聚己二酸对苯二甲酸丁二酯( PBAT)是一种新型的完全生物降解脂肪-芳香族共聚酯。与其它聚合物进行共混改性是改善 PBAT 基材综合性能的有效手段。本报告从PBAT的性能特点和应用出发,综述了近年来 PBAT与可降解聚合物、天然高分子、非降解聚合物、无机粒子等进行熔融共混改性的研究进展;并对 PBAT 将来的发展作了展望。
Poly( butylene adipate-co-butylene terephthalate) ( PBAT) is a new completely biodegradable polyester ( aliphatic-co-aromatic). Blending with other polymers is an effective way to improve the overall properties of PBAT based materials. From the viewpoints of performance characteristics and applications of PBAT,advances in solvent blending and melt blending modification of PBAT with degradable polymers,natural polymer,non-degradable polymers and inorganic particles for nearly a decade were reviewed and the developing tendency of PBAT was discussed.
参考文献
[1] | 顾书英,詹辉,任杰.聚乳酸/PBAT共混物的制备及其性能研究[J].中国塑料,2006(10):39-42. |
[2] | 赵正达,刘涛,顾书英.Joncryl增容PLA/PBAT共混体系结构及性能研究[J].材料导报,2008(Z2):416-418,421. |
[3] | 刘涛,赵正达,顾书英.AX8900增容聚乳酸/PBAT共混体系的研究[J].塑料工业,2009(03):75-77,81. |
[4] | 朱兴吉,顾书英,任杰,詹辉.PEG对PLA/Ecoflex复合材料性能的影响[J].塑料工业,2007(07):19-21. |
[5] | 卢伟,李雅明,杨钢,李启成,肖汉文,叶正涛.聚乳酸(PLA)/己二酸-对苯二甲酸-丁二酯共聚物(PBAT)/乙酰化柠檬酸三丁酯(ATBC)共混物的结晶行为[J].胶体与聚合物,2008(02):19-21. |
[6] | 王亮,顾书英,詹辉,任杰.聚己内酯对聚乳酸/PBAT共混物增容作用的研究[J].工程塑料应用,2007(08):5-8. |
[7] | 袁华,杨军伟,刘万强,任杰.熔融扩链反应制备PLA/PBAT多嵌段共聚物[J].工程塑料应用,2008(10):46-50. |
[8] | Kumar, M.;Mohanty, S.;Nayak, S.K.;Rahail Parvaiz, M. .Effect of glycidyl methacrylate (GMA) on the thermal, mechanical and morphological property of biodegradable PLA/PBAT blend and its nanocomposites[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2010(21):8406-8415. |
[9] | Oyama, H.T.;Tanaka, Y.;Hirai, S.;Shida, S.;Kadosaka, A. .Water-disintegrative and biodegradable blends containing poly(L-lactic acid) and poly(butylene adipate-co-terephthalate)[J].Journal of Polymer Science, Part B. Polymer Physics,2011(5):342-354. |
[10] | 吕怀兴,杨彪,许国志.PBS/PBAT共混型全生物降解材料的制备及其性能研究[J].中国塑料,2009(08):18-21. |
[11] | 王秋艳,许国志,翁云宣.PPC/PBAT生物降解材料热性能和力学性能的研究[J].塑料科技,2011(06):51-54. |
[12] | 王淑芳,陶剑,郭天瑛,付涛,袁晓燕,郑俊萍,宋存江.脂肪族聚碳酸酯(PPC)与聚乳酸(PLA)共混型生物降解材料的热学性能、力学性能和生物降解性研究[J].离子交换与吸附,2007(01):1-9. |
[13] | 欧阳春发,贾润萍,王霞,马丕明,张勇.PHBV/PBAT共混物形态与性能研究[J].中国塑料,2008(06):44-48. |
[14] | 宁平,陈明月,肖运鹤.淀粉填充改性PBAT的结构与性能研究[J].化工新型材料,2010(07):116-119. |
[15] | 邱桥平,谢新春,谭磊,向明.可生物降解TPS/PBAT复合材料的制备[J].合成树脂及塑料,2009(03):13-16. |
[16] | Olivato, J. B., Grossmann, M. V. E., Yamashita, F., Nobrega, M. M., Scapin, M. R. S., Eiras, D., Pessan, L. A. .Compatibilisation of starch/poly(butylene adipate co-terephthalate) blends in blown films.[J].International Journal of Food Science and Technology,2011(9):1934-1939. |
[17] | Parulekar Y;Mohanty AK .Extruded biodegradable cast films from polyhydroxyalkanoate and thermoplastic starch blends: Fabrication and characterization[J].Macromolecular materials and engineering,2007(12):1218-1228. |
[18] | Brandelero R P H;Yamashita F;Grossmann M V E .The effect of surfactant Tween 80 on the hy-drophilicity,water vapor permeation,and the me-chanical properties of cassava starch and poly(butylenes adipate-co-terephthalate)(PBAT)blend films[J].Carbohydrate Polymers,2010,82(04):1102-1109. |
[19] | 肖运鹤,宁平,薛继荣,冉进成.超细碳酸钙填充可降解聚酯材料的研究[J].塑料,2009(03):69-71. |
[20] | Kanzawa, T.;Tokumitsu, K. .Mechanical properties and morphological changes of poly(lactic acid)/polycarbonate/poly(butylene adipate-co-terephthalate) blend through reactive processing[J].Journal of Applied Polymer Science,2011(5):2908-2918. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%