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近来,聚合物热电材料因其成本低、资源丰富、热导率低等优势被认为是最有前途的热电材料之一.聚噻吩及其衍生物是研究较为广泛的一类聚合物热电材料.综述了近年来聚噻吩、聚噻吩衍生物以及聚噻吩基/无机复合热电材料在热电领域的研究进展.已有研究表明,聚噻吩及其衍生物热电材料具有高的Seebeck系数,其Seebeck系数与电导率通常是此消彼长的关系.通过制备低维材料,与高电导率的无机纳米材料复合以及适度掺杂等方法可有效提高聚噻吩及其衍生物的热电性能.

参考文献

[1] DiSalvo F J .Thermoelectric cooling and power generation[J].Science,1999,285(5428):703.
[2] Gonalves L M;Couto C;Alpuim P et al.Thermoelectric properties of Bi2Te3/Sb2Te3 thin films[J].Trans Techn Publ,2006,514:156.
[3] Venkatasubramanian R;Siivola E;Colpitts T et al.Thinfilm thermoelectric devices with high room temperature figures of merit[J].Nature,2001,413:597.
[4] Heremans J P;Jovovic V;Toberer E S et al.Enhancement of thermoelectric efficiency in PbTe by distortion of the electronic density of states[J].Science,2008,321:554.
[5] Gumeniuk R;Schneich M;Leithe J A et al.High pressure synthesis and exotic heavy-fermion behaviour of the filled skutterudite SmPt4 Gel2[J].New Journal of Physics,2010,12:103035.
[6] Harman T;Walsh M;Laforge B et al.Nanostructured thermoelectric materials[J].Journal of Electronic Materials,2005,34:19.
[7] Ismail K;Nelson S F;Chu J O et al.Electron transport properties of Si/SiGe heterostructures:Measurements and device implications[J].Applied Physics Letters,2009,63(05):660.
[8] Fischetti M V;Laux S E .Band structure,deformation potentials,and carrier mobility in strained Si,Ge,and SiGe alloys[J].Journal of Applied Physics,2009,80(04):2234.
[9] Bell L E .Cooling,heating,generating power,and recove ring waste heat with thermoelectric systems[J].Science,2008,321:1457.
[10] Shinohara Y;Ohara K;Imai Y.Problems of conduc tive polymers as thermoelectric materials[A].La Grande Motte:IEEE,2004:298.
[11] 王雷,王大刚,敖伟琴,朱光明,潘锋,李均钦.导电聚合物热电材料研究进展[J].高分子通报,2010(11):55-62.
[12] Li Junjie;Tang Xinfeng;Li Han et al.Synthesis and thermoelectric properties of hydrochloric acid-doped polyaniline[J].Synthetic Metals,2010,160(1-2):1153.
[13] Chuizhou Meng;Changhong Liu;Shoushan Fan .A Promising Approach to Enhanced Thermoelectric Properties Using Carbon Nanotube Networks[J].Advanced Materials,2010(4):535-539.
[14] Kemp NT;Kaiser AB;Trodahl HJ;Chapman B;Buckley RG;Partridge AC;Foot PJS .Effect of ammonia on the temperature-dependent conductivity and thermopower of polypyrrole[J].Journal of Polymer Science, Part B. Polymer Physics,2006(9):1331-1338.
[15] Chiang C K;Gau S C;Fincher C R et al.Polyacetylene,(CH) n:n-type and p-type doping and compensation[J].Applied Physics Letters,2009,33(01):18.
[16] Shinohara Y;Isoda Y;Imai Y.The effect of carrier conduction between main chains on thermoelectric properties of polythiophene[A].Korea,2007
[17] Y. Xuan;X. Liu;S. Desbief;P. Leclere;M. Fahlman;R. Lazzaroni;M. Berggren;J. Cornil;D. Emin;X. Crispin .Thermoelectric properties of conducting polymers: The case of poly(3-hexylthiophene)[J].Physical review, B. Condensed matter and materials physics,2010(11):115454:1-115454:9.
[18] Hiraishi K;Masuhara A;Nakanishi H et al.Evaluation of thermoelectric properties of polythiophene films synthesis by electrolytic polymerization[J].Japanese Journal of Applied Physics,2009,48(07):0715011.
[19] 胡玥,刘彦军.导电高分子聚噻吩及其衍生物的研究进展[J].材料导报,2006(01):64-68.
[20] Yamamoto T;Abe M;Wu B et al.Preparation of thermostable and electrical conducting poly (2,5-thienylene)[J].Journal of Polymer Science Part C:Polymer Letters,1980,18:9.
[21] Kili G B;Toppare L;Yurtsever E .Structural studies of polythiophenes[J].Synthetic Metals,1996,78(01):19.
[22] Themans B;Andre J M;Bredas J L .Electronic structure of the alkyl,benzyl and methoxy derivatives of polythiophene[J].Synthetic Metals,1987,21(1-3):149.
[23] Bak B;Christensen D;Hansen N L et al.The structure of thiophene[J].Journal of Molecular Spectroscopy,1961,7(1-6):58.
[24] 杜永,蔡克峰.聚噻吩及其衍生物、聚噻吩基复合材料的导电性能研究进展[J].材料导报,2010(21):69-73.
[25] 何有军,侯剑辉,范慧俐,李永舫.支链带有富勒烯的聚噻吩和齐聚噻吩及其光伏电池研究进展[J].化学通报(印刷版),2007(04):248-256.
[26] 佟拉嘎,王锦艳,蹇锡高,张庆民.烷基取代聚噻吩的化学合成与光电性能研究进展[J].功能高分子学报,2004(03):535-541.
[27] 黄佳乐,刘平,邓文基,麦裕良,栾安博.有机噻吩类衍生物液晶材料的研究进展[J].河南科学,2008(04):409-414.
[28] Bubnova O;Kha Z U;Malti A et al.Optimization of the thermoelectric figure of merit in the conducting polymer poly (3,4-ethylenedioxythiophene)[J].Nature Materials,2011,10:429.
[29] Sterholm J E;Passiniemi P;Isotalo H et al.Synthesis and properties of FeCl4-doped polythiophene[J].Synthetic Metals,1987,18(1-3):213.
[30] Masubuchi S.;Kazama S. .INTRINSIC TRANSPORT PROPERTIES IN ELECTROCHEMICALLY PREPARED POLYTHIOPHENE DOPED WITH PF6-[J].Synthetic Metals,1995(2):151-158.
[31] Lu B Y;Liu C C;Lu S et al.Thermoelectric performances of free-standing polythiophene and poly (3-methylthiophene)[J].Chinese Physics Letters,2010,27(05):057201.
[32] 佟拉嘎,蹇锡高,藤井彰彦,吉野胜美.烷基和烷氧基取代聚噻吩的合成、表征与光电性能[J].高分子学报,2004(05):628-633.
[33] Shinohara Y;Ohara K;Nakanish H et al.Thermoelectric properties of poly(3-alkylthiophenes)[J].Materials Science Forum,2005,492:141.
[34] Amit Babel;Samson A. Jenekhe .Alkyl chain length dependence of the field-effect carrier mobility in regioregular poly(3-alkylthiophene)s[J].Synthetic Metals,2005(2):169-173.
[35] Masubuchi S.;Yamazaki K.;Kazama S.;Takada J.;Matsuyama T.;Imai R. .Structure and electrical transport property of poly(3-octylthiophene)[J].Synthetic Metals,1999(1/3):594-595.
[36] Sun, J;Yeh, ML;Jung, BJ;Zhang, B;Feser, J;Majumdar, A;Katz, HE .Simultaneous Increase in Seebeck Coefficient and Conductivity in a Doped Poly(alkylthiophene) Blend with Defined Density of States[J].Macromolecules,2010(6):2897-2903.
[37] JIANG Feng-Xing,XU Jing-Kun,LU Bao-Yang,XIE Yu,HUANG Rong-Jin,LI Lai-Feng.Thermoelectric Performance of Poly(3,4-ethylenedioxythiophene): Poly(styrenesulfonate)[J].中国物理快报(英文版),2008(06):2202-2205.
[38] CONGCONG LIU;FENGXING JIANG;MINGYU HUANG;RUIRUI YUE;BAOYANG LU;JINGKUN XU;GUODONG LIU .Thermoelectric Performance of Poly(3,4-Ethylenedioxy-thiophene)/Poly(Styrenesulfonate) Pellets and Films[J].Journal of Electronic Materials,2011(5):648-651.
[39] KUEI-CHIEN CHANG;MING-SHAN JENG;CHANG-CHUNG YANG;YA-WEN CHOU;SHIH-KUO WU;MARIN ANDREW THOMAS;YEN-CHUN PENG .The Thermoelectric Performance of Poly(3,4-ethylenedi-oxythiophene)/Poly(4-styrenesulfonate) Thin Films[J].Journal of Electronic Materials,2009(7):1182-1188.
[40] Taggart, D.K.;Yang, Y.;Kung, S.-C.;McIntire, T.M.;Penner, R.M. .Enhanced thermoelectric metrics in ultra-long electrodeposited PEDOT nanowires[J].Nano letters,2011(1):125-131.
[41] Feng J.;Ellis TW. .Thermal management for semiconductor devices with conductive polymers[J].Synthetic Metals,2003(1/3):155-156.
[42] Eniko Pinter;Zoltan A. Fekete;Otto Berkesi;Peter Makra;Csaba Visy .Characterization of Poly(3-octylthiophene)/Silver Nanocomposites Prepared by Solution Doping[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(32):11872-11878.
[43] Kim, D.;Kim, Y.;Choi, K.;Grunlan, J.C.;Yu, C. .Improved thermoelectric behavior of nanotube-filled polymer composites with poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate)[J].ACS nano,2010(1):513-523.
[44] B. Zhang;J. Sun;H. E. Katz .Promising Thermoelectric Properties of Commercial PEDOT:PSS Materials and Their Bi2Te3 Powder Composites[J].ACS applied materials & interfaces,2010(11):3170-3178.
[45] Wang Y Y;Cai K F;Yao X .Facile fabrication and thermoelectric properties of PbTe-modified poly (3,4 ethylenedioxythiophene) nanotubes[J].ACS Appl Mater Interf,2011,3:1163.
[46] Sun Z;Liu F S;Yao Q et al.Materials low temperature synthesis of Bi2Te3 nanosheets and thermal conductivity of nanosheet-contained composites[J].Chemical Physics,2010,121(1-2):138.
[47] Lei Wang;Dagang Wang;Guangming Zhu;Junqin Li;Fred Pan .Thermoelectric properties of conducting polyaniline/graphite composites[J].Materials Letters,2011(7):1086-1088.
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