欢迎登录材料期刊网

材料期刊网

高级检索

The oxidation of adrenaline by dioxygen using copper phthalocyanine (CuPc) as the catalyzer was studied. CuPc has the optimal catalytic pH of 8.0 and the optimal catalytic temperature of 55 ℃. It also has good storage and operation stability. The fiber optic adrenaline biosensor based on CuPc catalysis and fluorescence quenching was fabricated and studied. This sensor has the detection range of 7.0×10-5 -1.5×10-4 mol/L, the response time of 4 min, good reproducibility and stability.

参考文献

[1] Palop SG;Mellado Romero A;Martinez Calatayud J .Oxidation of adrenaline and noradrenaline by solved molecular oxygen in a FIA assembly.[J].Journal of Pharmaceutical and Biomedical Analysis: An International Journal on All Drug-Related Topics in Pharmaceutical, Biomedical and Clinical Analysis,2002(6):1017-1025.
[2] Nagaraja P;Vasantha RA;Sunitha KR .A new sensitive and selective spectrophotometric method for the determination of catechol derivatives and its pharmaceutical preparations.[J].Journal of Pharmaceutical and Biomedical Analysis: An International Journal on All Drug-Related Topics in Pharmaceutical, Biomedical and Clinical Analysis,2001(3/4):417-424.
[3] Yao H;Sun YY;Lin XH;Cheng JH;Huang LY .Flow-injection chemiluminescence determination of catecholamines based on their enhancing effects on the luminol-potassium periodate system[J].Luminescence: The journal of biological and chemical luminescence,2006(2):112-117.
[4] Loay K.Abdulrahman;Anas M.Al-Abachi;Mayada H.Al-Qaissy .Flow injection-spectrophotometeric determination of some catecholamine drugs in pharmaceutical preparations via oxidative coupling reaction with p-toluidine and sodium periodate[J].Analytica chimica acta,2005(1/2):331-335.
[5] T S Zhou;Q Hu;H Yu et al.Separation and Determination of β-agonists in Serum by Capillary Zone Electrophoresis with Amperometric Detection[J].Analytica Chimica Acta,2001,441:23-28.
[6] K Kasuga;M Tsutsui .Some New Developments in the Chemistry of Metallophthalocyanines[J].Coordination Chemistry Reviews,1980,32:67-95.
[7] 何星存,李平,莫金垣.用修饰电极导数伏安法同时测定多巴胺和肾上腺素[J].分析测试学报,2000(01):19-21.
[8] Palop SG;Mellado Romero A;Martinez Calatayud J .Oxidation of adrenaline and noradrenaline by solved molecular oxygen in a FIA assembly.[J].Journal of Pharmaceutical and Biomedical Analysis: An International Journal on All Drug-Related Topics in Pharmaceutical, Biomedical and Clinical Analysis,2002(6):1017-1025.
[9] J B Zhang;X Chen;J Huang et al.Optical Fiber Oxygen Sensor for Detecting Dissolved Oxygen in Water[J].Journal of Transducers Technology,2002,21:4-7.
[10] Y Kitamura;T Takatsuki;M Kawamoto .Catalytic Activity of Silica Gels Bound Manganese(Ⅲ)-Prophyrin on Oxidative Reaction of Adrenaline[J].Chemical and Pharmaceutical Bulletin,2007,55(03):500-506.
[11] 杨杭生,彭图治,沈报恩.薄层光谱电化学研究多巴胺在碳纤维电极上的氧化过程[J].浙江大学学报(理学版),2001(03):294-298.
[12] B Chen;S Q Yang;C D Zhao .Study on the Mechanisms of Catalytic Desulfurization With Binuclear Metallo Phthalocyanine(Ⅲ)-The Electronic Structure of M (Ⅱ) Pc-PcM (Ⅱ) and Mode of Binding Between M (Ⅱ) and Pc[J].Chinese Journal of Molecular Science,1996,12(03):204-210.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%