针对转炉铬矿熔融还原法冶炼不锈钢母液工艺,利用冶金热力学原理对该过程中涉及的几个重要问题进行了理论分析和计算,为在转炉中用铬矿实现钢的直接合金化的热力学可行性提供了理论依据.得到结论:①铬矿石在熔融还原转炉中是完全可以被还原的;②金属熔体中铬的活度随金属中铬质量分数的增加而增大,温度对金属铬活度的影响较小;③在1500~1600℃范围内,当金属中铬的质量分数小于20%时,在铬矿熔融还原法冶炼不锈钢母液条件下,含碳饱和的铁铬碳合金内不析出铬的碳化物.
参考文献
[1] | 重盛富士夫;川崎正洋;喜多村健治 .コ-ルドボソド鉱の製造ぉょび性状[J].铁と钢,1982,68(11):766. |
[2] | Ding Y L;Merchant A J .Kinetics and Mechanism of Smelting Reduction of Fluxed Chromite Part l Carbon-Chromite-Flux Composite Pellets in Fe-Cr-C-Si Melts[J].Ironmaking and Steelmaking,1999,26(04):247. |
[3] | Hino M;Higuchi K;Nagasaka T .Phase Equilibria and Activities of the Constituents in FeO@Cr2O3-MgO@Cr2O3 Spinel Solid Solution Saturated With Cr2O3[J].ISIJ International,1994,34(09):739. |
[4] | Xiao Y;Reuter M;Holappa L.Oxidation State of Cromium in Molten Slags[A].Stockholm,Sweden-Helsinki,Finlaod,2000 |
[5] | 刘岩,姜茂发,许力贤,刘承军,王德永.铬矿熔融还原不锈钢直接合金化的热力学分析[J].钢铁研究学报,2006(11):15-18. |
[6] | 邹宗树;张丽娟;刘爱华 等.熔融还原法铬合金的直接合金化[J].东北大学学报(自然科学版),1996,17(04):356. |
[7] | 梁英教;车荫昌.无机物热力学数据手册[M].沈阳:东北大学出版社,1993 |
[8] | Kobayashi Y;Morita K;Sano N .Thermodynamics of Molten Fe-Cr-Csmtd Alloy[J].ISIJ International,1996,36(08):1009. |
[9] | 陈四红,杨建,薛向欣,陈韧,崔志英.CaO-SiO2-Al2O3-MgO-Na2O-CrOx炉渣中铬氧化物间的氧化还原平衡[J].中国有色金属学报,2003(01):255-258. |
[10] | Kosyrev K L;Marushkin K N;Alikhanyan A S .Determining the Activity of the Components of the Slag System Formed in the Production of Chromium Alloys[J].Metallurgist,2003,47(9-10):353. |
[11] | 陈家祥.炼钢常用图表数据手册[M].北京:冶金工业出版社,1984 |
[12] | Yuki Nabeshima;Shigeru Ogura;Sumio Yamada .Construction of New Stainless Steelmaking Shop with Highly Flexible Raw Material Choice: Construction and Operation of No. 4 Steelmaking Shop at Chiba Works[J].Kawasaki Steel Technical Report,1997(37):42-50. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%