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用共沉淀法合成了用铝掺杂的铁部分取代锰的富锂正极材料Li[Li0.2Mn0.4Fe0.3Al0.1]O2.采用XRD、SEM、电化学测试等方法对样品进行表征.结果表明,与Li[Li0.2Mn0.45Fe0.35]O2相比,Li[Li0.2Mn0.4Fe0.3Al0.1]O2具有较好的电化学性能,其初始容量达到241 mAh/g左右,经50次充放电循环后,容量衰减率在7%左右.

参考文献

[1] Michael M. Thackeray;Sun-Ho Rang;Christopher S. Johnson .Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2007(30):3112-3125.
[2] Johnson CS;Li NC;Lefief C;Thackeray MM .Anomalous capacity and cycling stability of xLi(2)MnO(3)center dot(1-x)LiMO2 electrodes (M = Mn, Ni, Co) in lithium batteries at 50 degrees C[J].Electrochemistry communications,2007(4):787-795.
[3] Hyun-Kon Song;Kyu Toe Lee;Min Cyu Kim;Linda F. Nazar;Jaephil Cho .Recent Progress in Nanostructured Cathode Materials for Lithium Secondary Batteries[J].Advanced functional materials,2010(22):3818-3834.
[4] Johnson CS;Kim JS;Lefief C;Li N;Vaughey JT;Thackeray MM .The significance of the Li2MnO3 component in 'composite' xLi(2)MnO(3) center dot (1-x)LiMn0.5Ni0.5O2 electrodes[J].Electrochemistry communications,2004(10):1085-1091.
[5] Y. Wu;A. Manthiram .High Capacity, Surface-Modified Layered Li[Li_((1-x)/3)Mn_((2-x)/3)Ni_(x/3)Co_(x/3)]O_2 Cathodes with Low Irreversible Capacity Loss[J].Electrochemical and solid-state letters,2006(5):A221-A224.
[6] Kobayashi, H.;Takenaka, Y.;Arachi, Y.;Nitani, H.;Okumura, T.;Shikano, M.;Kageyama, H.;Tatsumi, K..Study on Li de-intercalation/intercalation mechanism for a high capacity layered Li _(1.20)Ni _(0.17)Co _(0.10)Mn _(0.53)O _2 material[J].Solid state ionics,2012:580-584.
[7] Tabuchi M;Nabeshima Y;Ado K et al.Material design concept for Fe-substituted Li2MnOa-based positive electrodes[J].Journal of Power Sources,2007,174(02):554.
[8] Kikkawa J;Akita T;Tabuchi M;Shikano M;Tatsumi K;Kohyama M .Fe-rich and Mn-rich nanodomains in Li1.2Mn0.4Fe0.4O2 positive electrode materials for lithium-ion batteries[J].Applied physics letters,2007(5):54103-1-54103-3-0.
[9] Kim J S;Johnson C S;Vaughey J T et al.Electrochemical and structural properties of x Li2MnO3·(1-x) LiMn0.5-Ni0.5 O2 electrodes for lithium batteries (M=Ti,Mn,Zr; 0≤x≤0.3)[J].Chemistry of Materials,2004,16(10):1996.
[10] Jun Kikkawa;Tomoki Akita;Mitsuharu Tabuchi;Masahiro Shikano;Kuniaki Tatsumi;Masanori Kohyama .Coexistence of layered and cubic rocksalt structures with a common oxygen sublattice in Li_(1.2)Mn_(0.4)Fe_(0.4)O_(2) particles: A transmission electron microscopy study[J].Journal of Applied Physics,2008(10):104911-1-104911-10-0.
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