与传统的γ-Al2O3相比,介孔氧化铝分子筛具有较大的比表面积和较窄的孔径分布,作为工业催化剂或催化剂载体,具有更为广阔的应用前景.本文重点介绍了介孔氧化铝分子筛的不同合成方法、结构表征方法和催化性能,分析了模板剂类型、凝胶pH值、洗涤方法、焙烧方式等制备条件对其结构的影响.并对其催化应用进行了评述和展望.
参考文献
[1] | Beck J S et al.[J].Journal of the American Chemical Society,1992,114:10834-10843. |
[2] | Bagshaw S A et al.[J].Angewandte Chemie International Edition,1996,35(10):1102-1105. |
[3] | Gonzalez-Pena V et al.[J].Microporous and Mesoporous Materials,2001,44-45:203-210. |
[4] | Isabel Diaz;Veronica Gonzalez-Pena;Carlos Marquez-Alvarez;Eustathios S. Kikkinides .Transmission electron microscopy combined with stochastic reconstruction methods for structural characterization of porous alumina synthesized via non-ionic surfactant-templating route[J].Microporous and Mesoporous Materials,2004(1/3):11-19. |
[5] | Gonzalez-Pena et al.[J].Studies in Surface Science and Catalysis,2002,142:1283-1290. |
[6] | Deng W et al.[J].Microporous and Mesoporous Materials,2002,52:169-177. |
[7] | Yang P et al.[J].CHEMISTRY OF MATERIALS,1999,11(10):2813-2826. |
[8] | Vaudry F et al.[J].Chemistry of Materials,1996,8(07):1451-1464. |
[9] | Zhang XM.;Suo JS.;Li SB.;Zhang ZR. .Synthesis of transition-metal containing MSU mesoporous silica molecular sieves[J].Chemistry Letters,1998(8):755-756. |
[10] | Bagshaw S A et al.[J].Microporous Mesoporous Meterials,1998,22(1-3):419-433. |
[11] | Zhang W et al.[J].Chemical Communications,1998,28:1185-1188. |
[12] | Valange S et al.[J].Microporous and Mesoporous Materials,2000,35-36:597-607. |
[13] | Yada M.;Machida M.;Kijima T.;Ohya M. .Mesoporous gallium oxide structurally stabilized by yttrium oxide[J].Langmuir: The ACS Journal of Surfaces and Colloids,2000(10):4752-4755. |
[14] | Yada M.;Ohe K.;Machida M.;Kijima T.;Ohya M. .Porous yttrium aluminum oxide templated by alkyl sulfate assemblies[J].Langmuir: The ACS Journal of Surfaces and Colloids,2000(4):1535-1541. |
[15] | Sicard;Lorete et al.[J].Microporous and Mesoporous Materials,2001,44-45:25-31. |
[16] | Yada M et al.[J].Chemical Communications,1996,23:769-770. |
[17] | Zhang Xin et al.[J].Materials Letters,2004,58:2872-2877. |
[18] | Shan Z et al.[J].Applied Catalysis A:General,2003,254:339-343. |
[19] | Yada M et al.[J].Transactions Inorg Chem,1997,36:5565-5569. |
[20] | Valange S;Derouault A;Barrault J;Gabelica Z .One-step generation of highly selective hydrogenation catalysts involving sub-nanometric Cu2O supported on mesoporous alumina: strategies to control their size and dispersion[J].Journal of molecular catalysis, A. Chemical,2005(1/2):255-266. |
[21] | Jaroniec M et al.[J].Langmuir,1999,15(16):5410-5413. |
[22] | Kim J M et al.[J].Journal of Physical Chemistry,1995,99(45):16742-16747. |
[23] | Oikawa T .[J].Microporous and Mesoporous Materials,2004,74:93-103. |
[24] | Buelna G et al.[J].Microporous and Mesoporous Materials,2004,39:167-179. |
[25] | Kaluza L.[J].Catalysis Communications,2002(03):151-157. |
[26] | Kim P et al.[J].Journal of Molecular Catalysis A:Chemical,2004,219:87-95. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%