采用微弧氧化技术在MB8镁合金表面制备了陶瓷膜,使用的电解质溶液清洁、对环境友好.分析了选用不同制备参数时对应的电流密度与时间的关系曲线.同时,分析了陶瓷氧化膜厚度、微观形貌、膜层结构和成分.结果表明,随着电压和频率的增加,微弧氧化陶瓷层的厚度呈快速增长趋势,而随着占空比的增加,膜层的厚度呈先增加后减小的趋势.当电压为200V和250V时,陶瓷膜分布着大量不规则的堆积层,主要为Si、Ca、P的产物.
参考文献
[1] | Hanzi AC;Gunde P;Schinhammer M .On the biodegradation performance of an Mg-Y-RE alloy with various surface conditions in simulated body fluid.[J].Acta biomaterialia,2009(1):162-171. |
[2] | Song Y W;Shan D Y;Han E H .Electrodeposition of hydroxyapatite coating on AZ91D magnesium alloy for biomaterial application[J].Materials Letters,2008,62:3276. |
[3] | Tan L L;Wang Q;Geng F .Preparation and characterization of Ca-P coating on AZ31 magnesium alloy[J].Transactions of Nonferrous Metals Society of China,2010,20:648. |
[4] | Growth characteristics and corrosion resistance of micro-arc oxidation coating on pure magnesium for biomedical applications[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2010(7):2228. |
[5] | Liu G Y;Hu J;Ding Z K et al.Bioactive calcium phosphate coating formed on micro-arc oxidized magnesium by chemical deposition[J].Applied Surface Science,2011,257:2051. |
[6] | Wang Y M;Wang F H;Xu M J .Microstructure and corrosion behavior of coated AZ91 alloy by microarc oxidation for biomedical application[J].Applied Surface Science,2009,255:9124. |
[7] | Adjustment of the ratio of Ca/P in the ceramic coating on Mg alloy by plasma electrolytic oxidation[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2009(13/14):6724. |
[8] | Sun JF;Han Y;Cui K .Microstructure and apatite-forming ability of the MAO-treated porous titanium[J].Surface & Coatings Technology,2008(17):4248-4256. |
[9] | Dittrich K H;Kurze P;Krysmann W .Structure and properties of ANOF layers[J].Crystal Research and Technology,1984,19(01):93. |
[10] | Zhang W et al.Preparation and characterization of a novel Si-incorporated ceramic film on pure titanium by plasma electrolytic oxidation[J].Applied Surface Science,2008,254:5216. |
[11] | V. S. Rudnev;M. S. Vasil'eva;I. V. Lukiyanchuk .On the Surface Structure of Coatings Formed by Anodic Spark Method[J].Protection of Metals,2004(4):352-357. |
[12] | Cannillo V;Angulo J C et al.In vitro characterization of plasma-sprayed apatite/wollastonite glass-ceramic biocoatings on titanium alloys[J].Journal of the European Ceramic Society,2009,29:1665. |
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