介绍了可降解高吸水树脂的分类(天然高吸水树脂、改性高吸水树脂、合成高吸水树脂)、制备方法(水溶液聚合法、反相悬浮聚合法、本体聚合法等)、可降解性能的改进方法(在合成高分子中引入易生物降解的化学键,以各种天然可降解的聚合物为原料来合成以改善其可降解性能、接枝或共混的方式)以及在不同领域里的应用,详细阐述了近年来可降解高吸水树脂的研究进展,并对其在今后的研究和开发提出了建议和展望.
参考文献
[1] | 王丹,商士斌,宋湛谦.高吸水树脂耐盐性的改进方法[J].东北林业大学学报,2006(02):95-97. |
[2] | 董奋强,崔英德,崔亦华,秦建忠.蛋白高吸水凝胶研究的进展[J].材料导报,2006(07):46-50. |
[3] | Rathna C V N;Srinivasan D .Effect of nonprotein polymers on water-uptake properties of fish protein-based hydrogen[J].Journal of Applied Polymer Science,2002,85(01):45. |
[4] | Rathna C V N;Srinivasan D .Swelling behavior of proteinbased super absorbent hydrogels treated with ethano[J].Journal of Applied Polymer Science,2001,81(09):2190. |
[5] | 袁毅 .可降解高分子吸水树脂的研究[D].宁夏大学,2010. |
[6] | 刘玲秀 .可生物降解高吸水树脂的制备[D].青岛科技大学,2011. |
[7] | Zhang J P;Wang L;Wang A Q .Preparation and swelling behavior of fast-swelling superabsorbent hydrogels based on starch-g-poly(acrylic acid-co-sodium acrylate)[J].Macromolecular Materials and Engineering,2006,291:612. |
[8] | 董奋强,崔英德,胡军楚,何春林,李妮妮.明胶-丙烯酸-丙烯酰胺可降解高吸水树脂的制备[J].现代化工,2007(11):48-50. |
[9] | 赵妍嫣 .甘薯淀粉基高吸水树脂的合成及性质研究[D].合肥工业大学,2007. |
[10] | Doo-won L;Kyong-geun S;Kee-jong Y .Synthesis of acrylacid-based superabsorbent interpenetrated with sodium PVA sulfate using inverse-emulsion polymerization[J].European Polymer Journal,2002,38:579. |
[11] | Li Y F;Li X Z;Zhou L C .Study on the synthesis and application of salt-resisting polymeric hydrogels[J].Polymers For Advanced Technologies,2004,15:34. |
[12] | Heidel K;Krause F;Hofmann P .Process for the preparation of finely divided,water-swellable polysaccharide graft polymers[P].US,5180800,1993. |
[13] | Wichterle O;Lim D .Hydrophilic,swellable polymeric structure[J].Nature,1960,185:117. |
[14] | 张小红,崔英德,潘湛昌.聚丙烯酸/海藻酸钠高吸水性树脂的制备及生物降解性能[J].化工学报,2005(06):1134-1137. |
[15] | 邹新禧.超强吸水剂[M].北京:化学工业出版社,1991:31. |
[16] | Aiqin Hou;Xiaojun Wang;Lianghua Wu .Effect of microwave irradiation on the physical properties and morphological structures of cotton cellulose[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2008(4):934-937. |
[17] | 喻发全,刘艳萍,黄世英,姚树人.紫外光引发淀粉接枝丙烯腈反应动力学的研究[J].高分子材料科学与工程,1999(05):62-65. |
[18] | Junping Zhang;Qin Wang;Aiqin Wang .Synthesis and characterization of chitosan-g-poly(acrylic acid)/attapulgite superabsorbent composites[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2007(2):367-374. |
[19] | Zhang JP;Wang L;Wang AQ .Preparation and properties of chitosan-g-poly(acrylic acid)/montmorillonite superabsorbent nanocomposite via in situ intercalative polymerization[J].Industrial & Engineering Chemistry Research,2007(8):2497-2502. |
[20] | Ali P;Vagrik A;Hossein G .Synthesis,characterization and swelling behavior of chitosan-sucrose as a novel full-polysaccharide superabsorbent hydrogel[J].Journal of Applied Polymer Science,2008,109:2648. |
[21] | Prafulla K;Sahoo Pradeep K;Rana .Synthesis and biodegradability of starch-g-ethyl methacrylate/sodium acrylate/sodium silicate superabsorbing composite[J].Journal of Materials Science,2006,41:6470. |
[22] | 李仲谨;王磊;赖小娟 .海藻接枝丙烯酸高吸水性树脂的制备及性能研究[J].化工新型材料,2006,34(z1):52. |
[23] | Pratish V D;Manish P P;Ranjan G P .Swelling and dye adsorption study of novel superswelling hydrogels[J].J Polym Bull,2006,57:21. |
[24] | 杜太生;康绍忠;魏华.保水剂在节水农业中的应用研究与展望[J].农业现代化研究,2005(05):28. |
[25] | 崔英德,郭建维,易国斌,崔亦华,贾振宇.可生物降解超强吸水剂及其制备技术进展[J].化工进展,2003(08):845-849. |
[26] | Brune D .The global environment-science[J].Techn Manag,1997,2(03):1157. |
[27] | Welford R .Tools of corporate environment management eartbscan publication limited[J].Journal of Biochemisitry,1996,8:140. |
[28] | Scott G;Gilead D.Degradable polymers applications[M].London:Chapman and Hall,1995:217. |
[29] | 戈进杰.生物降解高分子材料[M].北京:化学工业出版社,2002:12. |
[30] | 周明,杨燕,代加林,周松.淀粉接枝丙烯酰胺和丙烯酸/蒙脱土纳米复合吸水材料的合成[J].高分子材料科学与工程,2008(11):36-39. |
[31] | Oerther S;Gall H L;Payan E .Hyalurnate-alginate gel as a novel biomaterial.mechanical properties and formation mechanical properties and formation mechanism[J].Biotechnology and Bioengineering,1999,63(02):210. |
[32] | Kunioka M.;Choi HJ. .Hydrolytic degradation and mechanical properties of hydrogels prepared from microbial poly(amino acid)s[J].Polymer Degradation and Stability,1998(1/3):33-37. |
[33] | Du L C;Meng Y Z;Wang S J .Synthesis and degradation behavior of poly derived from carbon dioxide and propylene oxide[J].Journal of Applied Polymer Science,2003,42(06):5. |
[34] | Errington J;Sporulation B .Regulation of gene expression and control of morphogensis[J].Microbiological Reviews,1993,57(01):1. |
[35] | 姚金水;任华荣 .丙烯酰胺与玉米淀粉接枝共聚物的合成及其吸水性能研究[J].离子交换与吸附,1998,14(03):242. |
[36] | 柳明珠;吴靖嘉;义建军 .丙烯酰胺与洋芋淀粉接枝共聚物的合成及其超高吸水性能研究[J].高分子材料科学与工程,1991,8(04):19. |
[37] | David C;De Kesel C .The biodegradation of polymers[J].Die Angewandte Makromolekulare Chemie,1994,216:21. |
[38] | Hara;Toshio .Biodegradable water absorbing poly(g-glutamic acid)resins and method for their manufacture[P].JP,10251402,1998. |
[39] | Sukegawa;Makoto .Manufacture of poly(amino acid) particles with narrow particle size distribution and their uses as water absorbents[P].JP,11240958,7,1999. |
[40] | Ishisaki;Kunihiko .Water-absorbing crosslinked acidic amino acid polymers and their manufacture[P].JP,11060728,1999. |
[41] | 陕西科技大学 .土壤改良型保水剂的合成方法[P].中国,03114579.5,2003-10-08. |
[42] | 李东万 .一种高效保水剂及其应用[P].中国,200510111764.3,2007-05-16. |
[43] | K Mohana Raju;M Padmanabha Raju;Y Murali Mohan .Synthesis of superabsorbent copolymers as water manageable materials[J].Polymer international,2003(5):768-772. |
[44] | Jun Yang;Fang Wang;Li Fang;Tianwei Tan .Synthesis, characterization and application of a novel chemical sand-fixing agent-poly(aspartic acid) and its composites[J].Environmental Pollution,2007(1):125-130. |
[45] | 张志军,李会珍,乔绍俊,张鑫,李胜彬.生物保水种衣剂对蔬菜种子发芽及幼苗生理特性的影响[J].种子,2010(03):36-38. |
[46] | HE Xu-sheng,LIAO Zong-wen,HUANG Pei-zhao,DUAN Ji-xian,GE Ren-shan,LI Hong-bo,GENG Zeng-chao.Characteristics and Performance of Novel Water-Absorbent Slow Release Nitrogen Fertilizers[J].中国农业科学(英文版),2007(03):338-346. |
[47] | Andry, H;Yamamoto, T;Irie, T;Moritani, S;Inoue, M;Fujiyama, H .Water retention, hydraulic conductivity of hydrophilic polymers in sandy soil as affected by temperature and water quality[J].Journal of Hydrology,2009(1/2):177-183. |
[48] | Mo C;Shu-Quan Z;Hua-Min L .Synthesis of poly(acrylic acid)/sodium humate superabsorbent composite for agri-cultural use[J]][J].Journal of Applied Polymer Science,2006,102(06):5137. |
[49] | Jianghua Liu;Qin Wang;Aiqin Wang .Synthesis and characterization of chitosan-g-poly(acrylic acid)/sodium humate superabsorbent[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2007(2):166-173. |
[50] | Chen Yu;Liu Yun-fei;Tan Hui-min .Synthesis and characterization of a novel superabsorbent polymer of N,O-carboxymethyl chitosan graft copolymerized with vinyl monomers[J].Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides,2009(2):287-292. |
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