,其激活能为41.6 kJ/mol,这个值低于所报道的掺杂Ti的NaAlH4的激活能.
n properties in both the amount of hydrogen release and the desorption kinetics. The activation energy of the NaAlH4 sample doped with 3 mol% LaCl3 was measured to be 41.6 kJ/mol. This value is lower than that reported for the Ti-doped NaAlH4.
参考文献
[1] | Gene D Berry;Salvador M Aceves .[J].Energy and Fuels,1998,12(01):49. |
[2] | Andrer C M;Walmsley J;Blanchard D et al.[J].Journal of Alloys and Compounds,2005,395:307. |
[3] | Bogdanovi(c) B;Schwickardi M .[J].Journal of Alloys and Compounds,1997,253-254:1. |
[4] | Wang J;Ebner A D;Zidan R et al.[J].Journal of Alloys and Compounds,2005,391:245. |
[5] | Sandrock G;Gross K;Thomas G .[J].Journal of Alloys and Compounds,2002,339:299. |
[6] | Balogh M P;Tibbetts G G;Pinkerton F E et al.[J].J Alloy Comd,2003,350:136. |
[7] | Gross K.J.;Gutlirie S. .In-situ X-ray diffraction study of the decomposition of NaA1H_4[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):270-281. |
[8] | Wang J;Ebner A D;Prozorov T et al.[J].Journal of Alloys and Compounds,2005,395:252. |
[9] | Pukazhselvan D;Sterlin Leo Hudson M;Gupta B K et al.[J].Journal of Alloys and Compounds,2007,439:243. |
[10] | Easton D S;Schneibel J H;Speakman S A .[J].Journal of Alloys and Compounds,2005,398:245. |
[11] | Andreasena A;Veggea T;Pedersena A S .[J].Journal of Solid State Chemistry,2005,178:3664. |
[12] | Chen J;Kuriyama N;Xu Q et al.[J].Journal of Physical Chemistry B,2001,105:11214. |
[13] | Resan M;Hampton M D;Lomness J K et al.[J].Int J Hydrogen E,2005,30:1413. |
[14] | Blanchard D;Brinks H W;Hauback B C et al.[J].Materials Science and Engineering B,2004,108:54. |
[15] | Balema V P;Wiench J W;Dennis K W et al.[J].Journal of Alloys and Compounds,2001,329:108. |
[16] | Resan M;Hampton M D;Lomness J K et al.[J].Int J Hydrogen B,2005,30:1417. |
[17] | Wang Jun;Armin D Ebner;James A Ritter .[J].Adsorption-Journal of the International Adsorption,2005,11:811. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%