欢迎登录材料期刊网

材料期刊网

高级检索

通过微波乙二醇法制备了Pt/CeO2/CNTs催化剂用于碱性体系中的甲醇电催化氧化,考察了不同的CeO2含量对其电催化活性的影响.X射线衍射(XRD)和透射电镜(TEM)结果表明,Pt/CeO2/CNTs催化剂中Pt颗粒较小,在载体上分散性较好.循环伏安曲线和计时电流测试结果表明,Pt/CeO2/CNTs催化剂表现出良好的甲醇电催化氧化性能,当Pt与CeO2质量比为1:0.5时,催化剂电化学活性面积为76.3 m2·g -1,甲醇氧化峰电流密度值为12.95 mA·cm-2.Pt和CeO2之间的协同作用促进了Pt/CeO2/CNTs催化剂的甲醇电催化氧化性能.

参考文献

[1] Zainoodin A M;Kamarudin S K;Daud W R W .Electrode in direct methanol fuel cell[J].International Journal of Hydrogen Energy,2010,35:4606.
[2] Liu H S;Song C J;Zhang L;Zhang J J Wang H J Wilkinson D P .A review of anode catalysis in the direct methanol fuel cell[J].Journal of Power Sources,2006,155:95.
[3] Shen P K;Xu C W;Zeng R;Liu Y L .Electrooxidation of methanol on NiO-promoted Pt/C and Pd/C catalysts[J].Electrochemical and Solid-State Letters,2006,9:39.
[4] Yuan H P;Guo D J;Qi X P;Zhu W T Chen L Q .Influence of metal oxides on Pt catalysts for methanol electrooxidation sing electrochemical impedance spectroscopy[J].Journal of Power Sources,2009,188:8.
[5] Justin P;Ranga R G .Enhanced activity of methanol electro-oxidation on Pt-V2O5/C catalysts[J].Catalysis Today,2009,141:138.
[6] 林叶,张世超.多壁碳纳米管负载高分散Pt-PrxCe1-xO2-δ复合催化剂对甲醇的电催化氧化作用研究[J].中国稀土学报,2009(04):464-469.
[7] Zou Z Q;Meng M;Guo L H;Zha Y Q .Synthesis and characterization of CuO/Ce1-xTixO2 catalysts used for low-temperature CO oxidation[J].Journal of Hazardous Materials B:Environmental Technologies,2009,163(02):853.
[8] 毛东森,陶丽华,王倩,郭杨龙,卢冠忠.CuO-CeO_2的固相反应法制备及其催化CO低温氧化性能[J].无机化学学报,2010(03):447-452.
[9] Wan H Q;Li D;Dai Y;Hu Y H Zhang Y H Liu L J Zhao B Liu B Sun K Q Dong L Chen Y .Effect of CO pretreatment on the performance of CuO/CeO2/γ-Al2O3 catalysts in CO + O2reaction[J].Applied Catalysis A:General,2009,1(31):26.
[10] Yuelan Zhang;Shaowu Zha;Meilin Liu .Dual-Scale Porous Electrodes for Solid Oxide Fuel Cells from Polymer Foams[J].Advanced Materials,2005(4):487-491.
[11] 郝仕油,黎胜.CeO2形态对CeO2/Au电极催化氧化乙醇的影响[J].中国稀土学报,2009(04):496-500.
[12] Lin D H;Lee W D;Chio D H;Lee H I .Effect of Ceria Nanoparti-clesinto the Pt/C Catalyst as Cathode Mate-rial on Electrocatalytic Activity and Durability for Low-temperature Fuel Cell[J].Applied Catalysis B:Environmental,2010,94:85.
[13] Spendelow J;Andrzej W .Electro-catalysis of oxygen reductionand small alcohol oxidation in alkaline media[J].Physical Chemistry Chemical Physics,2007,9:2654.
[14] Xu C W;Zeng R;Shen P K;Wei Z D .Synergistic effect of CeO2 modified Pt/C catalysts on the alcohols oxidation[J].Electrochimica Acta,2005,51:1031.
[15] 吴伟,曹洁明,陈煜,刘劲松,曹喻霖,房宝青,何建平,唐亚文,杨春,陆天虹.室温制备高合金化Pt-Ru/CMK-3催化剂及其对甲醇的电催化氧化[J].高等学校化学学报,2006(12):2394-2397.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%