利用溶胶-凝胶、氢气还原及热压工艺制备了纳米复合Mo-4La2O3(质量分数,%)阴极材料,其显微组织中La2O3粒径小于100nm,而常规Mo-4La2O3阴极中La2O3粒径为200~300 nm.在真空击穿实验中发现La2O3粒径对于阴极电子发射性能有显著的影响,纳米复合阴极的电子发射能力远高于常规阴极的发射能力,其电子发射点遍布整个阴极表面,而常规阴极电子发射点只是集中在一小块区域.通过建立会属-半导体电子相互作用模型,计算并绘制了Mo及La2O3中电子隧穿几率随La2O3粒径变化的关系曲线,解释了纳米复合阴极电子发射能力强的原因.
参考文献
[1] | Wang Jinshu;Zhou Meiling;Zuo Tieyong .A study of chemical behavior of lanthanum in La_2O_3-Mo thermionic cathode materials[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2002(1/2):293-298. |
[2] | Suga Y;Matsumoto H .[J].Journal of High Temperature Society,1991,17(03):136. |
[3] | Yang JC.;Nie ZR.;Wang YM. .Microstructure and emission ability of rare earth oxides doped molybdenum cathodes[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2003(1/4):87-95. |
[4] | Hui Zhang;Xianfeng Chen;Zhimao Yang .W-ThO_2 thermionic cathode activated with nanoscale oxide[J].Materials Letters,1999(6):401-405. |
[5] | 诸葛飞,王发展,张晖,丁秉钧.纳米复合W-6%ThO2和W-2%ThO2阴极材料的性能对比[J].稀有金属材料与工程,2003(02):141-143. |
[6] | 席晓丽,聂祚仁,郝世明,杨建参,翟立力,左铁镛.纳米复合W-La2O3材料的表面行为与热发射性能[J].中国有色金属学报,2005(06):907-911. |
[7] | 杨德清;庄伟.子发射原理与应用[M].昆明:云南大学出版社,1995:30. |
[8] | Nie Zuoren,Zhou Meiling,Wang Jinshu,Zhang Jiuxing,Zuo Tieyong.THERMIONIC EMISSION OF CARBONIZED La-Mo CATHODE[J].中国有色金属学会会刊(英文版),1999(02):230-234. |
[9] | WANG Jin-shu,ZHOU Mei-ling,NIE Zuo-ren,ZHANG Jiu-xing,LUO Feng-hua.Emission mechanism of Mo-Y2O3 cathode[J].中国有色金属学会会刊,2000(05):576. |
[10] | Fursey G N .[J].Insulation,1985,20(04):659. |
[11] | Fursey GN. .Field emission in vacuum micro-electronics[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2003(1/4):113-134. |
[12] | John Robertson .Band offsets of wide-band-gap oxides and implications for future electronic devices[J].Journal of Vacuum Science & Technology, B. Microelectronics and Nanometer Structures: Processing, Measurement and Phenomena,2000(3):1785-1791. |
[13] | 倪光炯.高等量子力学[M].上海:复旦大学出版社,2001:354. |
[14] | Gleiter H;Weissmuller J .[J].Acta Materialia,2001,49:737. |
[15] | Mulyukov R;Litvinov E A .[J].Physica B,2002,324:329. |
[16] | Cutler P.H.;Lerner P.B.;Chung Moon S.;Miskovsky N.M. .Use of internal field emission to inject electronic charge carriers into the conduction band of diamond films: A review[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,1999(1):126-133. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%