采用原位脱氯化氢缩合聚合法制备了聚（2-甲氧基-5-辛氧基）对苯乙炔/二元稀土配合物Eu（phen）2Cl3（PMO-COPV/Eu（phen）2Cl3）杂化材料。红外光谱证实了在Eu（phen）2Cl3表面的包覆层为PMOCOPV。紫外-可见吸收光谱表明与PMOCOPV相比,PMOCOPV/Eu（phen）2Cl3的最大吸收峰发生红移且强度增强。荧光光谱研究表明PMOCOPV/Eu（phen）2Cl3的最大发射波长发生红移且强度增强,荧光寿命得到提高,Eu（phen）2Cl3与PMOCOPV之间形成了光致电子转移体系,使得π电子离域程度增加,导致荧光量子效率提高。
The photoelectric hybrid material poly（2-methoxy-5-octyloxy）-p-phenylene vinylene/Eu（phen）2Cl3（PMOCOPV/Eu（phen）2Cl3） was prepared by a dehydrochlorination in situ polymerization.Results from Fourier transform infrared spectroscopy indicate that PMOCOPV is coated onto the surface of Eu（phen）2Cl3.Compared with PMOCOPV,the absorption of PMOCOPV/Eu（phen）2Cl3 is strengthened,and a red shift of the absorption peak can be clearly observed in the UV-Vis spectrum.Photoluminescence spectroscopy indicates that the maximum emission wavelength of the PMOCOPV/Eu（phen）2Cl3 is red-shifted and intensity of photoluminescence increases in comparasion with PMOCOPV.PMOCOPV/Eu（phen）2Cl3 shows increased fluorescence due to an intermolecular photo-induced charge transfer process.
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