研究了不同超声条件下所制备的聚偏氟乙烯(PVDF)膜的结构和性能.通过傅里叶全反射红外光谱、扫描电子显微镜、广角X射线衍射仪等对所制备的PVDF膜结构和形貌进行了表征.结果表明,超声场的加入在保证膜截留率的同时,能够显著提高PVDF膜的通量.超声条件为(100 kHz/300 W)时,膜水通量和玫瑰红水溶液(10 mg/L)通量提高幅度较大,分别提高了46.1%和43.4%,并且截留率仍保持在80.0%左右.超声辅助相转化过程中,PVDF有部分β晶型向α晶型转变.
参考文献
[1] | Buonomenna MG;Macchi P;Davoli M;Drioli E .Poly(vinylidene fluoride) membranes by phase inversion: the role the casting and coagulation conditions play in their morphology, crystalline structure and properties[J].European Polymer Journal,2007(4):1557-1572. |
[2] | Xuyun Wang;Lin Zhang;Dahai Sun .Formation mechanism and crystallization of poly(vinylidene fluoride) membrane via immersion precipitation method[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2009(1/3):170-178. |
[3] | M. Kallioinen;M. Manttari .Influence of Ultrasonic Treatment on Various Membrane Materials: A Review[J].Separation Science and Technology,2011(9/12):1388-1395. |
[4] | Tao, M.-M.;Liu, F.;Xue, L.-X. .Poly(vinylidene fluoride) membranes by an ultrasound assisted phase inversion method[J].Ultrasonics sonochemistry,2013(1):232-238. |
[5] | 王萍辉.超声空化影响因素[J].河北理工学院学报,2003(04):154-161. |
[6] | Yamaguchi K;Matsumoto T;Kuwata K .Proper calibration of ultrasonic power enabled the quantitative analysis of the ultrasonication-induced amyloid formation process.[J].Protein Science: A Publication of the Protein Society,2012(1):38-49. |
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