分别以氧化石墨粉(GO)、还原氧化石墨烯乙醇悬浮液(RGO)和热法还原石墨烯粉(TRG)为填料,分散于酚醛树脂(PR)的乙醇溶液中,再将这些基体混合物涂覆于炭纤维(CF)布上,经热压成型工艺制备氧化石墨烯/酚醛树脂/炭纤维、还原氧化石墨烯乙醇悬浮液/酚醛树脂/炭纤维、热法还原氧化石墨烯/酚醛树脂/炭纤维层次复合材料.研究了GO、RGO和TRG对复合材料结构、压缩性能、弯曲性能及磨擦性能的影响.结果表明,与纯酚醛树脂/炭纤维复合材料相比,当纳米填料的质量分数仅为0.1%时,层次复合材料的压缩性能可显著提高,其中,热法还原氧化石墨烯/酚醛树脂/炭纤维的压缩强度和模量分别提高了178.9%,129.5%;弯曲性能也可得到一定的改善.还原氧化石墨烯乙醇悬浮液/酚醛树脂/炭纤维层次复合材料的最大储能模量可提高75.2%.所有改性石墨烯/酚醛树脂/炭纤维层次复合材料的Tg均有所降低.
参考文献
[1] | Lotta Gaab;Dietmar Koch;Georg Grathwohl .Effects of thermal and thermomechanical induced mechanical changes of C/C composites[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(10):2980-2988. |
[2] | Shameel Farhan,李克智,郭领军,高全明,兰逢涛.密度和纤维取向对炭/炭复合材料烧蚀性能的影响[J].新型炭材料,2010(03):161-167. |
[3] | Phenolic matrix nanocomposites based on commercial grade resols: Synthesis and characterization[J].Composites science and technology,2010(4):571. |
[4] | Meng-Kao Yeh;Nyan-Hwa Tai;Jia-Hau Liu .Mechanical behavior of phenolic-based composites reinforced with multi-walled carbon nanotubes[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(1):1-9. |
[5] | F. Yavari;M. A. Rafiee;J. Rafiee .Dramatic Increase in Fatigue Life in Hierarchical Graphene Composites[J].ACS applied materials & interfaces,2010(10):2738-2743. |
[6] | Yanzhen Liu;Yongfeng Li;Yonggang Yang;Yuefang Wen;Maozhang Wang .Reduction of Graphene Oxide by Thiourea[J].Journal of nanoscience and nanotechnology,2011(11):10082-10086. |
[7] | Lin Y Z;Li Y F;Zhong M et al.A green and ultrafast approach to the synthesis scalable graphene nanosheets by Zn powder for electrochemical energy storage[J].Journal of Materials Chemistry,2011,21(39):15449-15455. |
[8] | Lv, W.;Tang, D.-M.;He, Y.-B.;You, C.-H.;Shi, Z.-Q.;Chen, X.-C.;Chen, C.-M.;Hou, P.-X.;Liu, C.;Yang, Q.-H. .Low-temperature exfoliated graphenes: Vacuum-promoted exfoliation and electrochemical energy storage[J].ACS nano,2009(11):3730-3736. |
[9] | Changgu Lee;Xiaoding Wei;Jeffrey W. Kysar;James Hone .Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene[J].Science,2008(5887):385-388. |
[10] | 刘燕珍,李永锋,杨永岗,温月芳,王茂章.低温热处理对氧化石墨烯薄膜的影响[J].新型炭材料,2011(01):41-45. |
[11] | 刘琳,叶紫平,胡楠.修饰碳纳米管对树脂基摩擦材料力学性能的影响[J].工程塑料应用,2009(09):13-17. |
[12] | Hughes J D H .The carbon fiber/epoxy interface[J].Composites Science and Technology,1991,41(01):13-45. |
[13] | 曾汉民.树脂基复合材料界面工程(ZENG H M.Interracial Process of Resin-based Composites[M].Beijing:Tsinghua University Press,1990.)[M].北京:清华大学出版社,1990 |
[14] | Rafiee, M.A.;Rafiee, J.;Wang, Z.;Song, H.;Yu, Z.-Z.;Koratkar, N. .Enhanced mechanical properties of nanocomposites at low graphene content[J].ACS nano,2009(12):3884-3890. |
[15] | Cai D Y;Song M .Recent advance in functionalized graphene/polymer nanocomposites[J].Journal of Materials Chemistry,2010,20(37):7906-7915. |
[16] | Kim H;Macosko CW .Morphology and properties of polyester/exfoliated graphite nanocomposites[J].Macromolecules,2008(9):3317-3327. |
[17] | Hyunwoo Kim;Yutaka Miura;Christopher W. Macosko .Graphene/Polyurethane Nanocomposites for Improved Gas Barrier and Electrical Conductivity[J].Chemistry of Materials: A Publication of the American Chemistry Society,2010(11):3441-3450. |
[18] | Kim, H;Macosko, CW .Processing-property relationships of polycarbonate/graphene composites[J].Polymer: The International Journal for the Science and Technology of Polymers,2009(15):3797-3809. |
[19] | Xiali Zhang;Liang Shen;Xue Xia;Haitao Wang;Qiangguo Du .Study On The Interface Of Phenolic Resin/expanded Graphite Composites Prepared Via In Situ Polymerization[J].Materials Chemistry and Physics,2008(2/3):368-374. |
[20] | Ming Fang;Zhen Zhang;Jianfeng Li .Constructing hierarchically structured interphases for strong and tough epoxy nanocomposites by amine-rich graphene surfaces[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2010(43):9635-9643. |
[21] | Kim K S;Jeon I Y;Ahn S N et al.Edge-functionalized graphene-like platelets as a co-curing agent and a nanoscale additive to epoxy resin[J].Journal of Materials Chemistry,2011,21(20):7337-7342. |
[22] | Huafeng Yang;Changsheng Shan;Fenghua Li .Convenient preparation of tunably loaded chemically converted graphene oxide/epoxy resin nanocomposites from graphene oxide sheets through two-phase extraction[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2009(46):8856-8860. |
[23] | Putz KW;Palmeri MJ;Cohn RB;Andrews R;Brinson LC .Effect of cross-link density on interphase creation in polymer nanocomposites[J].Macromolecules,2008(18):6752-6756. |
[24] | Yuqiang Guo;Chenlu Bao;Lei Song .In Situ Polymerization of Graphene, Graphite Oxide, and Functionalized Graphite Oxide into Epoxy Resin and Comparison Study of On-the-Flame Behavior[J].Industrial & Engineering Chemistry Research,2011(13):7772-7783. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%