在水热条件下,利用H2biim(H2biim=2,2'-联咪唑)与金属离子Co“组装,得到一个结构新颖的混合价态CoⅡ/Ⅲ四核簇状配合物[Co4(H2biim)4(Hbiim)2(SO4)3]·3H2O (1),并对其进行元素分析、红外光谱、热重分析、拓扑分析、X-射线单晶衍射等测定.标题配合物属单斜晶系P21/c空间群,晶胞参数:a=1.23477 (6) nm,b=2.19524(13) nm,c =2.22162(9) nm,β=121.735(2)°,Z=4,V=5.1216 (4) nm3,Dc =1.779 g·cm-3,μ=1.486mm-1.X-射线单晶衍射分析表明四核簇状配合物1中H2biim配体分别以中性的H2biim配体和负一价的Hbiim-配体与钴离子配位,SO42-分别以单齿、三齿和四齿与钴离子配位,构成四核[Co4(SO4)6]2-簇,四核Co簇再进一步以[Co(H2biim) (Hbiim)2]+结构单元链接形成具有一维通道的三维孔洞结构.
参考文献
| [1] | Yan-Hong Xu;Ya-Qian Lan;Ya-Hui Zhao .Two novel supramolecular isomers based on 2,2'-biimidazole derivative and zinc ions: Syntheses, structures and luminescent properties[J].Inorganic Chemistry Communications,2009(2):169-172. |
| [2] | A.K.Cheetham;G.Ferey;T.Loiseau .Open-framework inorganic materials[J].Angewandte Chemie International Edition,1999(22):3268-3292. |
| [3] | Bradshaw D;Claridge JB;Cussen EJ;Prior TJ;Rosseinsky MJ .Design, chirality, and flexibility in nanoporous molecule-based materials[J].Accounts of Chemical Research,2005(4):273-282. |
| [4] | 夏金虹,刘峥,金黎霞,冯小珍.4,4'-联吡啶钴（Ⅱ）、铜（Ⅱ）配合物的合成及其晶体结构[J].人工晶体学报,2008(02):441-445,440. |
| [5] | Braga D.;Desiraju GR.;Grepioni F. .Crystal engineering and organometallic architecture [Review][J].Chemical Reviews,1998(4):1375-1405. |
| [6] | Li F;Li TH;Li XJ;Li X;Wang YL;Cao R .Synthesis of chiral coordination polymers by spontaneous resolution[J].Crystal growth & design,2006(6):1458-1462. |
| [7] | Chen XD;Du M;Mak TCW .Controlled generation of heterochiral or homochiral coordination polymer: helical conformational polymorphs and argentophilicityinduced spontaneous resolution[J].Chemical communications,2005(35):4417-4419. |
| [8] | Hou, L.;Zhang, W.-X.;Zhang, J.-P.;Xue, W.;Zhang, Y.-B.;Chen, X.-M. .An octacobalt cluster based, (3,12)-connected, magnetic, porous coordination polymer[J].Chemical communications,2010(34):6311-6313. |
| [9] | David J. Tranchemontagne;Jose L. Mendoza-Cortes;Michael O'Keeffe .Secondary building units, nets and bonding in the chemistry of metal-organic frameworks[J].Chemical Society Reviews,2009(5):1257-1283. |
| [10] | Cui Y;Niu YL;Cao ML;Wang K;Mo HJ;Zhong YR;Ye BH .Ruthenium(II) 2,2 '-bibenzimidazole complex as a second-sphere receptor for anions interaction and colorimeter[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2008(13):5616-5624. |
| [11] | 单核Co（Ⅱ）含氮配体配合物[CO（py）3（H2O）3]（1,5-nds）的合成、晶体结构及热稳定性[J].人工晶体学报,2012(06):1785-1788,1792. |
| [12] | 陶兆林,梁丽丽,薛洪宝.基于4,4′-二（苯并咪唑-1-甲基）联苯及邻苯二甲酸配体的新型配合物[Co（bbmb）（Pht）]n的合成、晶体结构和性质[J].人工晶体学报,2012(05):1478-1482. |
| [13] | Laura Ion;Dolores Morales;Julio Perez;Lucia Riera;Victor Riera .Ruthenium biimidazole complexes as anion receptors[J].Chemical communications,2006(1):91-93. |
| [14] | Hannibal L;Bunge SD;van Eldik R;Jacobsen DW;Kratky C;Gruber K;Brasch NE .X-ray structural characterization of imidazolylcobalamin and histidinylcobalamin: Cobalamin models for aquacobalamin bound to the B-12 transporter protein transcobalamin[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2007(9):3613-3618. |
| [15] | Qu XS;Xu L;Gao GG;Li FY;Yang YY .Unprecedented eight-connected self-catenated network based on heterometallic {Cu4V4O12} clusters as nodes[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2007(12):4775-4777. |
| [16] | 杜秀红,崔节虎,赵俊伟.配位聚合物{[Co3（TCOPM）2（H2O）2]·17H2O}n的合成和结构[J].人工晶体学报,2014(03):723-726. |
| [17] | Karotsis G;Jones LF;Papaefstathiou GS;Collins A;Parsons S;Nguyen TD;Evangelisti M;Brechin EK .Rare tetranuclear mixed-valent [(Mn2Mn2IV)-Mn-II] clusters as building blocks for extended networks[J].Dalton transactions: An international journal of inorganic chemistry,2008(36):4917-4925. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%