本文以钛酸四丁酯(Ti(OC4H9)4)为原料,采用溶胶-凝胶法在ITO导电玻璃基片表面制备了均匀透明的TiO2薄膜.使用X射线衍射仪表征了薄膜的晶型结构.通过电化学方法对TiO2薄膜进行锂化,研究了TiO2薄膜的厚度、热处理温度和外加电压对薄膜锂化效果的影响.结果表明,当镀膜层数为4层,热处理温度为400℃时,TiO2薄膜Li+存储能力最强.当TiO2薄膜相对参比电极外加电压为±2V时,Li+可充分进入薄膜并与之结合形成蓝色化合物LixTiO2,变色效果最为明显.
参考文献
| [1] | Verma A;Samanta SB;Bakhshi AK;Agnihotry SA .Effect of stabilizer on structural, optical and electrochemical properties of sol-gel derived spin coated TiO2 films[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2005(1):47-64. |
| [2] | Wei Feng Chen;Shu Yii Wu;Yi Fang Ferng .The electrochromic properties of nickel oxide by chemical deposition and oxidization[J].Materials Letters,2006(6):790-795. |
| [3] | 毕孝国,盛伟,孟广波.聚苯胺电致变色薄膜的制备与应用[J].沈阳工程学院学报（自然科学版）,2007(03):295-298,302. |
| [4] | 李天文,刘鸿生.变色材料的研究与应用[J].现代化工,2004(02):62-64,70. |
| [5] | 朱泉峣,靳艾平,陈文.智能窗中电致变色材料的研究进展[J].国外建材科技,2006(01):4-7. |
| [6] | Verma A;Basu A;Bakhshi AK;Agnihotry SA .Structural, optical and electrochemical properties of sol-gel derived TiO2 films: Annealing effects[J].Solid state ionics,2005(29/30):2285-2295. |
| [7] | Sun DL.;Heusing S.;Puetz J.;Aegerter MA. .Influence of water on the electrochemical properties of (CeO2)(x)(TiO2)(1-x) and WO3 sol-gel coatings and electrochromic devices[J].Solid state ionics,2003(1/4):181-189. |
| [8] | 程银兵,马建华,吴广明,沈军,王珏.热处理对溶胶-凝胶TiO2薄膜的晶相转变和性能影响[J].功能材料,2003(01):73-75. |
| [9] | 罗志华,许可,孙理蓉,苏大为.纳米TiO2薄膜的研究[J].上海有色金属,2007(01):36-42. |
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