多相光催化"全"分解水制H2的研究已走过约40年路程,至今未获得真正的突破.目前国内、外发表的许多可见光催化牺牲体系放H2的文章,虽然它在氢离子还原机理方面有一定的参考意义,但它不能解决光催化"全"分解水制H2问题.本文提醒我国光催化界:勿把可见光牺牲体系产H2研究的结果,当成我们在分解水制H2方面取得的进展.应认真总结过去失败的经验教训,兼顾热力学和动力学两方面的要求,制订出正确的"全"分解水制H2催化剂的研究策略.
参考文献
| [1] | Frank E.Osterloh .Inorganic Materials as Catalysts for Photochemical Splitting of Water[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(1):35-54. |
| [2] | 马刚峰;李越湘;吕功煊.氧硫锌固溶体可见光制氢性能研究[A].上海,2008:MC301-MC335. |
| [3] | 金振声,李庆霖.微多相光催化的进展[J].感光科学与光化学,1987(02):49. |
| [4] | Jin Z S;Li Q L;Zheng X H et al.Surface properties of Pt-CdS andmechanism of photocatalytic dehydrogenation of aqueous alcohol[J].Journal of Photochemistry and Photobiology A:Chemistry,1993,71(01):85-96. |
| [5] | Jin Z S;Feng L B;Li Q L et al.Investigation of the relationship between molecular structure of aliphatic alcohols and their behaviorin photocatalytie dehydrogenationon Pt/CAS[J].Journal of Molecular Catalysis,1991,70(03):351-361. |
| [6] | Ningzhong Bao;Liming Shen;Tsuyoshi Takata .Self-Templated Synthesis of Nanoporous CdS Nanostructures for Highly Efficient Photocatalytic Hydrogen Production under Visible Light[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(1):110-117. |
| [7] | Abe Toshiyuki;Nagoshi Kentaro;Miyashita Kohichi;Kaneko Masao;Suzuki Eiji .Electron source in photoinduced hydrogen production on Pt-supported TiO2 particles[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,1999(7):1119-1123. |
| [8] | Kawai T;Sakata T .Conversion of carbohydrate into hydrDgen fuel by a photocatalytie process[J].Nature,1980,286:474-476. |
| [9] | Ma W H;Zhao J C .Visible-light-induced aerobic oxidation of alcohols in a coupled photocatalytie system of dye-sensitized TiO2 andTEMPO[J].Angewandte Chemie International Edition,2008,47(50):9730-9733. |
| [10] | Fujishima A;Honda K .Electrochemical phomlysis of water at a semiconductor electrode[J].Nature,1972,238:37-38. |
| [11] | Kiwi J;Gratzel M .Hydrogen evolution from water induced by visible light mediated by redox catalysis[J].Nature,1979,281:657-658. |
| [12] | Wagner F T;Somorjai G A .Photocatalytie hydrogen production from water on Pt-free SrTiO3 in alkali hydroxide solution[J].Nature,1980,285:559-560. |
| [13] | Zou Z;Ye J;Sayama K et al.Direct splitting of water under visible light irradiation with an oxide semiconductor photocatalyst[J].Nature,2001,414:625-627. |
| [14] | Maeda K;Teramura K;Lu D;Takata T;Saito N;Inoue Y;Domen K .Photocatalyst releasing hydrogen from water.[J].Nature,2006(7082):295-0. |
| [15] | Calvin M .Solar energy by photosynthesis[J].Science,1974,184:375-381. |
| [16] | Calvin M .Solar energy by photosynthesis:Manganese complex photolysis[J].Science,1974,185:376. |
| [17] | Khaselev O;Turner J A .A monolithic photovoltaie-phtoelectrochemical devices for hydrogen production via water splitting[J].Scqence,1998,280:425-432. |
| [18] | Khan S U M;Al-Shahry M;Ingler W B Jr .Efficient photochemical water splitting by a chemically modified n-TiO2[J].Science,2002,297:2243-2245. |
| [19] | Calvin M .Synthetic chloroplasts[J].Energy Research,1979,3(01):73-87. |
| [20] | Porter G .Fuel from water[J].Proc R Inst G B,1983,55(01):133-147. |
| [21] | Lehn J M;Sauvage J P;Ziessel R .Photochemical water splitting continuous generation hydrngen and oxygen by irradiation of aqueous suspension of metal loaded strontiumtitanate[J].Nouveau Journal de Chimie,1980,4(11):623-627. |
| [22] | Gai Y Q;Li J B;Lis S.Apassivated codoping approachfor enhanced photoelectrochernieal activity[J].Physical Review Letters,2009:036402-1-036402-4. |
| [23] | 石庆平;王闻声;吴鸣.光催化R&D的文献计量分布[A].辽宁大连,1998:7-10. |
| [24] | 葛堵根.光合作用--光子、激子、电子、质子、离子与光合膜之间的相互作用[M].合肥:安徽教育出版社,1991:1-7. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%