采用传统的熔融法制备了以P2O5为形核剂的Li2O-SiO2系统基础玻璃.通过差热分析方法获得该玻璃晶化的热处理条件,并确定了一步法和两步法的热处理工艺.利用XRD和SEM对一步法和两步法晶化处理后试样的物相组成和微观结构进行分析,讨论了不同热处理制度对析出晶相的种类和微观结构的影响.结果表明:一步法热处理得到的主晶相为亚稳定的一硅酸锂(Li2SiO3)晶体,继续升高热处理温度后,一硅酸锂(Li2SiO3)晶相向二硅酸锂(Li2Si2O5)转变,最后两步法热处理试样的晶相种类为Li2SiO3和Li2Si2O5 2种晶体.两步法热处理有利于稳定的Li2Si2O5晶体析出.从一步法到两步法的热处理,Li2Si2O5晶体的尺寸明显增加.另外,对于两步法热处理,在相同的形核时间下,延长晶体长大时间,Li2Si2O5晶体的生长比较缓慢.
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