采用NF270和GE DK纳滤膜,在不同压力、温度和pH条件进行纯水过滤试验,以测定不同条件下两种纳滤膜的膜通量,并研究不同条件下的纳滤膜渗透系数变化规律;构建纳滤膜渗透系数与热力学参数之间的关系式,计算两种纳滤膜的热力学参数,分析两种纳滤膜分离过程热力学原理.结果表明:两种纳滤膜的膜通量随着温度和压力的增加而增大,两种纳滤膜的渗透系数随着温度升高而增大,并随着压力和pH的变化呈现小幅波动;GE DK纳滤膜的活化能高于NF 270纳滤膜的活化能,分别为16.56 kJ/mol和14.22 kJ/mol.由此可知,在分离过程中GE DK纳滤膜比NF 270纳滤膜需更高的运行压力.
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