两亲性嵌段聚合物在选择性溶剂中的自组装行为导致其在纳米材料制备过程中具有非常好的应用前景.文中以两亲性嵌段聚合物的基本结构特点及自组装行为为出发点,概述了用于制备半导体纳米材料的两亲性嵌段聚合物的种类及特点,重点介绍了以两亲性嵌段聚合物为模板制备半导体纳米粒子的基本方法及在各种条件下半导体纳米粒子的不同生长机制,并对两亲性嵌段聚合物在制备功能化纳米材料方面的应用进行了展望.
参考文献
[1] | Moffitt M.;Eisenberg A.;Vali H. .Spherical assemblies of semiconductor nanoparticles in water-soluble block copolymer aggregates[J].Chemistry of Materials,1998(4):1021-1028. |
[2] | Hanying Zhao;Elliot P. Douglas;Benjamin S. Harrison;Kirk S. Schanze .Preparation of CdS Nanoparticles in Salt-Induced Block Copolymer Micelles[J].Langmuir: The ACS Journal of Surfaces and Colloids,2001(26):8428-8433. |
[3] | Yusuf H;Kim WG;Lee DH;Guo YY;Moffitt MG .Size control of mesoscale aqueous assemblies of quantum dots and block copolymers[J].Langmuir: The ACS Journal of Surfaces and Colloids,2007(26):868-878. |
[4] | Nicolas Duxin;Futian Liu;Hojatollah Vali;Adi Eisenberg .Cadmium Sulphide Quantum Dots in Morphologically Tunable Triblock Copolymer Aggregates[J].Journal of the American Chemical Society,2005(28):10063-10069. |
[5] | Haeng-Deog Koh;Nam-Goo Kang;Jae-Suk Lee .Location Control of Au/CdS Nanoparticles in Block Copolymer Micelles[J].Langmuir: The ACS Journal of Surfaces and Colloids,2007(23):11425-11429. |
[6] | Andrea B. R. Mayer .Formation of noble metal nanoparticles within a polymeric matrix: nanoparticle features and overall morphologies[J].Materials science & engineering, C. Biomimetic and supramolecular systems,1998(2/3):155-166. |
[7] | Yusuf H;Kim WG;Lee DH;Aloshyna M;Brolo AG;Moffitt MG .A hierarchical self-assembly route to three-dimensional polymer-quantum dot photonic arrays[J].Langmuir: The ACS Journal of Surfaces and Colloids,2007(10):5251-5254. |
[8] | Mayer ABR.;Morris RE.;Mark JE. .Palladium and platinum nanocatalysts protected by amphiphilic block copolymers[J].Polymer Journal,1998(3):197-205. |
[9] | Kaiqiang Chen;Yongfang Yang;Qina Sa .Suspension polymerization stabilized by triblock copolymer with CdS nanoparticles[J].Polymer,2008(11):2650-2655. |
[10] | Wang MF;Kumar S;Lee A;Felorzabihi N;Shen L;Zhao F;Froimowicz P;Scholes GD;Winnik MA .Nanoscale co-organization of quantum dots and conjugated polymers using polymeric micelles as templates[J].Journal of the American Chemical Society,2008(29):9481-9491. |
[11] | Zhao HY.;Douglas EP. .Preparation of corona-embedded CdS nanoparticles[J].Chemistry of Materials,2002(3):1418-1423. |
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