Electrical Properties and Microwave Synthesis of Mixed Rare Earth Oxide Ln0.7Sr0.3-xCaxCo0.9Fe0.1O3-δ

稀土学报(英文版), 2006, 24(z2): 288-292.

^1, , ^2, , ^3, , ^4, , ^5, , ^6,

1.Institute of Materials and Technology, Dalian Maritime University, Dalian 116026, China;Department of Material Science and Engineering, Dalian Institute of Light Industry, Dalian 116034, China

2.Institute of Materials and Technology, Dalian Maritime University, Dalian 116026, China

3.Institute of Materials and Technology, Dalian Maritime University, Dalian 116026, China

4.Department of Material Science and Engineering, Dalian Institute of Light Industry, Dalian 116034, China

5.Department of Material Science and Engineering, Dalian Institute of Light Industry, Dalian 116034, China

6.Department of Material Science and Engineering, Dalian Institute of Light Industry, Dalian 116034, China

基金项目: Sweden-Asia Partnership Program(DNR6964) 国家高技术研究发展计划(863计划)(2001AA51580) 辽宁省自然科学基金(20062145) 辽宁省教育厅资助项目(05L073)

Electrical Properties and Microwave Synthesis of Mixed Rare Earth Oxide Ln0.7Sr0.3-xCaxCo0.9Fe0.1O3-δ

Keywords： microwave synthesis

In order to lower the raw materials cost and develop a novel cathode materials for intermediate temperature solid oxide fuel cell(ITSOFC), using mixed rare earth replacing the expensive pure La2O3 as the raw materials, the powders of Ln0.7Sr0.3-xCaxCo0.9Fe0.1O3-δ (Ln=the mixed rare earth, x=0.05, 0.10, 0.15) for the applications as the cathode materials were prepared by microwave sintering process. The crystal structure and the particles morphology of the obtained powders were characterized by XRD and SEM, the electrical conductivity of all samples sintered at 1200 ℃ for 3 h was also measured as the function of the temperature from 100 to 800 ℃ by DC four-probe method in air. The experimental results show that due to the influence of mixed rare earth the powders of Ln0.7Sr0.3-xCaxCo0.9Fe0.1O3-δ synthesized at 1200 ℃ for 0.5 h with the mean particle size of 1～20 μm was of perovskite and cubic fluorite phase as well a little SrO phase, the electrical conductivity of the samples decreases with the adding Ca2+ content, and are all higher than 100 S·cm-1 from 500 to 700 ℃ when x≤0.10. Ln0.7Sr0.3-xCaxCo0.9Fe0.1O3-δ. Can meet the demand of the electrical properties for the cathode materials in ITSOFC.

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材料期刊网

Electrical Properties and Microwave Synthesis of Mixed Rare Earth Oxide Ln0.7Sr0.3-xCaxCo0.9Fe0.1O3-δ

参考文献