欢迎登录材料期刊网

材料期刊网

高级检索

The research on the sintered Sm2Co17 permanent magnets prepared by metal injection molding is still at the exploratory stage. Carbon and oxygen are two key factors that influence the magnetic properties. In this article, the effects of oxygen and carbon on the properties and microstructure of the magnets have been studied. The results indicate that oxygen consumes the effective Sm content of the magnets and forms Sm2O3-the non-magnetism phase, which result in the deterioration of the magnetic properties. Besides, the magnetic properties decrease in evidence with increasing carbon content. The main factor that affects the magnetic properties is the deterioration of the microstructure of the magnets. The Sm(Co, Cu)5 phase decreases, whereas the cell size increases with the increase of the carbon content. When the carbon content is above 0.43 wt.%, the Sm(Co, Cu)5 phase is not enough to form a uniform cellular microstructure. Thus the magnetic properties disappear. ZrC is detected in the magnets by XRD when the carbon content is above 0.21 wt.%. ZrC also reduces the properties of the magnets.

参考文献

[1] Schobinger D.;Gutfleisch O.;Hinz D.;Muller KH.;Schultz L.;Martinek G. .High temperature magnetic properties of 2 : 17 Sm-Co magnets[J].Journal of Magnetism and Magnetic Materials,2002(2):1347-1349.
[2] Zhang Y.;Hadjipanayis GC.;Liu JF.;Walmer MS.;Krishnan KM.;Corte-Real M. .Magnetic hardening studies in sintered Sm(Co,Cu-x,Fe,Zr)(z) 2 : 17 high temperature magnets[J].Journal of Applied Physics,2000(9 Pt.3):6722-6724.
[3] Liu JF.;Dimitrov D.;Hadjipanayis GC.;Chui T. .Abnormal temperature dependence of intrinsic coercivity in Sm(Co, Fe, Cu, Zr)(z) powder materials[J].Applied physics letters,1998(20):3007-3009.
[4] Christina H. Chen;Marlin S. Walmer;Michael H. Walmer .Magnetic pinning strength for the new Sm-TM magnetic materials for use up to 550℃[J].Journal of Applied Physics,2000(9):6719-6721.
[5] Moballegh L;Morshedian J;Esfandeh M .Copper injection molding using a thermoplastic binder based on paraffin wax[J].Materials Letters,2005,59:2832.
[6] Li S L;Huang B Y;Li Y M .A new type of binder for metal injection molding[J].Journal of Materials Processing Technology,2003,137:70.
[7] Marlin S. Walmer;Christina H. Chen;Michael H. Walmer .A New Class of Sm-TM Magnets for Operating Temperatures Up to 550℃[J].IEEE Transactions on Magnetics,2000(5):3376-3381.
[8] Liu S;Yang J;Doyle G .New sintered high temperature Sm-Co based permanent materials[J].IEEE Transactions on Magnetics,1999,35(05):3325.
[9] Fidler J;Skalicky P .Microstructure of precipitation hardened cobalt rare earth permanent magnets[J].Journal of Magnetism and Magnetic Materials,1982,27:127.
[10] Rabenberg L;Mishra R K;Thomas C .Microstructures of precipitation-hardened SmCo permanent magnets[J].Journal of Applied Physics,1982,53:2389.
[11] Liu J.F.;Zhang Y.;Dimitrov D.;Hadjipanayis G.C. .Microstructure and high temperature magnetic properties of Sm(Co, Cu, Fe, Zr)_z (z = 6.7-9.1) permanent magnets[J].Journal of Applied Physics,1999(5):2800-0.
[12] Liu S.;Doyle G.;Yang J.;Kuhl GE.;Chen C.;Walmer MS.;Walmer MH.;Potts G. .Effect of z value on high temperature performance of Sm(Co,Fe,Cu,Zr)(z) with z=7.14-8.10[J].IEEE Transactions on Magnetics,2000(5 Pt.1):3297-3299.
[13] Zhou S Z.Rare-Earth Permanent Magnets and Application[M].北京:冶金工业出版社,1995:314.
[14] Gong W;Ma B M .Comparison on the magnetic and structural properties of Sm(Co0.67-xFe0.25Cu0.06Zr0.02Cx)8.0,where x = 0-0.15,melt spun ribbons and cast alloys[J].Journal of Applied Physics,1999,85(08):4657.
[15] Tang W;Zhang Y;Hadjipanayis G C .Effects of Zr on the microstructure and magnetic properties os Sm(CobalFe0.1Cu0.088Zrx)8.5 magnets[J].Journal of Applied Physics,2000,87(01):399.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%