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制备了稀土固体超强酸SO2-4/TiO2/La3+,研究了以其为催化剂,癸二酸和无水乙醇为原料合成癸二酸二乙酯,并考察了影响反应的因素。结果表明,它是一种良好的酯化催化剂。

The rare-earth solid superacid SO2-4/TiO2/La3+ was prepared. Thesynthesis of diethyl sebacate has been studied using ethanol absolute and sebacic acid as reactants, and rare-earth solid superacid SO2-4/TiO2/La3+as catalyst. The influence factors of reaction were investigated. The results show that it is a good catalyst for esterifications.

参考文献

[1] 蒋文伟 .Research Advances in Superacid Catalysts[J].精细化工,1997,14(01):46-49.
[2] 王存得;牛岫琴;钱文元.Catalytic Synthesis of Isoamyl Acetate by Solid Superacid TiO2/SO2-4[J].香料香精化妆品,1991(02):8.
[3] 王存得;冯学兵 .Study on Catalytic Synthesis of Ester by Rare-earth Solid Superacid[J].石油化工,1994,23(03):166-169.
[4] 曲济方;顾宏邦;张端风.Catalytic Synthesis of Isoamyl Cinnamate by Solid Superacid TiO2/SO2-4[J].化学世界,1995(03):140-141.
[5] 高滋.ZrO2/SO42-超强酸体系形成过程的研究[J].高等学校化学学报,1992(12):1498-1502.
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