介孔碳材料不仅具有高比表面积和大孔径,还具有表面疏水性、良好的水热稳定性及优异的导电性等特点,在催化、电化学等诸多领域具有广阔的应用前景,成为国内外研究的热点之一。文中主要综述了近年来利用聚丙烯腈制备介孔碳材料的研究进展,并简要阐述了不同形貌的聚丙烯腈基介孔碳材料的制备方法及在催化剂载体、超级电容器、燃料电池等领域的具体应用,最后展望了介孔碳材料的发展趋势。
Due to the high specific surface area,large pore volume,hydrophobic,great aqueous and thermal stability,excellent conductivity,mesoporous carbon materials have been widely used in many fields,such as catalyst support and electrochemical,and then become one of the most popular topics at home and abroad.Based on the recent research progress of the mesoporous carbon materials from polyacrylonitrile,we summarized the preparation of mesoporous carbon materials with different structures,and covered representative research results,discussed their applications in catalysis,supercapacitor and fuel cell,we also analysiszed the development prospects of the new carbon material in future.
参考文献
| [1] | An-Hui Lu;Wiolfgang Schmidt;Nina matoussevitch;HelmutBonnemann;Bernd Spliethoff;Bernd Tesche .Nanoengineering of a Magnetically Separable Hydrogenation Catalyst[J].Angewandte Chemie,2004(33):4303-4306. |
| [2] | Lee J;Kim J;Hyeon T .Recent progress in the synthesis of porous carbon materials[J].Advanced Materials,2006(16):2073-2094. |
| [3] | da Silva CR;Wallau M;Urquieta-Gonzalez EA .Mesoporous carbons prepared by nano-casting with meso- or non-porous silica nanoparticles[J].Journal of the Brazilian Chemical Society,2006(6):1170-1180. |
| [4] | Sakintuna, B;Yurum, Y .Templated porous carbons: A review article[J].Industrial & Engineering Chemistry Research,2005(9):2893-2902. |
| [5] | Molenda M;Dziembaj R;Piwowarska Z;Drozdek M .A new method of coating powdered supportswith conductive carbon films[J].Journal of thermal analysis and calorimetry,2007(2):503-506. |
| [6] | Aqil A;Detrembleur C;Gilbert B;Jerome R;Jerome C .Controlled RAFT synthesis of polyacrylonitrile-b-poly(acrylic acid) diblocks as precursors of carbon nanocapsules with assistance of gold nanoparticles[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(9):2150-2154. |
| [7] | T. Kowalewski;R. D. McCullough;K. Matyjaszewski .Complex nanostructured materials from segmented copolymers prepared by ATRP[J].The European physical journal, E. Soft matter,2003(1):5-16. |
| [8] | Lu AH.;Kiefer A.;Schmidt W.;Schuth F. .Synthesis of polyacrylonitrile-based ordered mesoporous carbon with tunable pore structures[J].Chemistry of Materials,2004(1):100-103. |
| [9] | Kruk M;Dufour B;Celer EB;Kowalewski T;Jaroniec M;Matyjaszewski K .Well-defined poly(ethylene oxide)-polyacrylonitrile diblock copolymers as templates for mesoporous silicas and precursors for mesoporous carbons[J].Chemistry of Materials: A Publication of the American Chemistry Society,2006(6):1417-1424. |
| [10] | Kruk M;Dufour B;Celer EB;Kowalewski T;Jaroniec M;Matyjaszewski K .Grafting Monodisperse Polymer Chains from Concave Surfaces of Ordered Mesoporous Silicas[J].Macromolecules,2008(22):8584-8591. |
| [11] | Wu S;Ju HX;Liu Y .Conductive mesocellular silica-carbon nanocomposite foams for immobilization, direct electrochemistry, and biosensing of proteins[J].Advanced functional materials,2007(4):585-592. |
| [12] | Wang, HY;Wan, Y .Synthesis of ordered mesoporous Pd/carbon catalyst with bimodal pores and its application in water-mediated Ullmann coupling reaction of chlorobenzene[J].Journal of Materials Science,2009(24):6553-6562. |
| [13] | Haolin Tang;San Ping Jiang .Self-Assembled Pt/Mesoporous Silica—Carbon Electrocatalysts for Elevated-Temperature Polymer Electrolyte Membrane Fuel Cells[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(49):19748-19755. |
| [14] | Gang Liu;Xuguang Li;Prabhu Ganesan .Development of non-precious metal oxygen-reduction catalysts for PEM fuel cells based on N-doped ordered porous carbon[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2009(1/2):156-165. |
| [15] | Lin ML;Huang CC;Lo MY;Mou CY .Well-ordered mesoporous carbon thin film with perpendicular channels: Application to direct methanol fuel cell[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(3):867-873. |
- 下载量()
- 访问量()
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%