本文以Al(OH)3和H3PO4为原料,研究了磷酸盐粘结剂的最佳合成条件,探讨了P/Al配比和反应温度对Al(H2PO4)3的形成以及填料的加入对粘结剂耐热性的影响,利用XRD和TGDSC对粘结剂晶体结构和涂层热性能进行了分析.结果表明:P/Al比例为3∶1.4,合成温度在120～200℃范围内,可获得性能较好的Al(H2PO4)3粘结剂.填料的加入有利于粘结剂表面吸附水的蒸发和磷酸盐基体分子间结晶水的脱除,提高了涂层的热稳定性和耐高温性能.
参考文献
| [1] | 周锡荣,唐绍裘,周武艺.新型无机涂料的制备及其应用[J].山东陶瓷,2004(01):17-20. |
| [2] | 肖泽辉,冀运东,罗吉荣,吴执成.磷酸铝铸铁高温涂料的研制[J].现代铸铁,2003(02):53-55. |
| [3] | 冯莉,段慎修,刘辉.磷酸盐耐热涂料的研制[J].涂料工业,2002(08):14-16. |
| [4] | He LP;Chen DC;Shang SP .Fabrication and wear properties of Al2O3-SiC ceramic coatings using aluminum phosphate as binder[J].Journal of Materials Science,2004(15):4887-4892. |
| [5] | Vippola M.;Keranen J. .Structural characterization of aluminum phosphate binder[J].Journal of the American Ceramic Society,2000(7):1834-1836. |
| [6] | Vippola M.;Ahmaniemi S.;Keranen J.;Vuoristo P.;Lepisto T.;Mantyla T. Olsson E. .Aluminum phosphate sealed alumina coating: Characterization of microstructure[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2002(1/2):1-8. |
| [7] | 熊桂蓉,胡爱琼,张建新.TW-208无机磷酸盐防腐涂料的性能及施工应用[J].现代涂料与涂装,2008(03):45-48. |
| [8] | Hye-Jung Han;Dong-Pyo Kim .Studies on curing chemistry of aluminum-chromium-phosphates as low temperature curable binders[J].Journal of Sol-Gel Science and Technology,2003(1/2/3):223-228. |
| [9] | Maier CR;Jones LE .The influence of aluminum phosphates on graphite oxidation[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(11):2272-2276. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%